journal article·2015-11-13Open access

Polypropylene/Graphene and Polypropylene/Carbon Fiber Conductive Composites: Mechanical, Crystallization and Electromagnetic Properties

Chien-Lin Huang, Ching-Wen Lou, Chi-Fan Liu, Chen-Hung Huang, Xiao-Min Song, Jia-Horng Lin

Applied Sciences· Volume 5· Issue 4

Abstract

This study aims to examine the properties of composites that different carbon materials with different measurements can reinforce. Using a melt compounding method, this study combines polypropylene (PP) and graphene nano-sheets (GNs) or carbon fiber (CF) to make PP/GNs and PP/CF conductive composites, respectively. The DSC results and optical microscopic observation show that both GNs and CF enable PP to crystalize at a high temperature. The tensile modulus of PP/GNs and PP/CF conductive composites remarkably increases as a result of the increasing content of conductive fillers. The tensile strength of the PP/GNs conductive composites is inversely proportional to the loading level of GNs. Containing 20 wt% of GNs, the PP/GNs conductive composites have an optimal conductivity of 0.36 S/m and an optimal EMI SE of 13 dB. PP/CF conductive composites have an optimal conductivity of 10−6 S/m when composed of no less than 3 wt% of CF, and an optimal EMI SE of 25 dB when composed of 20 wt% of CF.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Natural Fiber Reinforced Composites · Fiber-reinforced polymer composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Fiber and Composite Materials, Feng Chia University, Taichung City 40724, Taiwan

Institute of Biomedical Engineering and Materials Science, Central Taiwan University of Science and Technology, Taichung City 40601, Taiwan

Office of Physical Education and Sports Affairs, Feng Chia University, Taichung 407, Taiwan

Department of Aerospace and Systems Engineering, Feng Chia University, Taichung City 40724, Taiwan

Laboratory of Fiber Application and Manufacturing, Department of Fiber and Composite Materials, Feng Chia University, Taichung City 40724, Taiwan

School of Chinese Medicine, China Medical University, Taichung City 40402, Taiwan

Department of Fashion Design, Asia University, Taichung City 41354, Taiwan

References (43)

Show source-provided references
1. The combined effects of carbon black and carbon fiber on the electrical properties of composites based on polyethylene or polyethylene/polypropylene blend10.1016/j.polymertesting.2011.03.007 ↗
2. Control of carbon nanotubes at the interface of a co-continuous immiscible polymer blend to fabricate conductive composites with ultralow percolation thresholds10.1016/j.carbon.2014.02.063 ↗
3. Development of electrical conductivity with minimum possible percolation threshold in multi-wall carbon nanotube/polystyrene composites10.1016/j.carbon.2011.06.070 ↗
4. Investigation of the electric conductivity and the electromagnetic interference shielding efficiency of SWCNTs/GNS/PAni nanocomposites10.1016/j.diamond.2011.06.007 ↗
5. Synergistic effect of carbon fibers on the conductive properties of a segregated carbon black/polypropylene composite10.1016/j.matlet.2014.04.189 ↗
6. Electrical and dielectric properties of carbon black filled co-continuous two-phase polymer blends10.1088/0022-3727/32/13/313 ↗
7. The electrical conductivity of carbon nanotube/carbon black/polypropylene composites prepared through multistage stretching extrusion10.1016/j.polymer.2012.02.003 ↗
8. Electrical properties of hybrid carbon black/carbon fiber polypropylene composites10.1007/s10853-006-1203-4 ↗
9. Improvement of melt spinning properties and conductivity of immiscible polypropylene/polystyrene blends containing carbon black by addition of styrene-ethylene-butene-styrene block copolymer10.1002/pen.21828 ↗
10. Conductive nitrile rubber composite containing carbon fillers: Studies on mechanical properties and electrical conductive10.1016/0010-4361(92)90439-2 ↗
11. Correlated electrical conductivity and mechanical property analysis of high-density polyethylene filled with graphite and carbon fiber10.1016/S0032-3861(02)00043-5 ↗
12. Electrical property and microstructure analysis of poly(vinylidene fluoride)-based composites with different conducting fillers10.1016/j.cplett.2007.02.076 ↗
13. A new compounding method for exfoliated graphite–polypropylene nanocomposites with enhanced flexural properties and lower percolation threshold10.1016/j.compscitech.2006.11.014 ↗
14. A review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites10.1016/j.progpolymsci.2010.11.003 ↗
15. AC and DC percolative conductivity of single wall carbon nanotube polymer composites10.1002/polb.20597 ↗
16. Improvement of electrical conductivity with phase-separation in polyolefin/multiwall carbon nanotube/polyethylene oxide composites10.1002/app.38591 ↗
17. Graphene-based composite materials10.1038/nature04969 ↗
18. Graphene-based polymer nanocomposites10.1016/j.polymer.2010.11.042 ↗
19. The rise of graphene10.1038/nmat1849 ↗
20. Using a non-covalent modification to prepare a high electromagnetic interference shielding performance graphene nanosheet/water-borne polyurethane composite10.1016/j.carbon.2013.03.056 ↗
21. Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding10.1016/j.polymer.2010.01.027 ↗
22. Nucleating effect of calcium stearate coated CaCO3 nanoparticles on polypropylene10.1016/j.jcis.2010.10.069 ↗
23. A plant fiber reinforced polymer composite prepared by a twin-screw extruder10.1016/j.biortech.2008.03.065 ↗
24. Functionalized multi-walled carbon nanotubes improve nonisothermal crystallization of poly(ethylene terephthalate)10.1016/j.polymertesting.2007.09.012 ↗
25. Crystallization behavior of poly(trimethylene terephthalate)-poly(ethylene glycol) segmented copolyesters/multi-walled carbon nanotube nanocomposites10.1016/j.polymertesting.2010.09.009 ↗
26. Crystallization and reinforcement of poly (vinylidene fluoride) nanocomposites: Role of high molecular weight resin and carbon nanotubes10.1016/j.polymertesting.2011.10.005 ↗
27. Role of multi-wall carbon nanotube network in composites to crystallization of isotactic polypropylene matrix10.1016/j.polymer.2007.11.041 ↗
28. Effect of carbon nanotubes content on crystallization kinetics and morphology of polypropylene10.1016/j.polymertesting.2008.10.001 ↗
29. Crystallization behaviors in the isotactic polypropylene/graphene composites10.1016/j.polymer.2014.06.027 ↗
30. Reinforcing brittle and ductile epoxy matrices using carbon nanotubes masterbatch10.1016/j.compositesa.2014.02.016 ↗
31. Masterbatch-based multi-walled carbon nanotube filled polypropylene nanocomposites: Assessment of rheological and mechanical properties10.1016/j.compscitech.2008.10.005 ↗
32. Electromagnetic interference shielding mechanisms of CNT/polymer composites10.1016/j.carbon.2009.02.030 ↗
33. Comparative study of electromagnetic interference shielding properties of injection molded versus compression molded multi-walled carbon nanotube/polystyrene composites10.1016/j.carbon.2012.06.053 ↗
34. Electrical and electromagnetic interference shielding properties of flow-induced oriented carbon nanotubes in polycarbonate10.1016/j.carbon.2011.04.039 ↗
35. High thermal conductivity and high electrical resistivity of poly(vinylidene fluoride)/polystyrene blends by controlling the localization of hybrid fillers10.1016/j.compscitech.2013.09.024 ↗
36. Electromagnetic absorbing properties of graphene–polymer composite shields10.1016/j.carbon.2014.02.053 ↗
37. The electrical conductivity and electromagnetic interference shielding of injection molded multi-walled carbon nanotube/polystyrene composites10.1016/j.carbon.2011.11.004 ↗
38. Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials10.1016/j.mser.2013.06.001 ↗
39. Fabrication of microwave exfoliated graphite oxide reinforced thermoplastic polyurethane nanocomposites: Effects of filler on morphology, mechanical, thermal and conductive properties10.1016/j.compositesa.2012.12.009 ↗
40. Synthesis of well dispersed graphene in conjugated poly(3,4-ethylenedioxythiophene):polystyrene sulfonate via click chemistry10.1016/j.compscitech.2013.12.024 ↗
41. Electrical behavior of polypropylene composites melt mixed with carbon-based particles: Effect of the kind of particle and annealing process10.1016/j.compscitech.2014.05.018 ↗
42. Tunable architecture for flexible and highly conductive graphene–polymer composites10.1016/j.compscitech.2014.02.013 ↗
43. Interpenetrating network formation in isotactic polypropylene/graphene composites10.1016/j.polymer.2013.04.059 ↗