journal article·2019-04-29Open access

Gasochromic WO3 Nanostructures for the Detection of Hydrogen Gas: An Overview

Ali Mirzaei, Jae-Hun Kim, Hyoun Woo Kim, Sang Sub Kim

Applied Sciences· Volume 9· Issue 9

Abstract

Hydrogen is one of the most important gases that can potentially replace fossil fuels in the future. Nevertheless, it is highly explosive, and its leakage should be detected by reliable gas sensors for safe operation during storage and usage. Most hydrogen gas sensors operate at high temperatures, which introduces the risk of hydrogen explosion. Gasochromic WO3 sensors work based on changes in their optical properties and color variation when exposed to hydrogen gas. They can work at low or room temperatures and, therefore, are good candidates for the detection of hydrogen leakage with low risk of explosion. Once their morphology and chemical composition are carefully designed, they can be used for the realization of sensitive, selective, low-cost, and flexible hydrogen sensors. In this review, for the first time, we discuss different aspects of gasochromic WO3 gas sensor-based hydrogen detection. Pristine, heterojunction, and noble metal-decorated WO3 nanostructures are discussed for the detection of hydrogen gas in terms of changes in their optical properties or visible color. This review is expected to provide a good background for research work in the field of gas sensors.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Transition Metal Oxide Nanomaterials · Advanced Chemical Sensor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, Shiraz University of Technology, Shiraz 71557-13876, Iran

Department of Materials Science and Engineering, Inha University, Incheon 22212, Korea

The Research Institute of Industrial Science, Hanyang University, Seoul 04763, Korea

Division of Materials Science and Engineering, Hanyang University, Seoul 04763, Korea

References (100+)

Show source-provided references
1. Complex behavior of hydrogen sensor using nanoporous palladium film prepared by evaporation10.1016/j.apsusc.2019.02.088 ↗
2. Fabrication of porous silicon filled Pd/SiC nanocauliflower thin films for high performance H2 gas sensor10.1016/j.snb.2018.02.164 ↗
3. Preparation of palladium-doped mesoporous WO3 for hydrogen gas sensors10.1016/j.jallcom.2018.10.372 ↗
4. Reliability of commercially available hydrogen sensors for detection of hydrogen at critical concentrations: Part I-Testing facility and methodologies10.1016/j.ijhydene.2008.10.004 ↗
5. Highly sensitive and selective hydrogen gas sensor using sputtered grown Pd decorated MnO2 nanowalls10.1016/j.snb.2016.04.152 ↗
6. Hydrogen sensor based on polymer-filled hollow core fiber with Pt-loaded WO3/SiO2 coating10.1016/j.snb.2017.01.206 ↗
7. Catalytic hydrogen sensing using microheated platinum nanoparticle-loaded graphene aerogel10.1016/j.snb.2014.09.057 ↗
8. Hydrogen sensing of the mixed-potential-type MnWO4/YSZ/Pt sensor10.1016/j.snb.2014.09.055 ↗
9. Palladium nanoparticle-based surface acoustic wave hydrogen sensor10.1021/am507531s ↗
10. Hydrogen sensing properties and mechanism of NiO-Nb2O5 composite nanoparticle-based electrical gas sensors10.1016/j.ceramint.2017.01.050 ↗
11. Thermochemical hydrogen sensor based on Pt-coated nanofiber catalyst deposited on pyramidally textured thermoelectric film10.1016/j.apsusc.2016.10.022 ↗
12. Hydrogen sensors-A review10.1016/j.snb.2011.04.070 ↗
13. Preparation of Pt/WO3-coated polydimethylsiloxane membrane for transparent/flexible hydrogen gas sensors10.1016/j.matchemphys.2018.12.052 ↗
14. Ultra-responsive hydrogen gas sensors based on PdO nanoparticle-decorated WO3 nanorods synthesized by precipitation and impregnation methods10.1016/j.snb.2015.11.120 ↗
15. Detection of hazardous volatile organic compounds (VOCs) by metal oxide nanostructures-based gas sensors: A review10.1016/j.ceramint.2016.06.145 ↗
16. Microwave-assisted synthesis of metal oxide nanostructures for gas sensing application: A review10.1016/j.snb.2016.06.114 ↗
17. α-Fe2O3 based nanomaterials as gas sensors10.1007/s10854-015-4200-z ↗
18. An optical ammonia (NH3) gas sensing by means of Pd/CuPc interferometric nanostructures based on white light interferometry10.1016/j.snb.2013.04.051 ↗
19. Construction of solid-state Z-scheme carbon-modified TiO2/WO3 nanofibers with enhanced photocatalytic hydrogen production10.1016/j.jpowsour.2016.08.001 ↗
20. Optical fiber hydrogen sensor based on evaporated Pt/WO3 film10.1016/j.snb.2014.09.093 ↗
21. WO3/TiO2 core-shell nanostructure for high performance energy-saving smart windows10.1016/j.solmat.2014.11.007 ↗
22. Removal of acetylsalicylate and methyl-theobromine from aqueous environment using nano-photocatalyst WO3-TiO2 @g-C3N4 composite10.1016/j.jhazmat.2018.09.055 ↗
23. Transparent WO3/Ag/WO3 electrode for flexible organic solar cells10.1016/j.matlet.2016.11.054 ↗
24. Response to humidity of TiO2:WO3 sensors doped with V2O5: Influence of fabrication route10.1016/j.snb.2016.05.109 ↗
25. Ordered mesoporous WO3/ZnO nanocomposites with isotype heterojunctions for sensitive detection of NO210.1016/j.snb.2018.12.089 ↗
26. Cubic WO3 stabilized by inclusion of Ti: Applicable in photochromic glazing10.1016/j.solmat.2016.04.041 ↗
27. Tungsten-based glasses for photochromic, electrochromic, gas sensors, and related applications: A review10.1016/j.jnoncrysol.2018.03.050 ↗
28. Colouration of tungsten oxide films: A model for optically active coatings10.1016/S0927-0248(98)00196-2 ↗
29. The high-temperature phases of WO310.1006/jssc.1999.8173 ↗
30. Optical characterisation of nanostructured Au/WO3 thin films for sensing hydrogen at low concentrations10.1016/j.snb.2012.09.102 ↗
31. Pandurang, A. (2017). Transition Metal Oxide Thin Film Based Chromogenics and Devices, Elsevier. [1st ed.].
32. IR Spectroscopic studies of charged-discharged crystalline WO3 films10.1016/S0013-4686(01)00361-9 ↗
33. Hydrogen behavior in gasochromic tungsten oxide films investigated by elastic recoil detection analysis10.1016/j.nimb.2007.11.016 ↗
34. Comparative study of gasochromic and electrochromic effect in thermally evaporated tungsten oxide thin films10.1016/j.tsf.2008.12.020 ↗
35. Investigations of reversible optical transmission in gasochromic (Ti-V-Ta) Ox thin film for gas sensing applications10.1016/j.snb.2014.04.084 ↗
36. Improved room-temperature hydrogen sensing performance of directly formed Pd/WO3 nanocomposite10.1016/j.snb.2013.11.057 ↗
37. A fast response/recovery of hydrophobic Pd/V2O5 thin films for hydrogen gas sensing10.1016/j.snb.2016.05.141 ↗
38. Gasochromic response of nanocrystalline vanadium pentoxide films deposited from ethanol dispersions10.1016/j.tsf.2010.07.010 ↗
39. Characterization of gasochromic vanadium oxides films by X-ray absorption spectroscopy10.1016/j.tsf.2013.02.080 ↗
40. Effect of O2 partial pressure and thickness on the gasochromic properties of sputtered V2O5 films10.1007/s10853-005-2851-5 ↗
41. Effects of oxygen partial pressure on structural and gasochromic properties of sputtered VOx thin films10.1016/j.tsf.2013.02.083 ↗
42. Plasmonic Au-MoO3 colloidal nanoparticles by reduction of HAuCl4 by blue MoOx nanosheets and observation of the gasochromic property10.1007/s11468-018-0704-8 ↗
43. Pd on MoO3 nanoplates as small-polaron-resonant eye-readable gasochromic and electrical hydrogen sensor10.1016/j.snb.2017.03.033 ↗
44. Pulsed laser deposition of (MoO3)1-x (V2O5)x thin films: Preparation, characterization and gasochromic studies10.1016/j.tsf.2010.09.003 ↗
45. H2S gasochromic effect of mixed ammonium salts of phosphomolybdate nanoparticles synthesized by microwave assisted technique10.1016/j.snb.2016.06.166 ↗
46. Gasochromic α, β–Ni (OH)2 films for the determination of CO and chlorine content10.1016/j.snb.2017.01.062 ↗
47. Gasochromic effect of palladium doped peroxopolytungstic acid films prepared by the sol-gel route10.1016/S0925-4005(98)00241-X ↗
48. Gasochromic behavior of sol-gel derived Pd doped peroxopolytungstic acid (W-PTA) nano-composite films10.1023/A:1008773614398 ↗
49. Seeing hydrogen in colors: Low-cost and highly sensitive eye readable hydrogen detectors10.1002/adfm.201303065 ↗
50. Color change of V2O5 thin films upon exposure to organic vapors10.1016/j.solmat.2006.11.021 ↗
51. Metallo-porphyrin zinc as gas sensitive material for colorimetric gas sensors on planar optical waveguides10.1007/s00542-011-1412-x ↗
52. Polyoxometalate-based gasochromic silica10.1039/b801764f ↗
53. Color-changing microfiber-based multifunctional window screen for capture and visualized monitoring of NH310.1021/acsami.8b02516 ↗
54. Eye-readable gasochromic and electrical detectability of hydrogenated Pd-TiO2 to gaseous fluorine species10.1016/j.apsusc.2018.08.159 ↗
55. Gasochromic property of dehydrogenation-catalyst loaded tungsten trioxide10.1016/j.jpcs.2012.09.007 ↗
56. Gasochromic switching of reactively sputtered molybdenumoxide films: A correlation between film properties and deposition pressure10.1016/j.tsf.2006.03.045 ↗
57. Optical and photoelectric properties and colour centres in thin films of tungsten oxide10.1080/14786437308227562 ↗
58. Hydrogen detection based on coloration of anodic tungsten oxide film10.1063/1.106467 ↗
59. The gasochromic properties of sol-gel WO3 films with sputtered Pt catalyst10.1016/S0038-092X(00)00033-5 ↗
60. Gasochromic tungstenoxide films with PdCl2 solution as an aqueous hydrogen catalyst10.1016/j.solmat.2012.08.018 ↗
61. Gasochromic switching of tungsten oxide films: A correlation between film properties and coloration kinetics10.1016/S0040-6090(02)00496-0 ↗
62. Hydrogen sensing characteristics of an electrodeposited WO3 thin film gasochromic sensor activated by Pt catalyst10.1016/j.tsf.2007.07.055 ↗
63. Gasochromic effect in platinum-doped tungsten trioxide films prepared by the sol-gel method10.1023/A:1008645530803 ↗
64. IR spectroscopic investigations of gasochromic and electrochromic sol-gel-derived peroxotungstic acid/ormosil composite and crystalline WO3 films10.1023/A:1015147530846 ↗
65. The effect of operating temperature on gasochromic properties of amorphous and polycrystalline pulsed laser deposited WO3 films10.1016/j.snb.2012.04.082 ↗
66. Recent advances in optochemical sensors for the detection of H2, O2, O3, CO, CO2 and H2O in air10.1016/j.trac.2006.06.009 ↗
67. Hydrogen incorporation in gasochromic coloration of sol–gel WO3 thin films10.1016/j.snb.2011.05.008 ↗
68. Gasochromic effect and relative mechanism of WO3 nanowire films10.1088/0957-4484/18/20/205701 ↗
69. Flower-like nanostructures of WO3: Fabrication and characterization of their in-liquid gasochromic effect10.1016/j.snb.2015.11.044 ↗
70. Mechanism of the gasochromic coloration of porous WO3 films10.1016/S0167-2738(99)00273-8 ↗
71. Structural and gasochromic properties of epitaxial WO3 films prepared by pulsed laser deposition10.1016/j.nimb.2007.12.092 ↗
72. Hydrogen sensing by wet-gasochromic coloring of PdCl2 (aq)/WO3 and the role of hydrophilicity of tungsten oxide films10.1016/j.snb.2013.06.097 ↗
73. Pt and Pd as catalyst deposited by hydrogen reduction of metal salts on WO3 films for gasochromic application10.1016/j.apsusc.2013.02.027 ↗
74. Raman spectroscopic studies of gasochromic a-WO3 thin films10.1016/S0013-4686(01)00379-6 ↗
75. Highly sensitive gasochromic H2 sensing by nano-columnar WO3-Pd films with surface moisture10.1016/j.snb.2016.07.058 ↗
76. Fast coloration in sputtered gasochromic tungsten oxide films10.1002/pssa.200622159 ↗
77. Low-temperature chemical fabrication of Pt-WO3 gasochromic switchable films using UV irradiation10.1016/j.solmat.2017.05.058 ↗
78. 2-D WO3 decorated with Pd for rapid gasochromic and electrical hydrogen sensing10.1016/j.ijhydene.2017.05.172 ↗
79. Excimer laser treatment of TiO2/WO3 thin films for self-cleaning gasochromic applications: Preparation and characterization10.1016/j.solmat.2014.06.029 ↗
80. Hydrogen gas-sensing properties of Pt/WO3 thin film in various measurement conditions10.1007/s11581-012-0683-2 ↗
81. Green deposition of Pd nanoparticles on WO3 for optical, electronic and gasochromic hydrogen sensing applications10.1016/j.snb.2015.06.086 ↗
82. Low power-consumption CO gas sensors based on Au-functionalized SnO2-ZnO core-shell nanowires10.1016/j.snb.2018.04.079 ↗
83. Study of self-heating phenomenon and its resultant effect on ultrafast gasochromic coloration of Pt-WO3 nanowire films10.1016/j.snb.2012.07.120 ↗
84. Temperature dependence and degradation of gasochromic response behavior in hydrogen sensing with Pt/WO3 thin film10.1016/j.tsf.2014.02.080 ↗
85. Evidence of localized water molecules and their role in the gasochromic effect of WO3 nanowire films10.1021/jp903581s ↗
86. Study of the catalyst poisoning and reactivation of Pt nanoparticles on the surface of WO3 nanowire in gasochromic coloration10.1016/j.snb.2012.06.042 ↗
87. Fabrication of tungsten oxide nanofibers via electrospinning for gasochromic hydrogen detection10.1016/j.snb.2018.04.120 ↗
88. Optical H2 sensing properties of vertically aligned Pd/WO3 nanorods thin films deposited via glancing angle rf magnetron sputtering10.1016/j.snb.2013.03.091 ↗
89. Preparation and characterization of gasochromic Pt/WO3 hydrogen sensor by using the Taguchi design method10.1016/j.snb.2010.01.021 ↗
90. An ultra-fast response gasochromic device for hydrogen gas detection10.1016/j.snb.2013.06.004 ↗
91. Tandem gasochromic-Pd-WO3/graphene/Si device for room-temperature high-performance optoelectronic hydrogen sensors10.1016/j.carbon.2018.01.013 ↗
92. Influence of oxygen gas concentration on hydrogen sensing of Pt/WO3 thin film prepared by sol-gel process10.1016/j.snb.2015.04.020 ↗
93. Examination of the kinetics and performance of a catalytically switching (gasochromic) device10.1016/S0927-0248(98)00060-9 ↗
94. Electroless plating of palladium on WO3 films for gasochromic applications10.1016/j.solmat.2009.09.002 ↗
95. Effects of composition and structure on gasochromic coloration of tungsten oxide films investigated with XRD and RBS10.1016/j.nimb.2007.04.261 ↗
96. Pulsed laser deposition of (WO3)1-x (Nb2O5)x thin films: Characterization and gasochromic studies10.1016/j.tsf.2011.07.062 ↗
97. Pulsed laser deposition of W-V-O composite films: Preparation, characterization and gasochromic studies10.1016/j.solmat.2008.02.018 ↗
98. Palladium nanoparticle deposition onto the WO3 surface through hydrogen reduction of PdCl2: Characterization and gasochromic properties10.1016/j.solmat.2011.04.002 ↗
99. Pd2+ reduction and gasochromic properties of colloidal tungsten oxide nanoparticles synthesized by pulsed laser ablation10.1007/s00339-012-6899-1 ↗
100. Synthesis of monoclinic WO3 nanosphere hydrogen gasochromic film via a sol-gel approach using PS-b-PAA diblock copolymer as template10.1016/j.solidstatesciences.2010.05.016 ↗