journal article·2012-05-29Open access

Overview of the Development of the Fluoropolymer Industry

Hongxiang Teng

Applied Sciences· Volume 2· Issue 2

Abstract

The present review briefly describes the development of the fluoropolymer industry in the past 70 years. Discussed are industrial fluoropolymers including polytetrafluoroethylene, polychlorotrifluoroethylene, polyvinylidenefluoride, polyvinylfluoride, ETFE, ECTFE, FEP, PFA, THV, Teflon AF and Cytop. Nafion is included as a special functional fluoropolymer material. These industrial fluoropolymers are introduced in the order of their discovery or time of first production, included are their chemical structures, thermal properties, mechanical properties, electrical and electronic properties, optical properties, chemical resistance, oxidative stabilities, weather stabilities, processabilities and their general applications. The main manufacturing companies for the different types of fluoropolymer products are also mentioned.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Fuel Cells and Related Materials · Advanced Battery Materials and Technologies · Life Cycle Costing Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Polymer Research Institute, Department of Chemical and Biological Sciences, Polytechnic Institute of New York University, 6 Metrotech Center, Brooklyn, NY 11201, USA

References (42)

Show source-provided references
1. New industrial fluoropolymer science and technology10.1002/masy.19950980164 ↗
2. Salamone, J.C. (1996). Polymeric Materials Encyclopedia, CRC Press.
3. Scheirs, J. (1997). Modern Fluoropolymers, Wiley.
4. Hougham, G. (1999). Fluoropolymers, Kluwer Academic.10.1007/b114560 ↗
5. Ebnesajjad, S. (2002). Fluoroplastics, Plastic Design Library.
6. Ameduri, B., and Boutevin, B. (2004). Well-Architectured Fluoropolymers, Elsevier.
7. Drobny, J.G. (2008). Technology of Fluoropolymers, CRC Press. [2nd].10.1201/9781420063189 ↗
8. Fluoropolymers Division. Available online:http://www.fluoropolymers.org/index.htm.
9. Seymour, R.B., and Kirshenbaum, G.S. The History of Polytetrafluoroethylene: Discovery and Development. High Performance Polymers: Their Origin and Development, Proceed. Symp., High Performance Polymers at the ACS Meeting in New York, April 1986.10.1007/978-94-011-7073-4 ↗
10. Plunkett, R.J. (1941). Tetrafluoroethylene polymers. (2,230,654), U.S. Patent.
11. Gangal, S.V. (1989). Encyclopedia of Polymer Science and Engineering, John Wiley & Sons. [2nd].
12. Brasure, D.E., and Ebnesajjad, S. (1989). Encyclopedia of Polymer Science and Engineering, John Wiley & Sons. [2nd].
13. Dittman, A.L., and Wrightson, J.M. (1953). Manufacture of halocarbons. (2,636,908), U.S. Patent.
14. Daikin’s PCTFE equivalent to 3M’s Kel-F®. Available online:http://www.daikin-america.com/faq/default.aspx.
15. Ebnesajjad, S. (2002). Melt Processible Fluoroplastics: The Definitive User’s Guide and Data Book, Plastics Design Library, William Andrew Publishing; Elsevier.
16. Gangal, S.V., and Brothers, P.D. (2010). Encyclopedia of Polymer Science and Technology, Wiley Online Library.
17. England, D.C., Uschold, R.E., and Starkweather, H. (, 1982). Fluoropolymers: Their Development and Performance. Proceedings of the Robert A. Welch Foundation Conference on Chemical Research, XXVI, Houston, TX, USA.
18. Fluorine-containing polymers II. Polytetrafluoroethylene10.1007/BFb0050504 ↗
19. Recent advances in perfluorinated ionomer membranes10.1016/0376-7388(96)00155-X ↗
20. State of understanding of Nafion10.1021/cr0207123 ↗
21. Connolly, D.J., and Gresham, W.F. (1966). Fluorocarbon vinyl ether polymers. (3,282,875), U.S. Patent.
22. Perma Pure LLC. Available online:http://www.permapure.com/tech-notes/key-concepts/nafion-physical-and-chemical-properties/.
23. Proton and water transport in nano-separated polymer membrane10.1051/jp4:2000756 ↗
24. The morphology in Nafion perfluorinated membrane products, as determined by wide- and small-angle X-ray studies
25. Parallel cylindrical water nanochannels in Nafion fuel-cell membranes10.1038/nmat2074 ↗
26. Organic Synthesis by Catalysis with Ion-Exchange Resins10.1021/ie0580405 ↗
27. Nafion, Wikipedia. Available online:http://en.wikipedia.org/wiki/Nafion.
28. Ford, T.A. (1949). Copolymers of vinylidene fluoride. (2,468,054), U.S. Patent.
29. Bro, M.I. (1960). Polymerization of perfluorocarbon polymers. (2,952,669), U.S. Patent.
30. Berry, K.L. (1951). Aqueous colloidal dispersions of polymers. (2,559,752), U.S. Patent.
31. Carlson, D.P. (1986). Heat stable tetrafluoroethylene-perfluoro(alkyl vinyl ether) copolymers. (4,599,386), U.S. Patent.
32. Ford, T.A., and Hanford, W.E. (1948). Polyvinylidene fluoride and process. (2,435,537), U.S. Patent.
33. Resnick, P.R. (1975). Fluorinated dioxoles. (3,865,845), U.S. Patent.
34. Resnick, P.R. (1976). Polymers of fluorinated dioxoles. (3,978,030), U.S. Patent.
35. Nakamura, M., Kaneko, I., Oharu, K., Kojima, G., Matsuo, M., Samejuma, S., and Kamba, M. (1990). Novel fluorine-containing cyclic polymer. (4,897,457), U.S. Patent.
36. Nakamura, M., Unoki, M., Aosaki, K., and Yokotsuka, S. (, January June). Cyclized perfluoropolymer (CPFP) a low k dielectric for microelectronics device. IMC 1992 Proceedings, Yokohama, Japan.
37. Navarrini, W., Tortelli, V., Colaianna, P., and Abusleme, J. (1997). Perfluorodioxoles, the preparation process thereof, and homopolymers and copolymers obtained therefrom. (EP 0633257 B1), European Patent.
38. Scheirs, J. (1997). Modern Fluoroplastics, John Wiley and Sons.
39. Select the right fluoropolymers for your plant
40. Vedantam, S. (2001). Accumulating Teflon chemical raises environmental concern. Washington Post.
41. SPI: the plastics industry trade association. Available online:http://www.fluoropolymer-facts.com/PFOA/content.cfm?ItemNumber=4137&navItemNumber=4040.
42. (2005). The Guide to Safe Handling of Fluoropolymers Resins, The Society of Plastic Industry, Inc.. [4th].