journal article·2026-08

Structural, magnetic and theoretical investigations on the magnetocaloric properties inLa0.68Sm0.1K0.22Mn0.99O3-δ compound

R. Selmi, W. Cherif, L. Fernández Barquín, María de la Fuente, L. Ktari

Applied Physics A· Volume 132· Issue 8
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OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials · Advancements in Solid Oxide Fuel Cells

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References (62)

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1. H. Baaziza, A. Tozri, E. Dhahri, E.K. Hlil, Effect of particle size reduction on the magnetic phase transition and the magnetocaloric properties in ferromagnetic insulator La0.9Sr0.1MnO3 nanoparticles. Chem. Phys. Lett. 625, 168–173 (2015). https://doi.org/10.1016/j.cplett.2015.03.00410.1016/j.cplett.2015.03.004 ↗
2. Y. Xu, M. Meier, P. Das, M.R. Koblischka, U. Hartmann, Perovskite manganites: potential materials for magnetic cooling at or near room temperature. Cryst. Eng. 5, 383–389 (2002). https://doi.org/10.1016/S1463-0184(02)00049-710.1016/S1463-0184(02)00049-7 ↗
3. W. Kh. Abdouli, H. Cherif, M. Omrani, M.A. Mansouri, M.P.F. Valent, L. Graça, Ktari, Structural, magnetic and magnetocaloric properties of La0.5Sm0.2Sr0.3Mn1–xFexO3 compounds with (0 ≤ x ≤ 0.15). J. Magn. Magn. Mater. 475, 635–642 (2019). https://doi.org/10.1016/j.jmmm.2018. 12.00710.1016/j.jmmm.2018 ↗
4. L.H. Nguyen, L.X. Hung, N.X. Phuc, P.H. Nam, L.T.T. Ngan, N.V. Dang, L.V. Bau, P.H. Linh, P.T. Phong, Composites (1-x)La0.7Ca0.3MnO3/xLa0.7Sr0.2Ca0.1MnO3: Electrical transport properties and enhancing of low-field-magnetoresistance and colossal magnetoresistance. J. Alloys Compd. 849, 156607 (2020). https://doi.org/10.1016/j.jallcom.2020.15660710.1016/j.jallcom.2020.156607 ↗
5. M.K. Verma, N.D. Sharma, S. Sharma, N. Choudhary, D. Singh, High magnetoresistance in La0.5Nd0.15Ca0.25A0.1MnO3 (A = Ca, Li, Na, K) CMR manganites: correlation between their magnetic and electrical properties. J. Mater. Res. Bull. 125, 110813 (2020). https://doi.org/10.1016/j.materresbull.2020.11081310.1016/j.materresbull.2020.110813 ↗
6. N. Choudhary, M.K. Verma, N.D. Sharma, S. Sharma, D. Singh, Correlation between magnetic and transport properties of rare earth doped perovskite manganites La0.6R0.1Ca0.3MnO3 (R = La, Nd, Sm, Gd, and Dy) synthesized by Pechini process. Mater. Chem. Phys. 242, 122482 (2020). https://doi.org/10.1016/j.matchemphys.2019.12248210.1016/j.matchemphys.2019.122482 ↗
7. M. Khlifi, M. Bejar, O. El Sadek, E. Dhahri, M.A. Ahmed, E.K. Hlil, Structural, magnetic and magnetocaloric properties of the lanthanum deficient in La0.8Ca0.2–x□xMnO3 (x = 0-0.20) manganites oxides. J. Alloys Comp. 509, 7410–7415 (2011). https://doi.org/10.1016/j.jallcom.2011. 04.04910.1016/j.jallcom.2011 ↗
8. I.O. Troyanchuk, S.V. Trukhanov, H. Szymczak, K. Baerner, Effect of oxygen content on the magnetic and transport properties of Pr0.5Ba0.5MnO3−γ. J. Phys. Condens. Matter. 12, L155–L158 (2000)10.1088/0953-8984/12/7/103 ↗
9. Y. Xu, U. Memmert, U. Hartmann, Magnetic field sensors from polycrystalline manganites. Sens. Actuators A Phys. 91, 26–29 (2001). https://doi.org/10.1016/S0924-4247(01)00493-910.1016/S0924-4247(01)00493-9 ↗
10. V. Yunhui Xu, A. Dworak, U. Drechsler, Hartmann, Anisotropic low-field magnetoresistance of polycrystalline manganite sensors. Appl. Phys. Lett. 74, 2513 (1999). https://doi.org/10.1063/1.12302410.1063/1.123024 ↗
11. P. Shuk, L. Tichonova, U. Guth, Materials for electrodes based on rare earth manganites. Solid State Ion. 68, 177–184 (1994). https://doi.org/10.1063/1.12302410.1063/1.123024 ↗
12. I. Pallecchi, L. Pellegrino, A. Caviglia, E. Bellingeri, G. Canu, G.C. Gazzadi, A.S. Siri, D. Marré, Current-driven hysteresis effects in manganite spintronics devices. Phys. Rev. B 74, 014434 (2006). https://doi.org/10.1103/PhysRevB.74.01443410.1103/PhysRevB.74.014434 ↗
13. D. Mazumdar, K. Das, I. Das, Study of modification of the magnetic and magnetocaloric properties with Gd doping in Sm-Sr based manganite compounds: influence of short range charge-orbital ordering. J. Magn. Magn. Mater. 519, 167413 (2021). https://doi.org/10.1016/j.jmmm.2020.16741310.1016/j.jmmm.2020.167413 ↗
14. I.Z. Al-Yahmadi, A. Gismelssed, I.A. Abdel-Latif, F.A. Ma’Mari, A. Al-Rawas, S. Al-Harthi, I.A. Al-Omari, A. Yousf, H. Widatallah, M. ElZain, M.T.Z. Myint, Giant magnetocaloric effect and magnetic properties of nanocomposites of manganite Nd1–xSrxMnO3 (0.0 ≤ x ≤ 0.8) synthesized using modified sol-gel method. J. Alloys Comp. 857, 157566 (2021). https://doi.org/10.1016/j.jallcom.2020.15756610.1016/j.jallcom.2020.157566 ↗
15. E. Bouzaiene, A.H. Dhahri, J. Dhahri, E.K. Hlil, Structural, magnetic, magnetocaloric properties and critical behavior of La0.6Bi0.1Sr0.3–xCaxMn0.9Cu0.1O3 manganites (with x = 0.1 and 0.15). Inorg. Chem. Commun. 132, 108824 (2021). https://doi.org/10.1016/j.inoche.2021.10882410.1016/j.inoche.2021.108824 ↗
16. N. Mtiraoui, N. Dhouibi, J. Dhahri, O. Toulemonde, Magnetic and magnetocaloric properties in Nd1–3xBaxCaxSrxMnO3(x = 0.11and 0.133) perovskite manganites. J. Solid State Chem. 294, 121847 (2021). https://doi.org/10.1016/j.jssc.2020.12184710.1016/j.jssc.2020.121847 ↗
17. K. Dörr, Ferromagnetic manganites: spin-polarized conduction versus competing interactions. J. Phys. D: Appl. Phys.39 (7) (2006)10.1088/0022-3727/39/7/R01 ↗
18. V. Esposito, M. Fechner, R. Mankowsky, H. Lemke, M. Chollet, J.M. Glownia, M. Nakamura, M. Kawasaki, Y. Tokura, U. Staub, P. Beaud, M. Först, Nonlinear Electron-Phonon Coupling Doped Manganites Phys. Rev. Lett. 118, 247601 (2017). https://doi.org/10.1103/PhysRevLett10.1103/PhysRevLett ↗
19. Y. Lu, J. Klein, F. Herbstritt, J.B. Philipp, A. Marx, R. Gross, Effect of strain and tetragonal lattice distortions in doped perovskite manganites. Phys. Rev. B 73, 184406 (2006). https://doi.org/10.1103/PhysRevB.73.18440610.1103/PhysRevB.73.184406 ↗
20. L.P. Gor’kov, V.Z. Kresin, Mixed-valence manganites: fundamentals and main properties. Phys. Rep. 400(3), 149–208 (2004). https://doi.org/10.1016/j.physrep.2004. 08.00310.1016/j.physrep.2004 ↗
21. Y. Tokura, features of colossal magnetoresistive manganites. Rep. Prog Phys. 69, 797–851 (2006)10.1088/0034-4885/69/3/R06 ↗
22. E. Hernández, V. Sagredo, G.E. Delgado, Synthesis and magnetic characterization of LaMnO3 nanoparticles. Rev. Mex Fis. 61, 166–169 (2015)
23. P.G. de Gennes, Effects of Double Exchange in Magnetic Crystals Phys. Phys. Rev. 118, 141 (1960). https://doi.org/10.1103/PhysRev.118.14110.1103/PhysRev.118.141 ↗
24. S.B. Kansara, D. Dhruv, B. Kataria, C.M. Thaker, S. Rayaprol, C.L. Prajapat, M.R. Singh, P.S. Solanki, D.G. Kuberkar, N.A. Shah, J. Ceram. Int. 41(5), 7162–7173 (2015). https://doi.org/10.1016/j.ceramint.2015.02.03710.1016/j.ceramint.2015.02.037 ↗
25. M. Jeddi, J. Massoudi, H. Gharsallah, S.I. Ahmed, E. Dhahri, E.K. Hlil, Impact of potassium substitution on structural, magnetic, magnetocaloric and magneto-transport properties of Nd0.6Sr0.4–xKxMnO3 (0.0 ≤ x ≤ 0.2) manganite. J. Mater. Sci: Mater. Electron. 32, 18751–18764 (2021). https://doi.org/10.1007/s10854-021-06394-410.1007/s10854-021-06394-4 ↗
26. L. Pi, M. Hervieu, A. Maignan, C. Martin, B. Raveau, Structural and magnetic phase diagram and room temperature CMR effect of La1−xAgxMnO3. Solid State Commun. 126(4), 229–234 (2003). https://doi.org/10.1016/S0038-1098(02)00890-610.1016/S0038-1098(02)00890-6 ↗
27. S. Zhang, T. Sun, F. Ji, G. Dong, Y. Liu, Z. Li, H. Zhang, Q. Chen, X. Liu, Electrical and magnetic properties of La1–xAgxMnO3(0 ≤ x ≤ 0.5) polycrystalline ceramics by combination of first principles calculations and experimental methods. J. Alloys Comp. 808, 151709 (2019). https://doi.org/10.1016/j.jallcom.2019.15170910.1016/j.jallcom.2019.151709 ↗
28. K.Y. Pan, S.A. Halim, K.P. Lim, W.M. Daud, S.K. Chen, Effect of sintering temperature on microstructure, electrical and magnetic properties of La0.85K0.15MnO3 prepared by sol-gel method. J. Supercond. Nov. Magn. 25, 1177–1183 (2012). https://doi.org/10.1007/s10948-011-1392-110.1007/s10948-011-1392-1 ↗
29. S.K. Giri, A. Poddar, T.K. Nath, Surface spin glass and exchange bias effect in Sm0.5Ca0.5MnO3 manganite nanopar ticles. AIP Adv. 1, 032110 (2011). https://doi.org/10.1063/1.362342810.1063/1.3623428 ↗
30. F. Khammassi, L. Alfhaid, W. Chérif, A. Mendoza, O. Messaoudi, D. Salazar, A.S. Aljaloud, Structural and critical magnetic behavior in polycrystalline Sm0.47La0.20K0.33MnO3 manganite prepared via solid-state reaction. Appl. Phys. A 130, 515 (2024). https://doi.org/10.1007/s00339-024-07611-710.1007/s00339-024-07611-7 ↗
31. T. Roisnel, J. Rodriguez-Carvajal, C. Program, FULLPROF, LLB-LCSIM (2003)
32. H.M. Rietveld, A profile refinement method for nuclear and magnetic structures. J. Appl. Crystallogr. 2(2), 65–71 (1969). https://doi.org/10.1107/S002188986900655810.1107/S0021889869006558 ↗
33. J. Yang, Y.Q. Ma, B.C. Zhao, W.J. Lu, R. Ang, W.H. Song, Y.P. Sun, Structural, magnetic and transport properties in the manganites La0.7Sr0.3−xTexMnO3(0 ≤ x ≤ 0.15). Solid State Commun. 134(7), 443–447 (2005). https://doi.org/10.1016/j.ssc.2005.02.03010.1016/j.ssc.2005.02.030 ↗
34. C.B. Larsen, S. Samothrakitis, A.D. Fortes, A.O. Ayaş, M. Akyol, A. Ekicibil, M. Laver, Basal plane ferromagnetism in the rhombohedral manganite La0.85Ag0.15MnO3+δ. J. Magn. Magn. Mater. 498, 166192 (2005). https://doi.org/10.1016/j.jmmm.2019.1661910.1016/j.jmmm.2019.16619 ↗
35. R. Selmi, W. Cherif, A.R. Sarabando, N.M. Ferreira, L. Ktari, Enhanced relative cooling power of lanthanum-deficiency manganites La0.77–xMg0.23MnO3 (0 ≤ x ≤ 0.2): structural, magnetic and magnetocaloric properties. J. Mater. Sci: Mater. Electron. 33, 1703–1723 (2022). https://doi.org/10.1007/s10854-022-07726-810.1007/s10854-022-07726-8 ↗
36. K. Brandenburg, Diamond Version2.0 Impact Gbr, Bonn, Germany, 1998
37. A. Mabrouki, T. Mnasri, A. Bougoffa, A. Benali, E. Dhahri, M.A. Valente, Experimental study and DFT calculation of the oxygen deficiency effects on structural, magnetic and optical properties of La0.8□0.2MnO3–δ (δ = 0, 0.1 and 0.2) compounds. J. Alloys Comp. 860, 157922 (2021). https://doi.org/10.1016/j.jallcom.2020.15792210.1016/j.jallcom.2020.157922 ↗
38. I.A. Abdel-Latif, M.R. Ahmed, I.A. Al-Omari, A. Sellai, Electrical and magnetic transport in Strontium doped Europium Ferrimanganites. J. Magn. Magn. Mater. 420, 363–370 (2016). https://doi.org/10.1016/j.jmmm.2016.07.01610.1016/j.jmmm.2016.07.016 ↗
39. P.R. Spackman, M.J. Turner, J.J. McKinnon, S.K. Wolff, D.J.D. Grimwood, M.A. Jayatilaka, J. Spackman, CrystalExplorer: a program for Hirshfeld surface analysis, visualization and quantitative analysis of molecular crystals. J. Appl. Crystallogr. 54(3), 1006–1011 (2021). https://doi.org/10.1107/S160057672100291010.1107/S1600576721002910 ↗
40. R. Soman, S. Sujatha, S. De, V.C. Rojisha, P. Parameswaran, B. Varghese, C. Arunkumar, Eur. Inorg. Chem. 16, 2653–2662 (2014). https://doi.org/10.1002/ejic.20140 200810.1002/ejic.20140 ↗
41. M.N. Iliev, M.V. Abrashev, H.-G. Lee, V.N. Popov, Y.Y. Sun, C. Thomsen, R.L. Meng, C.W. Chu, Raman spectroscopy of orthorhombic perovskite like YMnO3 and LaMnO3. Phys. Rev. B 57, 2872 (1998)10.1103/PhysRevB.57.2872 ↗
42. N. Dodiya, D. Varshney, Structural properties and Raman spectroscopy of rhombohedral La1–xNaxMnO3 (0.075 ≤ x ≤ 0.15). J. Mol. Str. 1031, 104–109 (2013). https://doi.org/10.1016/j.molstruc.2012.07.03710.1016/j.molstruc.2012.07.037 ↗
43. M. Chebaane, R. Bellouz, M. Oumezzine, E.K. Hlil, A. Fouzri, Copper-doped lanthanum manganite La0.65Ce0.05Sr0.3Mn1−xCuxO3 influence on structural, magnetic and magnetocaloric effects. RSC Adv. 8, 7186 (2018). https://doi.org/10.1039/C7RA13244A10.1039/C7RA13244A ↗
44. R. Selmi, W. Cherif, L. FernandezBarquín, M. de la Fuente, L. Rodríguez, Ktari, Structure and spin glass behavior in La0.77Mg0.23–x□xMnO3 (0 ≤ x ≤ 0.2) manganites. J. Alloys Comp. 738, 528–539 (2018). https://doi.org/10.1016/j.jallcom.2017.12.18910.1016/j.jallcom.2017.12.189 ↗
45. H. Gharsallah, A. Souissi, M. Bejar, E. Dhahri, E.K. Hlil, Magnetic anisotropy and superparamagnetism in La0.6Ca0.4MnO3, La0.6Sr0.4MnO3 and their mixed composition 0.875 La0.6Ca0.4MnO3/0.125 La0.6Sr0.4MnO3, agglomerated at different temperatures. Mater. Chem. Phys. 182, 429–438 (2016). https://doi.org/10.1016/j.matchemphys.201610.1016/j.matchemphys.2016 ↗
46. D. Becker, Mechanochemical synthesis, phase transformation and surface functionalization of metal oxides. In Dissertation, Edit. Universität des Saarlandes (2020). https://doi.org/10.22028/D291-3215010.22028/D291-32150 ↗
47. F. Khammassi, L. Alfhaid, W. Chérif, A. Mendoza, O. Messaoudi, D. Salazar, A.S. Aljaloud, Structural and critical magnetic behavior in polycrystalline Sm0.47La0.20K0.33 MnO3 manganite prepared via solid-state reaction. Appl. Phys. A 130, 515 (2024). https://doi.org/10.1007/s00339-024-07611-710.1007/s00339-024-07611-7 ↗
48. D. Bhoi, N. Khan, A. Midya, M. Nandi, A. Hassen, P. Choudhury, P. Mandal, Formation of nanosize Griffiths-like clusters in solid solution of ferromagnetic manganite and cobaltite. J. Phys. Chem. C 117, 16658 (2013). https://doi.org/10.1021/jp402726f10.1021/jp402726f ↗
49. S. Banik, I. Das, Effect of A-site ionic disorder on magnetocaloric properties in large band width manganite systems. J. Alloys Compd. 742, 248–255 (2018). https://doi.org/10.1016/j.jallcom.2018.01.29510.1016/j.jallcom.2018.01.295 ↗
50. A. Gasmi, M. Boudard, S. Zemni, F. Hippert, M. Oumezzine, Influence of non-magnetic Ti4+ ion doping at Mn site on structural and magnetic properties of La0.67Ba0.33MnO3. J. Phys. D:Appl. Phys. 42, 225408–225414 (2009)10.1088/0022-3727/42/22/225408 ↗
51. S. Gupta, G. Sharma, V.R. Reddy, V.G. Sathe, V. Siruguri, Griffiths phase-like behavior and origin of spin-phonon interaction in Eu0.75Y0.25MnO3. J. Magn. Magn. Mater. 482, 38–43 (2019). https://doi.org/10.1016/j.jmmm.2019.03.05010.1016/j.jmmm.2019.03.050 ↗
52. F. Issaoui, M. Bejar, E. Dhahri, M. Bekri, P. Lachkar, E.K. Hlil, Crystal, spin glass, Griffiths phases and magneticaloric properties of the Sr1.5Nd0.5MnO4 compound. Phys. B 414, 42–49 (2013). https://doi.org/10.1016/j.physb.2012.12.03910.1016/j.physb.2012.12.039 ↗
53. S. Ghosh, S. Saha, A. Ahmed, A. Magar, M. Panda, R. Roy, R. Mondal, R. Nath, I. Das, T. Paramanik, Role of Fe-Mn interaction in developing cluster glass behaviour and Griffiths phase in ferrimagnetic Gd(Fe0.75Mn0.25)Si2. J. Alloys Compd. 1039, 182719 (2025). https://doi.org/10.1016/j.jallcom.2025.18271910.1016/j.jallcom.2025.182719 ↗
54. N. Marcano, E.M. Jefremovas, I. Titov, A. Michels, N.J. Steinke, J.H. Belo, J.P. Araújo, P.A. Algarabel, L. Fernández Barquín, Evolution at the nanoscale of magnetic clustering of the Griffiths-like phase in Tb4.925La0.075Si2Ge2. J. Alloys Compd. 1039, 182787 (2025). https://doi.org/10.1016/j.jallcom.2025.18278710.1016/j.jallcom.2025.182787 ↗
55. M.A. Hamad, Great magnetocaloric effect of La0.27Nd0.4Ca0.33MnO3. J. Supercond. Nov. Magn. 28(11), 3365–3369 (2015). https://doi.org/10.1007/s10948-015-3167-610.1007/s10948-015-3167-6 ↗
56. M. Abassi, J. Dhahri, E.K. Hlil, Theoretical work on magnetocaloric effect in La0.67Ba0.23Ca0.10Mn0.90Cr0.10O3 manganite. J. Supercond. Nov. Magn. 28(8), 2455–2459 (2015). https://doi.org/10.1007/s10948-015-3029-210.1007/s10948-015-3029-2 ↗
57. H. Gharsallah, M. Bejar, E. Dhahri, E.K. Hlil, L. Bessais, Prediction of magnetocaloriceffect in La0.6Ca0.4–xSrxMnO3 compounds for x = 0, 0.05 and 0.4 with phenomenological model. J. Ceram. Int. 42, 697–704 (2016). https://doi.org/10.1016/j.ceramint.2015. 08.16710.1016/j.ceramint.2015 ↗
58. V. Franco, J.S. Blázquez, J.J. Ipus, J.Y. Law, L.M. Moreno-Ramírez, A. Conde, Magnetocaloric effect: From materials research to refrigeration devices. Prog. Mater. Sci. 93, 112–232 (2018). https://doi.org/10.1016/j.pmatsci.2017.10.00510.1016/j.pmatsci.2017.10.005 ↗
59. M.A. Hamad, Theoretical work on magnetocaloric effect in La0.75Ca0.25MnO3. J. Adv. Ceram. 1, 290–295 (2012). https://doi.org/10.1007/s40145-012-0027-810.1007/s40145-012-0027-8 ↗
60. M. Ah. Dhahri, E. Jemmali, M.A. Dhahri, Valente, Structural characterization, magnetic, magnetocaloric properties and phenomenological model in manganite La0.75 Sr0.1Ca0.15MnO3 compound. J. Alloy Compd. 638, 221–227 (2015). https://doi.org/10.1016/j.jallcom.2015.01.31410.1016/j.jallcom.2015.01.314 ↗
61. M.A. HAMAD, Magnetocaloric effect in La1–xCexMnO3. J. Adv. Ceram. 4(3), 206–210 (2015). https://doi.org/10.1007/s40145-015-0150-410.1007/s40145-015-0150-4 ↗
62. A.D. Souza, M. Daivajna, Magnetocaloric Properties of NanostructuredLa0.7–xBixSr0.3MnO3(x = 0.0, 0.1) Manganites Using Phenomenological Model. J Supercond Nov Magn. 33, 1781–1788 (2020). https://doi.org/10.1007/s10948-02005428-y10.1007/s10948-02005428-y ↗