journal article·2026-07

Graphene derivatives as HTLs for Cu2MgSnS4 based solar cells

Nadia Mahsar, Beddiaf Zaidi, Lakhdar Dehimi, Fortunato Pezzimenti, Fatma Hadef

Applied Physics A· Volume 132· Issue 7
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OpenAlex topics: Chalcogenide Semiconductor Thin Films · Chemical and Physical Properties of Materials · Copper-based nanomaterials and applications

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References (66)

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1. M. Arif Dar, M. Satgunam, K. Mujasam Batoo, S. Kalpnan, P. Arularasan, U. Ali Dar, S. Suthakaran, L. Guganathan, A.A. Rather, M. Mishra, Majid. Future Photovoltaic Applications of Nanostructured Metal Chalcogenides. Comments Inorg. Chem. 45(6), 614–667 (2025). https://doi.org/10.1080/02603594.2025.246473210.1080/02603594.2025.2464732 ↗
2. D.L. Taesoo, U.E. Abasifrekem, A review of thin film solar cell technologies and challenges. Renew. Sustain. Energy Rev. 70(C), 1286–1297 (2017). https://doi.org/10.1016/j.rser.2016.12.02810.1016/j.rser.2016.12.028 ↗
3. A. Hammoud, B. Alhalaili, R. Vidu, N. Kamoun, Spray Pyrolysis Technique for Cu2MgSnS4 Thin Films. Mater. Sci. IntechOpen. (2024). https://doi.org/10.5772/intechopen.100956710.5772/intechopen.1009567 ↗
4. Y. Gang, Z. Xiaoli, L. Yongfeng, Y. Bin, D. Zhanhui, D. Rui, Z. Haifeng, Z. Ligong, Z. Zhenzhong, Synthesis and characterizations of Cu2MgSnS4 thin films with different sulfuration temperatures. Mater. Lett. 242, 58–61 (2019). https://doi.org/10.1016/j.matlet.2019.01.10210.1016/j.matlet.2019.01.102 ↗
5. S. Ashutosh, R.L. Trupti, S.K. Tripathy, SCAPS-1D Simulations for Comparative Study of Alternative Absorber Materials Cu. (X = Fe Mg Mn Ni Sr) CZTS-Based Solar Cells Micro Nanoelectronics Devices. 781, 329–337 (2021). https://doi.org/10.1007/978-981-16-3767-4_3110.1007/978-981-16-3767-4_31 ↗
6. A.C. Towhid, Numerical analysis to enhance efficiency of Cu2MgSnS4-based solar cell by inserting V2O5 back surface field. Phys. Scr. 100, 045951 (2025). https://doi.org/10.1088/1402-4896/adbdfa10.1088/1402-4896/adbdfa ↗
7. N. Mahsar, B. Zaidi, L. Dehimi, F. Pezzimenti, Performance evaluation of graphene, C60, and TiO2/graphene ETLs for Cu2MgSnS4 solar cells. Sol. Energy. 304, 114189 (2026). https://doi.org/10.1016/j.solener.2025.11418910.1016/j.solener.2025.114189 ↗
8. S. Rabhi, M.A. Benatallah, T. Hidouri, A.I. Shimul, B.C. Biswas, O.H. Alsalmi, H. Al Dmour, Alam. Machine learning-enhanced SCAPS optimization of 28.38%-efficient bifacial triple-cation perovskite solar cells for building integration. Surf. Interfaces. 91, 109216 (2026). https://doi.org/10.1016/j.surfin.2026.10921610.1016/j.surfin.2026.109216 ↗
9. S. Vaish, S.K. Dixit, O. Saidani, A. Yousfi, B. Joshi, Enhanced performance of lead-free tandem solar cells with CsSnCl3 perovskites: 44% power conversion efficiency. Next Energy. 11, 100594 (2026). https://doi.org/10.1016/j.nxener.2026.10059410.1016/j.nxener.2026.100594 ↗
10. M.S. Reza, A. Ghosh, N. Drissi, H. Al-Dmour, R.K. Prodhan, M.M. Islam, S. Begum, M.S. Reza, S. Sultana, Evaluation of design and device parameters for lead-free Sr3PBr3/Sr3NCl3 duel-layer perovskite photovoltaic device technology. RSC Adv. 14(49), 36675–36697 (2024). https://doi.org/10.1039/d4ra07912d10.1039/d4ra07912d ↗
11. N. Mahsar, B. Zaidi, L. Dehimi, A. Barkhordari, F. Hadef, The performance of Cu2MnSnS4 based solar cells with CZTS as hole transport nanolayer. Sci. Rep. 15, 26774 (2025). https://doi.org/10.1038/s41598-025-12766-110.1038/s41598-025-12766-1 ↗
12. S. K.Zeghdar, L. Mansouri, F. Dehimi, H.A. Pezzimenti, A.M.S. Magda, J.R. Alhuthali, J.R. Chaitany, M.K. Balachandran, Hossain, Optimizing photovoltaic efficiency CZTS solar cells by investigating the role of different advanced materials as back surface field layer. Sci. Rep. 15, 25294 (2025). https://doi.org/10.1038/s41598-025-10958-310.1038/s41598-025-10958-3 ↗
13. A.K. Kang, M.H. Zandi, N.E. Gorji, Simulation analysis of graphene contacted perovskite solar cells using SCAPS-1D. Opt. Quant. Electron. 51(91) (2019). https://doi.org/10.1007/s11082-019-1802-310.1007/s11082-019-1802-3 ↗
14. D. Davis, K. Sudheer, Graphene Oxide and Reduced Graphene Oxide as Hole Transport Layers for Improved Efficiency in Fullerene-Based Bulk Heterojunction Organic Solar Cells: A Numerical Simulation Study. East. Eur. J. Phys. 1, 217–232 (2025). https://doi.org/10.26565/2312-4334-2025-1-2310.26565/2312-4334-2025-1-23 ↗
15. G.A. Nowsherwan, A. Samad, M.A. Iqbal, T. Mushtaq, A. Hussain, M. Malik, S. Haider, P.V. Pham, J.R. Choi, Performance Analysis and Optimization of a PBDB-T:ITIC Based Organic Solar Cell Using Graphene Oxide as the Hole Transport Layer. Nanomaterials. 12, 1767 (2021). https://doi.org/10.3390/nano1210176710.3390/nano12101767 ↗
16. K.K. Ezwan, A.J. Nabilah, F. Salehuddin, F. Arith, M. Zain, A. Suhaila, A. Ibrahim, M. Junos, S. Aisah, H. Afifah, Optimal modeling of perovskite solar cell with graphene oxide as hole transport layer using L32 (28) Taguchi design. Int. J. Nanoelectronics Mater. (IJNeaM). 17, 23–30 (2024). https://doi.org/10.58915/ijneam.v17i1.44810.58915/ijneam.v17i1.448 ↗
17. A. Najim, L. Moulaou, A. Laassouli, Design and simulation of an organic-inorganic GO/P3HT/MASnI3 solar cell using the SCAPS-1D program. Electr. Eng. 107, 7657–7671 (2025). https://doi.org/10.1007/s00202-024-02941-410.1007/s00202-024-02941-4 ↗
18. S.A. Alshomrany, F.J. Rasheed, M.H.J. Mohsenah, A. Thamraa, A.S. Kashif, K. Firoz, Role of Reduced Graphene Oxide in Achieving High Efficiency of All-Inorganic Perovskite Solar Cells: An Experimental and Numerical Investigation. Energy Fuels. 39, 828–842 (2025). https://doi.org/10.1021/acs.energyfuels.4c0465510.1021/acs.energyfuels.4c04655 ↗
19. A. Kumar, M.I. Sayyed, D. Punina, E. Naranjo, E. Jácome, M.K. Abdulameer, H.Z. Albazoni, Z. Shariatinia, Graphene quantum dots (GQD) and edge-functionalized GQDs as hole transport materials in perovskite solar cells for producing renewable energy: a DFT and TD-DFT study. RSC Adv. 13, 29163–29173 (2023). https://doi.org/10.1039/D3RA05438A10.1039/D3RA05438A ↗
20. P. Shangzheng, Z. Chunfu, Z. Hairong, D. Hang, C. Dazheng, Z. Weidong, X. He, C. Jingjing, L. Zhenhua, Z. Jincheng, H. Yue, Boosting performance of perovskite solar cells with Graphene quantum dots decorated SnO2 electron transport layers. Appl. Surf. Sci. 507, 145099 (2020). https://doi.org/10.1016/j.apsusc.2019.14509910.1016/j.apsusc.2019.145099 ↗
21. L. Miaomiao, N. Wang, K. Bin, W. Xiangjian, Z. Long, Z. Qian, L. Guankui, Z. Yi, C. Yongsheng, Graphene quantum dots as the hole transport layer material for high-performance organic solar cells. Phys. Chem. Chem. Phys. 15, 18973–18978 (2013)10.1039/c3cp53283f ↗
22. M. Saifee, A. Feroz, K. Fareha, A. Javid, K. Mohammad, K. Mohd, Graphene quantum dots as hole transport material in lead free perovskite solar cell: a SCAPS-1D numerical study. Eng. Res. Express. 7, 015003 (2025). https://doi.org/10.1088/2631-8695/ada7c210.1088/2631-8695/ada7c2 ↗
23. S.M. Amanullah, K.M. Shahid, A. Javid, A. Ahsaan, K. M. Ajmal. Performance Optimization of Lead-Free KGeCl3 Solar Cells Using SCAPS-1D and Stacked Machine Learning Models. (2026). https://doi.org/10.2139/ssrn.622865910.2139/ssrn.6228659 ↗
24. S. Ghosh, S. Yasmin, J. Ferdous, B.B. Saha, Numerical Analysis of a CZTS Solar Cell with MoS2 as a Buffer Layer and Graphene as a Transparent Conducting Oxide Layer for Enhanced Cell Performance. Micromachines. 13, 1249 (2022). https://doi.org/10.3390/mi1308124910.3390/mi13081249 ↗
25. S. Erkan, A. Yagmyrov, A. Altuntepe, R. Zan, M.A. Olgar, Integration of single layer graphene into CZTS thin film solar cells. J. Alloys Compd. 920, 166041 (2022). https://doi.org/10.1016/j.jallcom.2022.16604110.1016/j.jallcom.2022.166041 ↗
26. D. Fatihi, G. Tseberlidis, V. Trifiletti, S. Binetti, E. Isotta, P. Scardi, A. Kamal, R. Adhiri, N. Ataollahi, Enhanced Efficiency of CZTS Solar Cells with Reduced Graphene Oxide and Titanium Dioxide Layers: A SCAPS Simulation Study. Chem. Eng. 9, 38 (2025). https://doi.org/10.3390/chemengineering902003810.3390/chemengineering9020038 ↗
27. W.L. Jeong, S.H. Park, Y.D. Jho, S.K. Joo, D.S. Lee, The Role of the Graphene Oxide (GO) and Reduced Graphene Oxide (RGO) Intermediate Layer in CZTSSe Thin-Film Solar Cells. Materials. 15, 3419 (2022). https://doi.org/10.3390/ma1510341910.3390/ma15103419 ↗
28. Y. Liu, Y. Sun, A. Rockett, A new simulation software of solar cells-wxAMPS. Solar Energy Mater. Solar Cells. 98, 124–128 (2012). https://doi.org/10.1016/j.solmat.2011.10.01010.1016/j.solmat.2011.10.010 ↗
29. A. Shakoor, G.A. Nowsherwan, M. Aamir, A. Ahmar, S. Rehman, W. Alam, M. Yasir, K. Arif, M. Ahmad, Y. Jamal. Performance Evaluation of Solar Cells by Different Simulating Softwares. Intech (2023). https://doi.org/10.5772/intechopen.11163910.5772/intechopen.111639 ↗
30. P.A. Sehrawat, S.S. Islam, Reduced graphene oxide (rGO) based wideband optical sensor and the role of Temperature, Defect States and Quantum Efficiency. Sci. Rep. 8, 3537 (2018). https://doi.org/10.1038/s41598-018-21686-210.1038/s41598-018-21686-2 ↗
31. Y. Wang, Y. Chen, S.D. Lacey, X. Lisha, H. Xie, L. Tian, V.A. Danner, L. Hu, Reduced graphene oxide film with record-high conductivity and mobility. Mater. Today. 21, 186–192 (2018). https://doi.org/10.1016/j.mattod.2017.10.00810.1016/j.mattod.2017.10.008 ↗
32. M. Panachikkool, E.T. Aparna, P. Asaithambi, Design and numerical simulation of CuBi2O4 solar cells with graphene quantum dots as hole transport layer under ideal and non-ideal conditions. Sci. Rep. 15, 100 (2025). https://doi.org/10.1038/s41598-024-83700-010.1038/s41598-024-83700-0 ↗
33. N.Tashtoush, O. Kasasbeh, Optical properties of vanadium pentoxide thin films prepared by thermal evaporation method. Jordan J. Pharm. Sci. 6, 7–15 (2025). https://jjp.yu.edu.jo/index.php/jjp/article/view/880
34. G.G. Politano, C. Versace, Electrical and Optical Characterization of Graphene Oxide and Reduced Graphene Oxide Thin Films. Crystals. 12, 1312 (2022). https://doi.org/10.3390/cryst1209131210.3390/cryst12091312 ↗
35. R. Biswal, B. Khan, M.K. Singh, Synthesis, optical, dielectric, and magneto-dielectric properties of graphene quantum dots (GQDs). J. Mater. Res. 37, 3459–3469 (2022). https://doi.org/10.1557/s43578-022-00717-910.1557/s43578-022-00717-9 ↗
36. A. Yousfi, O. Saidani, Y. Belhadad, R. Zouache, A. Brahimi, S. Bhattarai, Sahoo. Leveraging machine learning for the design and optimization of environmentally friendly K2CuCrCl6 perovskite solar cells. Mater. Sci. Engineering: B 323, 118697 (2026). https://doi.org/10.1016/j.mseb.2025.11869710.1016/j.mseb.2025.118697 ↗
37. F. Azri, A. Meftah, N. Sengouga, A. Meftah, Electron and hole transport layers optimization by numerical simulation of a perovskite solar cell. Sol. Energy. 181, 372–378 (2019). https://doi.org/10.1016/j.solener.2019.02.01710.1016/j.solener.2019.02.017 ↗
38. S.A. Ansari, Graphene Quantum Dots: Novel Properties and Their Applications for Energy Storage Devices. Nanomaterials. 12, 21 (2022). https://doi.org/10.3390/nano1221381410.3390/nano12213814 ↗
39. N.P. Ngidi, M.A. Ollengo, V.O. Nyamori, Effect of Doping Temperatures and Nitrogen Precursors on the Physicochemical, Optical, and Electrical Conductivity Properties of Nitrogen-Doped Reduced Graphene Oxide. Materials. 12, 20 (2019). https://doi.org/10.3390/ma1220337610.3390/ma12203376 ↗
40. R. Atowar, Enhancing the photovoltaic performance of Cd-free Cu2ZnSnS4 heterojunction solar cells using SnS HTL and TiO2 ETL. Solar Energy. 2015, 64–76 (2021). https://doi.org/10.1016/j.solener.2020.12.02010.1016/j.solener.2020.12.020 ↗
41. A. Sunny, S. Rahman, M.M. Khatun, S. Rashel Al, Ahmed, Numerical study of high performance HTL-free CH3NH3SnI3 based perovskite solar cell by SCAPS-1D. AIP Adv. 11, 065102 (2021). https://doi.org/10.1063/5.004964610.1063/5.0049646 ↗
42. S.P. Cho, G. Han, Y.H. Seo, Y.J. Noh, J.Y. Sohn, I.T. Hwang, J. Shin, C.H. Jung, S.I. Na, Highly-dispersible reduced graphene oxide/polymer nanocomposites as efficient hole-transporting materials for perovskite solar cells. Compos. Sci. Technol. 201, 108548 (2021). https://doi.org/10.1016/j.compscitech.2020.10854810.1016/j.compscitech.2020.108548 ↗
43. K. Sornek, W. Goryl, R. Figaj, G. Dąbrowska, J. Brezdeń, Development and Tests of the Water Cooling System Dedicated to Photovoltaic Panels. Energies. 15, 5884 (2022). https://doi.org/10.3390/en1516588410.3390/en15165884 ↗
44. I. Qasim, O. Ahmad, A. Rashid, Numerical optimization of (FTO/ZnO/CdS/CH3NH3SnI3/GaAs/Au) perovskite solar cell using solar capacitance simulator with efficiency above 23% predicted. Opt. Quant. Electron. 53, 713 (2021). https://doi.org/10.1007/s11082-021-03361-510.1007/s11082-021-03361-5 ↗
45. A.K. Sharma, N.K. Chourasia, P.K. Jha, Characteristic Features and Performance Investigations of a PTB7:PC71BM/PFN:Br Pure Organic Solar Cell Using SCAPS-1D. J. Electron. Mater. 52, 4302–4311 (2023). https://doi.org/10.1007/s11664-022-10202-y10.1007/s11664-022-10202-y ↗
46. T. Ouslimane, L. Et-taya, L. Elmaimouni, A. Benami, Impact of absorber layer thickness, defect density, and operating temperature on the performance of MAPbI3 solar cells based on ZnO electron transporting material. Heliyon. 7, e06379 (2021). https://doi.org/10.1016/j.heliyon.2021.e0637910.1016/j.heliyon.2021.e06379 ↗
47. Z, Cheng, Relation between structural defects and trap states in graphene quantum dots perovskite solar cell. Appl. Comput. Eng. 7, 24–28 (2023). https://doi.org/10.54254/2755-2721/7/2023031910.54254/2755-2721/7/20230319 ↗
48. Y. Zhong, H. Zhang, D. Pan, L. Wang, X. Zhong, Graphene quantum dots assisted photovoltage and efficiency enhancement in CdSe quantum dot sensitized solar cells. J. Energy Chem. 24(6), 722–728 (2015). https://doi.org/10.1016/j.jechem.2015.10.00610.1016/j.jechem.2015.10.006 ↗
49. A. Saltelli, M. Ratto, T. Andres, F. Campolongo, J. Cariboni, D. Gatelli, M. Saisana, Tarantola. Global sensitivity analysis: the primer. Wiley. 304(4) (2008). https://doi.org/10.1002/9780470725184.ch610.1002/9780470725184.ch6 ↗
50. O. Benedict, L. Jaseun, Y. Minjun, S. Changwoo, Z. Jian-Min, I. Adesida, Au, Semicond. Sci. Technol. 29, 095005 (2014). https://doi.org/10.1088/0268-1242/29/9/095005. and Ni/Pt/Au Schottky contacts on AlGaN/GaN heterostructures10.1088/0268-1242/29/9/095005 ↗
51. P. Sawicka-Chudy, Z. Starowicz, G. Wisz, R. Yavorskyi, Z. Zapukhlyak, M. Bester, L. Głowa, M. Sibiński, Cholewa. Simulation of TiO2/CuO solar cells with SCAPS-1D software. Mater. Res. Express. 6, 085918 (2019). https://doi.org/10.1088/2053-1591/ab22aa10.1088/2053-1591/ab22aa ↗
52. P. Malkeshkumar, R. Abhijit, Enhancement of output performance of Cu2ZnSnS4 thin film solar cells-A numerical simulation approach and comparison to experiments. Phys. B: Condens. Matter. 407, 4391–4397 (2012). https://doi.org/10.1016/j.physb.2012.07.04210.1016/j.physb.2012.07.042 ↗
53. M. Panachikkool, E.T. Aparna, P. Asaithambi, Design and numerical simulation of CuBi2O4 solar cells with graphene quantum dots as hole transport layer under ideal and non-ideal conditions. Sci. Rep. 15, 100 (2025). https://doi.org/10.1038/s41598-024-83700-010.1038/s41598-024-83700-0 ↗
54. M.A. Hasan, T.S. C.Suhi, Hossain. Highly Stable Perovskite Solar Cells Using Graphene and its Derivatives: A Review. Adv. Mater. Interfaces. 13, e00855 (2025). https://doi.org/10.1002/admi.20250085510.1002/admi.202500855 ↗
55. S. Yadav, S.K. Gupta, C.M.S. Negi, Graphene derivatives as efficient hole transport materials for lead-free double perovskite (Cs2SnI6) solar cells: a numerical study. Optoelectron. Lett. 21, 155–159 (2025). https://doi.org/10.1007/s11801-025-4020-110.1007/s11801-025-4020-1 ↗
56. Z.A. Mahmoud, H.N.K. AL-Salman, H.H. Hussein, High-performance TiO2/perovskite solar cell based GO as hole transport layer. J. Mater. Sci: Mater. Electron. 35, 1311 (2024). https://doi.org/10.1007/s10854-024-12998-310.1007/s10854-024-12998-3 ↗
57. T. Titu, Numerical study on the effect of graphene oxide as hole transporting layer in caesium based perovskite solar cell-scaps 1D approach. ECS Meeting Abstracts. MA2022-02, 16 (2022). https://doi.org/10.1149/MA2022-0216842mtgabs10.1149/MA2022-0216842mtgabs ↗
58. S. Pramanik, K. Majumder, A. Chandra, A. Sett, N. Burman, D. Kumar, Numerical Simulation of Tin-Based Perovskite Solar Cell Incorporating 2D Graphene Derivatives as Hole Transport Layer: Optimization of Absorber Layer. Book. (2025). https://doi.org/10.1109/DevIC63749.2025.1101218010.1109/DevIC63749.2025.11012180 ↗
59. D. Fatihi, G. Tseberlidis, V. Trifiletti, S. Binetti, E. Isotta, P. Scardi, A. Kamal, R. Adhiri, N. Ataollahi, Enhanced Efficiency of CZTS Solar Cells with Reduced Graphene Oxide and Titanium Dioxide Layers: A SCAPS Simulation Study. ChemEngineering. 9(2), 38 (2025). https://doi.org/10.3390/chemengineering902003810.3390/chemengineering9020038 ↗
60. E. Jokar, Z.Y. Huang, S. Narra, C.Y. Wang, V. Kattoor, C.C. Chung, E.W.G. Diau, Anomalous Charge-Extraction Behavior for Graphene-Oxide (GO) and Reduced Graphene-Oxide (rGO) Films as Efficient p-Contact Layers for High-Performance Perovskite Solar Cells. Adv. Energy Mater. 8, 1701640 (2018). https://doi.org/10.1002/aenm.20170164010.1002/aenm.201701640 ↗
61. A. Kumar, S. Chand, Synthesis and investigation of optical and high-temperature conduction mechanism of pure and S-GQDs thin films as a transparent conducting material. J. Mater. Sci: Mater. Electron. 36, 1834 (2025). https://doi.org/10.1007/s10854-025-15899-110.1007/s10854-025-15899-1 ↗
62. F.V. Kusmartsev, W.M. Wu, M.P. Pierpoint, K.C. Yung, Application of graphene within optoelectronic devices and transistors. In: Misra, P. (eds) Applied Spectroscopy and the Science of Nanomaterials. Progress in Optical Science and Photonics. vol. 2, pp. 191–221(2015). https://doi.org/10.1007/978-981-287-242-5_910.1007/978-981-287-242-5_9 ↗
63. A. Gutiérrez-Cruz, A.R. Ruiz-Hernández, J.F. .Vega-Clemente, A review of top-down and bottom-up synthesis methods for the production of graphene, graphene oxide and reduced graphene oxide. J. Mater. Sci. 57, 14543–14578 (2022). https://doi.org/10.1007/s10853-022-07514-z10.1007/s10853-022-07514-z ↗
64. S. Mahalingam, A. Manap, K.S. Lau, A. Omar, P. Chelvanathan, C.H. Chia, N. Amin, I.J. Mathews, N.F. Afandi, N.A. Rahim, Mixture deposition method for graphene quantum dots-based dye-sensitized solar cell. Electrochim. Acta. 404, 139732 (2022). https://doi.org/10.1016/j.electacta.2021.13973210.1016/j.electacta.2021.139732 ↗
65. M.A. Hasan, T.S. C.Suhi, Highly stable perovskite solar cells using graphene and its derivatives: a review. Adv. Mater. Interfaces. 13(1) (2026). https://doi.org/10.1002/admi.202500855. e0085510.1002/admi.202500855 ↗
66. W. Wu, J. Zhang, W. Shen, M. Zhong, S. Guo, Graphene Quantum Dots Band Structure Tuned by Size for Efficient Organic Solar Cells. Phys. Status Solidi A 216, 1900657 (2019). https://doi.org/10.1002/pssa.20190065710.1002/pssa.201900657 ↗