Composite cathode design for intermediate-temperature SOFCs: Ba0.5Sr0.5Co0.8Fe0.2O3−δ-Ce0.8Gd0.2O2−δ thermal compatibility
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OpenAlex topics: Advancements in Solid Oxide Fuel Cells · Thermal Expansion and Ionic Conductivity · Magnetic and transport properties of perovskites and related materials
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References (49)
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1. N. Li, B. Liu, L. Jia, D.Y.J. Li, Liquid biofuels for solid oxide fuel cells: A review. J. Power Sources. 556, 232437 (2023)10.1016/j.jpowsour.2022.232437 ↗
2. H. Ling, D.Z.X. Zhu, N. Wang, J. Bai, H. Gong, Y. Zhang, Y. Chen, W. Yan, Qiurong Zhu, A high-performance composite cathode based on thermal expansion complementation for SOFC, Fuel 362, 130864 (2024)
3. B.K. Kang, H.C. Lee, Y.W. Heo, J.J. Kim, J.Y. Kim, J.H. Lee, Thermal expansion behavior of La-doped (Ba0.5Sr0.5Co0.8Fe0.2)O3-Cathode material, Ceram. Int. 39, 8267–8271 (2013)
4. -I. Jae, S.T. Jung, D.D. Misture, Edwards, Oxygen stoichiometry, electrical conductivity, and thermo-power measurements of BSCF (Ba0.5Sr0.5CoxFe1–xO3–δ, 0 ≤ x ≤ 0.8) in air. Solid State Ion. 181, 1287–1293 (2010)10.1016/j.ssi.2010.06.033 ↗
5. H. K. Hieu, L. T. Lam, New insights into the dopant size-ionic transport relationship for Ln2O3-doped Ceria (Ln = Yb, Er, Ho, Y. Dy, Gd, Eu, Sm, Nd, and La) electrolytes through statistical moment calculations, Mat. Sci. Semicon. Proc. 190, 109317 (2025)10.1016/j.mssp.2025.109317 ↗
6. Z. Yihang Dong, G. Liu, L. Qiu, Y. Pang, S. Han, J. Yao, X. Ding, Wang, Thermal behavior, crystal structure and electrical conductivity of {(ZrO2)0.92(Y2O3)0.08}1–x(Cr2O3)x (x = 0, 0.05, 0.10, 0.15) solid solution, Mat. Sci. Semicon. Proc. 137, 106208 (2022)10.1016/j.mssp.2021.106208 ↗
7. G. Mtabazi, B.S. Sahini, Mwankemwa, Nikola Kanas, BaxSr1–xCoyFe1–yO3–δ (BSCF) mixed ionic-electronic conducting (MIEC) materials for oxygen separation membrane and SOFC applications: Insights into processing, stability, and functional properties. Ceram. Int. 48, 2948 (2022)10.1016/j.ceramint.2021.10.189 ↗
8. T. Nilam Shah, X. Zhu, H. Xu, Z. Wang, L. Zhu, Ge, Synergistic thermal expansion reduction in cobalt-containing perovskite cathodes for solid oxide fuel cells. J. Power Sources. 654, 237832 (2025)10.1016/j.jpowsour.2025.237832 ↗
9. L. Wu, J. Sun, H. Qi, B. Tu, C. Xiong, F. Chen, P. Qiu, Boosting steam tolerance and electrochemical performance of an La0.6Sr0.4Co0.2Fe0.8O3–δ-based air electrode for protonic ceramic electrochemical cells,J. Mater. Chem. A 12, 25979 (2024)10.1039/D4TA03706E ↗
10. X. Jing Chen, D. Yang, B. Wan, L. Li, T. Lei, B. Tian, F. Chi, Chen, Novel structured Sm0.5Sr0.5CoO3–δ cathode for intermediate and low temperature solid oxide fuel cells. Electrochim. Acta. 341, 136031 (2020)10.1016/j.electacta.2020.136031 ↗
11. P. Wang, L. Yao, M. Wang, W. Wu, XPS and voltammetric studies on La1–xSrxCoO3-δ perovskite oxide electrodes. J. Alloys Compd. 311, 53–56 (2000)10.1016/S0925-8388(00)00860-4 ↗
12. M.-V. Le, D.-S. Tsai, Tuan-Anh Nguyen,BSCF/GDC as a refined cathode to the single-chamber solid oxide fuel cell based on a LAMOX electrolyte, Ceram. Int. 44, 1726–1730 (2018)
13. A. Santosh Chauhan, S.K. Chandra, Jaiswal, X-ray photoelectron spectra, conductivity, and oxygen permeation characteristics of (Ba0.5Sr0.5)(Fe1–xCex)O3–δ (x = 0–1.0) perovskites. Mat. Chem. Phys. 297, 127408 (2023)10.1016/j.matchemphys.2023.127408 ↗
14. C.S. Devi, G. Prasad, Development of Nano-Structured and Nano Porous BSCF Cathode for Low Temperature Solid Oxide Fuel Cell Application. Trans. Indian Ceram. Soc. 77, 1–6 (2018)
15. Q. Zhou, F. Wang, Y. Shen, Performances of LnBaCo2O5+x-Ce0.8Sm0.2O1.9 composite cathodes for intermediate-temperature solid oxide fuel cells. J. Power Sources. 195, 2174–2181 (2010)10.1016/j.jpowsour.2009.10.062 ↗
16. A. Petric, P. Huang, F. Tietz, Evaluation of La-Sr-Co-Fe-O perovskites for solid oxide fuel cells and gas separation membranes. Solid State Ion. 135, 719–725 (2000)10.1016/S0167-2738(00)00394-5 ↗
17. S. Li, Z.L.B. Wei, X. Huang, J. Miao, G. Cao, R. Zhu, WenhuiSu, A study of (Ba0.5Sr0.5)1–xSmxCo0.8Fe0.2O3–δ as a cathode material for IT-SOFCs. J. Alloys Compd. 426, 408–414 (2006)10.1016/j.jallcom.2006.02.040 ↗
18. Z. Xin, C. Yang, C. Yang, J. Li, B. Chi, Self-assembled cathode induced by polarization for high performance solid oxide fuel cell. J. Mater. Chem. A 11, 1785–1792 (2023)10.1039/D2TA08525A ↗
19. C.S. Devi, G. Prasad, Development of Nano-Structured and Nano-Porous BSCF Cathode for Low Temperature Solid Oxide Fuel Cell Application. Trans. Indian Ceram. Soc. 77, 67–72 (2018)10.1080/0371750X.2018.1452633 ↗
20. H. Xianzhong, J. Chen, Q. Lin, A.A. Konnov, Experimental and kinetic modeling study of the laminar burning velocity of CH4/H2 mixtures under oxy-fuel conditions. Fuel. 376, 132597 (2024)10.1016/j.fuel.2024.132597 ↗
21. Chen, N. Mu, C. Chen, B. Li, A novel Gd2O3–Al2O3–SiO2 glass-ceramics substrate material with comprehensive performance. Ceram. Int. 50, 26382–26390 (2024)10.1016/j.ceramint.2024.04.303 ↗
22. J.I. Jung, S.T. Misture, D.D. Edwards, Oxygen stoichiometry, electrical conductivity, and thermopower measurements of BSCF (Ba₀.₅Sr₀.₅CoₓFe₁–ₓO₃–δ). Solid State Ionics. 181, 1287–1293 (2010)10.1016/j.ssi.2010.06.033 ↗
23. M.G. Sahini, B.S. Mwankemwa, N. Kanas, BSCF mixed ionic–electronic conducting materials for oxygen separation membranes and SOFC cathodes: A review. Ceram. Int. 48, 2948–2960 (2022)10.1016/j.ceramint.2021.10.189 ↗
24. Q.L. Liu, K.A. Khor, S.H. Chan, High-performance low-temperature solid oxide fuel cell with novel BSCF cathode. J. Power Sources. 161, 123–128 (2006)10.1016/j.jpowsour.2006.03.095 ↗
25. A. Petric, P. Huang, F. Tietz, Evaluation of La–Sr–Co–Fe–O perovskites for SOFC applications. Solid State Ionics. 135, 719–725 (2000)10.1016/S0167-2738(00)00394-5 ↗
26. Q. Zhou, F. Wang, Y. Shen, T. He, Performance of composite cathodes for intermediate-temperature SOFCs. J. Power Sources. 195, 2174–2181 (2010)10.1016/j.jpowsour.2009.10.062 ↗
27. L. Hu, D. Zhou, X. Zhu, N. Wang, J. Bai, H. Gong, Y. Zhang, Y. Chen, W. Yan, Q. Zhu, High-performance composite cathode based on thermal expansion complementation for SOFC. Fuel. 362, 130864 (2024)10.1016/j.fuel.2024.130864 ↗
28. K. Chen, H. Yang, Z. Chen, J. Huang, J. Qian, Z. Yue, L. Zhang, C. Guan, X. Wang, Y. Shao, S.P. Jiang, N. Ai, Stable operation of BSCF-based composite cathodes for intermediate-temperature SOFCs. Ceram. Int. 50, 46822 (2024)10.1016/j.ceramint.2024.09.033 ↗
29. C.S. Devi, K.K. Katta, N. Chanakya, G. Prasad, Upender, Gd3+ and Sm3+ doped CeO2 for IT-SOFC and room temperature formaldehyde gas sensing applications. Inorg. Chem. Commun. 160, 111843 (2024)10.1016/j.inoche.2023.111843 ↗
30. L. Tang, W. Zhang, D. Lin, Y. Ren, H.Z. QinxinLuo, L. Wei, H. Liu, J. Chen, K. Tang, The hexagonal perovskite Ba0.5Sr0.5Co0.8Fe0.2O3–δ as an efficient electrocatalyst for the oxygen evolution reaction. Inorg. Chem. Front. 7, 4488–4497 (2020)10.1039/D0QI00754D ↗
31. C. Kasarapu Venkataramana, C. Madhuri, A. Madhusudan, B. Bhogi, C. Srinivas, Vishnuvardhan Reddy, Influence of La3+, Sm3+and Dy3+ dopants on ceria solid electrolytes for IT–SOFCs, Mat. Sci. Semicon. Proc. 142, 106495 (2022)10.1016/j.mssp.2022.106495 ↗
32. H. Reza Bagheri, Kafashan, Physical characterizations of Se-doped CdS nanostructures. Phys. B 688, 416156 (2024)10.1016/j.physb.2024.416156 ↗
33. Y. He, L.F.M. Afzal, M. Singh, W. Zhang, Y. Zhao, J. Li, B. Zhu, Cobalt oxides coated commercial Ba0.5Sr0.5Co0.8Fe0.2O3–δ as high performance cathode for low-temperature SOFCs. Electrochim. Acta. 191, 223–229 (2016)10.1016/j.electacta.2016.01.090 ↗
34. P.V.C.K. Subhashini, K.V.D. Rajesh, Doped BSCF cathode materials for low-temperature solid oxide fuel cell applications-a short review, Mater. Today: Proc. 78, 520–523 (2023)10.1016/j.matpr.2022.11.212 ↗
35. Jerzy Kubacki, AbhijitChanda, MarekKulpa, BronisławPsiuk, Surface chemistry of BSCF material after Ar+ ion treatment and at elevated temperatures. Rad Phys. Chem. 175, 108340 (2020)10.1016/j.radphyschem.2019.05.030 ↗
36. A. Nora, B.P. Merino, P. Barbero, L.E. Eloy, Cadús, La1–xCaxCoO3 perovskite-type oxides: Identification of the surface oxygen species by XPS. Appl. Surf. Sci. 253, 1489–1493 (2006)10.1016/j.apsusc.2006.02.035 ↗
37. Y. Aiyu, M. Cheng, Y. Dong, W. Yang, V. Maragou, S. Song, P. Tsiakaras, Investigation of a Ba0.5Sr0.5Co0.8Fe0.2O3–δ based cathode IT-SOFC: I. The effect of CO2 on cell performance. Appl. Catal. B: Environ. 66, 64–71 (2006)10.1016/j.apcatb.2006.02.021 ↗
38. Y. Bangwu Liu, L. Zhang, Tang, Preparation and characterization of La0.9Sr0.1Ga0.8Mg0.2O3–δ thin film on the porous cathode for SOFC. Int. J. Hydrog Energy. 34, 440–445 (2009)10.1016/j.ijhydene.2008.10.020 ↗
39. Y. Bangwu Liu, L. Zhang, Tang, X-ray photoelectron spectroscopic studies of Ba0.5Sr0.5Co0.8Fe0.2O3–δcathode for solid oxide fuel cells. Int. J. Hydrog Energy. 34, 435–439 (2009)10.1016/j.ijhydene.2008.10.046 ↗
40. E. Tayebeh Roohandeh, Saievar-Iranizad, A study on the formation and migration of oxygen vacancies in Ba0.5Sr0.5Co0.8Fe0.2O3–δperovskite surfaces by first-principles modelling. Mater. Chem. Phys. 226, 371–377 (2019)10.1016/j.matchemphys.2019.01.046 ↗
41. E.A. Kotomin, Y.A. Mastrikov, M.M. Kuklja, R. Merkle, A. Roytburd, J. Maier, First principles calculations of oxygen vacancy formation and migration in mixed conducting Ba0.5Sr0.5Co1–yFeyO3–δ perovskites. Solid State Ion. 188, 1–5 (2011)10.1016/j.ssi.2010.10.011 ↗
42. R. Wei Zhou, Z. Ran, W. Shao, Jin, NanpingXu, Evaluation of A-site cation-deficient (Ba0.5Sr0.5)1–xCo0.8Fe0.2O3–δ (x > 0) perovskite as a solid-oxide fuel cell cathode,J. Power Sources. 182, 24–31 (2008)10.1016/j.jpowsour.2008.04.012 ↗
43. C. Shouguo Huang, Z. Peng, Zong, A high-performance Gd0.8Sr0.2CoO3–Ce0.9Gd0.1O1.95 composite cathode for intermediate temperature solid oxide fuel cell. J. Power Sources. 176, 102–106 (2008)10.1016/j.jpowsour.2007.10.018 ↗
44. F. Wang, T. Nakamura, K. Yashiro, J. Mizusakia, K. Amezawa, The crystal structure, oxygen non-stoichiometry and chemical stability of Ba0.5Sr0.5Co0.8Fe0.2O3–δ (BSCF). Phys. Chem. Chem. Phys. 16, 7307 (2014)10.1039/c3cp54810d ↗
45. L. Zhang, M. Liu, J. Huang, Z. Song, Y. Fu, Y. Chang, C. Li, T. He, Improved thermal expansion and electrochemical performances of Ba0.6Sr0.4Co0.9Nb0.1O3–δ–Gd0.1Ce0.9O1.95 composite cathodes for IT-SOFCs. Int. J. Hydrog Energy. 39, 7972 (2014)10.1016/j.ijhydene.2014.03.055 ↗
46. Q.L. Liu, K.A. Khor, S.H. Chan, High-performance low-temperature solid oxide fuel cell with novel BSCF cathode, J. Power Sources 161, 123 (2006)10.1016/j.jpowsour.2006.03.095 ↗
47. C. Kim, Kim Junyoung,Shin Jeeyoung,Kim Guntae, Effects of composite cathode on electrochemical and redox properties for intermediate-temperature solid oxide fuel cells. Int. J. Hydrog Energy. 39, 20812 (2014)10.1016/j.ijhydene.2014.07.007 ↗
48. L.-H. Luo, H. Jia-Xing, C. Liang, X. Xu, W. Ye-Fan, L. You-Chen, Performance of the Composite Cathode Ba0.5Sr0.5Co0.8Fe0.2O3-δ-Ce0.9Gd0.1O2-δ for medium-low temperature solid oxide fuel cell. J. Inorg. Mater. 33, 441 (2018)10.15541/jim20170232 ↗
49. K. Chen, H. Yang, Z. Chen, J. Huang, J. Qian, Z. Yue, L. Zhang, C. Guan, X. Wang, Y. Shao, San Ping Jiang, Na Ai, Enabling stable operation of Ba0.5Sr0.5Co0.8Fe0.2O3–δ based multiphase nanocomposite cathode for efficient intermedium temperature solid oxide fuel cells. Ceram. Int. 15, 46822 (2024)10.1016/j.ceramint.2024.09.033 ↗