Mixed alkali effect in Na2O-Li2O glass-ceramics: studies of physical properties and transport phenomena
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OpenAlex topics: Glass properties and applications · Thermodynamic and Structural Properties of Metals and Alloys · Thermal Expansion and Ionic Conductivity
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References (49)
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1. B. Karmakar, K. Rademann, A. Stepanov (eds.), Glass nanocomposites: synthesis, properties and applications (William Andrew, 2016)
2. G. Qian, X. Liao, Y. Zhu, F. Pan, X. Chen, Y. Yang, Designing flexible lithium-ion batteries by structural engineering. ACS Energy Lett. 4(3), 690–701 (2019)10.1021/acsenergylett.8b02496 ↗
3. P. Phogat, S. Dey, M. Wan, Comprehensive review of sodium-ion batteries: principles, materials, performance, challenges, and future perspectives. Materials Science and Engineering: B 312, 117870 (2025)
4. N.V. Kosova, A.A. Shindrov, Effect of mixed Li+/Na+-ion electrolyte on electrochemical performance of Na4Fe3 (PO4) 2P2O7 in hybrid batteries. Batteries. 5(2), 39 (2019)10.3390/batteries5020039 ↗
5. P. Adelhelm, P. Hartmann, C.L. Bender, M. Busche, C. Eufinger, J. Janek, From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries. Beilstein J. Nanotechnol. 6(1), 1016–1055 (2015)10.3762/bjnano.6.105 ↗
6. S. Ghosh, A. Ghosh, Electrical conductivity and conductivity relaxation in mixed alkali fluoride glasses. Solid State Ionics. 149(1–2), 67–72 (2002)10.1016/S0167-2738(02)00170-4 ↗
7. L. Bih, L. Abbas, S. Mohdachi, A. Nadiri, Thermal and electrical properties of mixed alkali in Li2O–Na2O–WO3–P2O5 glasses. Journal of Molecular Structure 891(1–3), 173–177 (2008)10.1016/j.molstruc.2008.03.019 ↗
8. H.D. Luong, T.D. Pham, Y. Morikawa, Y. Shibutani, V.A. Dinh, Diffusion mechanism of Na ion–polaron complex in potential cathode materials NaVOPO4 and VOPO4 for rechargeable sodium-ion batteries. Phys. Chem. Chem. Phys. 20, 23625 (2018)10.1039/C8CP03391A ↗
9. B. Saravana Karthikeyan, V. Manasa, R. Karpagam, S. Kavitha, K. Sakthipandi, R. Sivakumar, J. Yuvaraj, S. Ponmariappan, G. Rajkumar, Investigation of in vitro bioactivity and mechanical behavior of MgO-added fluorophosphate glasses. Ceramics International 51, 55431–55438 (2025). https://doi.org/10.1016/j.ceramint.2025.09.26310.1016/j.ceramint.2025.09.263 ↗
10. R. Dharshini, S. Kavitha, V. Dhivya, R. Karpagam, K. Sakthipandi, Evaluation of physico-chemical, antioxidant and antibacterial properties of ZnO added fluorophosphate glasses. Ceram. Int. 50, 45105–54113 (2024). https://doi.org/10.1016/j.ceramint.2024.08.35010.1016/j.ceramint.2024.08.350 ↗
11. S.F. Ahmed, N. Ravikumar, S. Kavitha, S. Mahalaxmi, V. Dhivya, G. Rajkumar, Impact of strontium added fluorophosphate glass on the physico-chemical properties of mineral trioxide aggregate. Ceram. Int. 51, 312–319 (2025). https://doi.org/10.1016/j.ceramint.2024.10.46110.1016/j.ceramint.2024.10.461 ↗
12. C. Franchini, M. Reticcioli, M. Setvin, U. Diebold, Polarons in materials. Nat. Rev. Mater. 6, 560 (2021)
13. M.S. Sutrisno, R. Hisam, Ionic and polaronic conduction in mixed ionic-electronic 98[20Li2O-xBi2O3-(80 – x)TeO2]-2Ag glass system. Ionics. 30, 271 (2024)10.1007/s11581-023-05301-7 ↗
14. I.A. Sokolov, I.V. Murin, N.A. Mel’Nikova, A.A. Pronkin, A study of ionic conductivity of glasses in the PbCl2–PbO· B2O3 and PbCl 2–2PbO· B2O3 systems. Glass Phys. Chem. 29, 291–299 (2003)10.1023/A:1024490217054 ↗
15. K. Poria, S. Dhankhar, R. Parmar, R.S. Kundu, D. Singh, Frequency-dependent electrical conductivity and impedance analysis on KCl modified tellurite-based glasses (MATERIALS RESEARCH BULLETIN, 2025), p. 18710.1016/j.materresbull.2025.113358 ↗
16. A. Edukondalu, B. Kavitha, M.A. Samee, S.K. Ahmmed, S. Rahman, K.S. Kumar, Mixed alkali tungsten borate glasses–optical and structural properties. J. Alloys Compd. 552, 157–165 (2013)10.1016/j.jallcom.2012.10.010 ↗
17. H. Liua, S. Liub, J. Kanga, Y. uea, X. Jiang, Co-improvementsofchemicalstabilityandglasstransitiontemperaturevia amixedalkalieffect inlow-melting Li2O-Na2O-CaO-P2O5sealingglasses. J. Non-Cryst. Solids 648, 123309 (2025)
18. Y. Hou, G.-H. Zhang, K.-C. Chou, Mixed alkali effect in SiO2-CaO-Al2O3-TiO2-R2O (R = Li, Na) glass ceramics. J. Alloys Compd. 856, 158239 (2021)
19. H.D. Subhashini, N.K. Shashikala, Udayashankar, Investigation of mixed alkali effect on mechanical, structural and thermal properties of three-alkali borate glass system. J. Alloys Compd. 658, 996 (2016)10.1016/j.jallcom.2015.11.014 ↗
20. S. Kojima, Mixed-alkali effect in borate glasses: thermal, elastic, and vibrational properties. Solids 1(1), 16–30 (2020)10.3390/solids1010003 ↗
21. S. Ghosh, A. Ghosh, Relaxation dynamics of charge carriers in mixed alkali fluoride glasses. J. Chem. Phys. 119(17), 9106–9110 (2003)10.1063/1.1613638 ↗
22. S.J. Japari, A.K. Yahya, R. Hisam, Effects of mixed-alkali oxides on AC conductivity and dielectric properties of xNa2O-(20-x) K2O-30V2O5-50TeO2 glasses. Results Phys. 16, 102905 (2020)10.1016/j.rinp.2019.102905 ↗
23. K. Patel, A. Patel, V.P. Jethwa, H. Patel, G.K. Solanki, X-ray diffraction analysis of orthorhombic SnSe nanoparticles by Williamson–Hall, Halder–Wagner and Size–Strain plot methods. Chem. Phys. Impact 8, 100547 (2024)
24. M.A. Algradee, M. Sultan, O.M. Samir, A.E.B. Alwany, Electronic polarizability, optical basicity and interaction parameter for Nd2O3 doped lithium–zinc–phosphate glasses. Appl. Phys. A 123, 1–12 (2017)10.1007/s00339-017-1136-6 ↗
25. S. Vyazovkin, DSC to explore activation energy landscape of glass relaxation. Thermochim. Acta 748, 179985 (2025)10.1016/j.tca.2025.179985 ↗
26. C. Calahoo, L. Wondraczek, Ionic glasses: structure, properties and classification. J. Non-Cryst. Solids X 8, 100054 (2020)
27. Z. Imran, M.A. Rafiq, M.M. & Hasan, Charge carrier transport mechanisms in perovskite CdTiO3 fibers. AIP Adv. 4, 067137 (2014). https://doi.org/10.1063/1.488546210.1063/1.4885462 ↗
28. S. Ghosh, A. Ghosh, Mixed mobile ion effect in fluoride glasses. Phys. Rev. B 66(13), 132204 (2002)10.1103/PhysRevB.66.132204 ↗
29. A. Faivre, D. Viviani, J. Phalippou, Mixed alkali effect in Li and Na aluminophosphate glasses: influence of the cation environment. Solid State Ionics. 176(3–4), 325–332 (2005)10.1016/j.ssi.2004.07.020 ↗
30. J.T. Bendler, C.A. Edmondson, J.J. Fontanella, M.F. Shlesinger, M.C. Wintersgill, Electrical conductivity in glass-forming solid electrolytes: theory and experiment. Solid state ionics. 154, 337–342 (2002)10.1016/S0167-2738(02)00531-3 ↗
31. A. Grandjean, M. Malki, C. Simonnet, D. Manara, B. Penelon, Correlation between electrical conductivity, viscosity, and structure in borosilicate glass-forming melts. Phys. Rev. B—Condensed Matter Mater. Phys. 75(5), 054112 (2007)10.1103/PhysRevB.75.054112 ↗
32. J. Habasaki, K.L. Ngai, The mixed alkali effect in ionically conducting glasses revisited: a study by molecular dynamics simulation. Physical Chemistry Chemical Physics 9(33), 4673–4689 (2007)10.1039/b704014h ↗
33. W. Ncib, A. Ben JaziaKharrat, M. Saadi, K. Khirouni, N. Chniba-Boudjada, W. Boujelben, Structural, AC conductivity, conduction mechanism and dielectric properties of La 0.62 Eu 0.05 Ba 0.33 Mn 0.85 Fe 0.15 O 3 ceramic compound. J. Mater. Sci.: Mater. Electron. 30, 18391–18404 (2019)
34. S. Bhattacharya, A. Ghosh, Applied physics letters 88(13), 133122 (2006)10.1063/1.2191430 ↗
35. C. Tsonos, Exploring the high frequencies AC conductivity response in disordered materials by using the damped harmonic oscillator. J. Compos. Sci. 6(7), 200 (2022)10.3390/jcs6070200 ↗
36. J. Yong, T. Winie, M.U. Khandaker, Y. Chen, H.J. Woo, Various types of AC conduction mechanism models for solid polymer electrolytes (SPE): a review. Journal of Power Sources 645, 237217 (2025)10.1016/j.jpowsour.2025.237217 ↗
37. B.A. Mei, O. Munteshari, J. Lau, B. Dunn, L. Pilon, Physical interpretations of Nyquist plots for EDLC electrodes and devices. J. Phys. Chem. C 122(1), 194–206 (2018)10.1021/acs.jpcc.7b10582 ↗
38. A. Bendahhou, K. Chourti, R. El Bouayadi, S. El Barkany, M. Abou-Salama, Structural, dielectric and impedance spectroscopy analysis of Ba 5 CaTi 1.94 Zn 0.06 Nb 8 O 30 ferroelectric ceramic. RSC Adv. 10(47), 28007–28018 (2020)10.1039/D0RA05163B ↗
39. H. Yurtseven, O. Akay, Calculation of the inverse relaxation time and the activation energy as a function of temperature for the Raman modes close to the phase transitions in solid nitrogen. J. Mol. Struct. 1226, 129347 (2021)10.1016/j.molstruc.2020.129347 ↗
40. P.A. Santoro, E.K. Lenzi, L.R. Evangelista, F. Ciuchi, A. Mazzulla, N. Scaramuzza, Anomalous diffusion effects on the electrical impedance response of liquid-crystalline systems. Mol. Cryst. Liq. Cryst. 576(1), 23–31 (2013)10.1080/15421406.2013.789423 ↗
41. P.B. Macedo, C.T. Moynihan, R. Bose, The role of ionic diffusion in polarization in vitreous ionic conductors. Phys. Chem. Glasses 13, 171 (1972)
42. N.G. McCrum, B.E. Read, G. Williams, Anelastic and Dielectric Effects in Polymeric Solids (Wiley, NewYork, 1967), p.108
43. R. Schmidt, S. Pandey, P. Fiorenza, D.C. Sinclair, Nonstoichiometry in ‘CaCu3Ti4O12’ (CCTO) ceramics. RSC Adv. 3, 14580 (2013)10.1039/c3ra41319e ↗
44. C. Rayssi, S.E. Kossi, J. Dhahri, K. Khirouni, Frequency and temperaturedependence of dielectric permittivity and electric modulus studies of the solid solution Ca0.85Er0.1Ti1 − xCo4x/3O3 (0⩽ x⩽ 0.1). RSC Adv. 8, 17139 (2018)10.1039/C8RA00794B ↗
45. A.K. Jonscher, Dielectric relaxation in solids. J. Phys. D 32, R57 (1999)10.1088/0022-3727/32/14/201 ↗
46. D.L. Sidebottom, Dimensionality dependence of the conductivity dispersion in ionic materials. Phys. Rev. Lett. 83(5), 983 (1999)10.1103/PhysRevLett.83.983 ↗
47. S. Ghosh, A. Ghosh, (2005). Ion dynamics and mixed mobile ion effect in fluoride glasses. Journal of applied physics, 97(12)10.1063/1.1939084 ↗
48. K. Górska, A. Horzela, K.A. Penson, Non-Debye relaxations: the ups and downs of the stretched exponential vs. Mittag–Leffler’sMatchings. Fractal Fract. 5(4), 265 (2021)10.3390/fractalfract5040265 ↗
49. S. Ghosh, A. Ghosh, Conductivity relaxation in mixed alkali fluorideglasses. J. Phys. Condens. Matter 14(10), 2531 (2002)