journal article·2026-05

Reentrant spin glass behavior in the Ga(0.67–0.67x)CoxCr2S4 (x = 0.5–0.8) spinel solid solutions

A. D. Denischenko, E. V. Busheva, G. G. Shabunina, P. N. Vasilev, N. N. Efimov

Applied Physics A· Volume 132· Issue 5
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advanced Condensed Matter Physics · Magnetic and transport properties of perovskites and related materials · Magnetic Properties and Synthesis of Ferrites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (59)

Show source-provided references
1. S.V. Trukhanov, I.V. Bodnar, M.A. Zhafar, Magnetic and electrical properties of (FeIn2S4)1−(CuIn5S8) solid solutions. J. Magn. Magn. Mater. 379, 22–27 (2015). https://doi.org/10.1016/j.jmmm.2014.10.12010.1016/j.jmmm.2014.10.120 ↗
2. B.R. Myoung, J.T. Lim, C.S. Kim, Investigation of magnetic properties on spin-ordering effects of FeGa2S4 and FeIn2S4. J. Magn. Magn. Mater. 438, 121–125 (2017). https://doi.org/10.1016/j.jmmm.2017.04.05610.1016/j.jmmm.2017.04.056 ↗
3. M. Zulqarnain, S.S. Ali, C. Cheng, K. Nadeem, M. Rizwan, T. Anwar, Structural tuning interlinking various optical, dielectric and magnetic trends in annealed Mn0.5Zn0.5Fe2O4 spinel ferrites nanostructures. J. Magn. Magn. Mater. 565, 170252 (2023). https://doi.org/10.1016/j.jmmm.2022.17025210.1016/j.jmmm.2022.170252 ↗
4. X. Bai, J. Li, Photocatalytic hydrogen generation over porous ZnIn2S4 microspheres synthesized via a CPBr-assisted hydrothermal method. Mater. Res. Bull. 46, 1028–1034 (2011). https://doi.org/10.1016/j.materresbull.2011.03.01210.1016/j.materresbull.2011.03.012 ↗
5. H. Jia, W. He, Y. Lei, X. Chen, Y. Xiang, S. Zhang, W.M. Lau, Z. Zheng, Controllable fabrication of ternary ZnIn2S4 nanosheet array film for bulk heterojunction solar cells. RSC Adv. 3, 8909–8914 (2013). https://doi.org/10.1039/C3RA40322J10.1039/C3RA40322J ↗
6. P. He, X. Li, T. Wang, W. Chen, H. Zhang, W. Che, Keggin-type polyoxometalate/thiospinel octahedron heterostructures for photoelectronic devices. Inorg. Chem. Front. 7, 2621–2628 (2020). https://doi.org/10.1039/D0QI00371A10.1039/D0QI00371A ↗
7. M. Amiri, M. Salavati-Niasari, A. Akbari, Magnetic nanocarriers: evolution of spinel ferrites for medical applications. Adv. Colloid Interface Sci. 265, 29–44 (2019). https://doi.org/10.1016/j.cis.2019.01.00310.1016/j.cis.2019.01.003 ↗
8. Y. Su, S. Zhao, Y. Bai, Efficient magneto-tunable photocurrent in multiferroics. Appl. Phys. Lett. 127, 122901 (2025). https://doi.org/10.1063/5.027632810.1063/5.0276328 ↗
9. J. Li, X. Li, J. Yang, A review of bipolar magnetic semiconductors from theoretical aspects. Fundamental Research 2, 511–521 (2022). https://doi.org/10.1016/j.fmre.2022.04.00210.1016/j.fmre.2022.04.002 ↗
10. T. Dietl, A. Bonanni, H. Ohno, Families of magnetic semiconductors — an overview. J. Semicond. 40, 080301 (2019). https://doi.org/10.1088/1674-4926/40/8/08030110.1088/1674-4926/40/8/080301 ↗
11. H. Kalita, M. Bhushan, L.R. Singh, A comprehensive review on theoretical concepts, types and applications of magnetic semiconductors. Mater. Sci. Eng. B Solid State Mater. Adv. Technol. 288, 116201 (2023). https://doi.org/10.1016/j.mseb.2022.11620110.1016/j.mseb.2022.116201 ↗
12. P. Zhao, C. He, Y. Su, Y. Zou, Y. Bai, S. Zhao, Probing ballistic photovoltaic currents in Bi6-xPrxTi3Fe2O18 multiferroics. J. Eur. Ceram. Soc. 44, 5752–5764 (2024). https://doi.org/10.1016/j.jeurceramsoc.2024.03.04410.1016/j.jeurceramsoc.2024.03.044 ↗
13. T.G. Aminov, E.V. Busheva, G.G. Shabunina, N.N. Efimov, Paramagnetism of Fex(Cu0.5In0.5)1–xCr2S4 solid solutions. Inorg. Mater. 56, 993–999 (2020). https://doi.org/10.1134/S002016852010001510.1134/S0020168520100015 ↗
14. M. Pardo-Sainz, S. Moris, C. Piquer, J.A. Rodríguez-Velamazán, M.L. López, I. Álvarez-Serrano, A. Galdámez, J. Campo, Suppression of ferromagnetism and emergence of spin-glass-like behavior in the CuCr2-xSnxS2Se2 spinels. Phys. Rev. B 110, 064436 (2024). https://doi.org/10.1103/PhysRevB.110.06443610.1103/PhysRevB.110.064436 ↗
15. Jendrzejewska, T. Groń, K. Knizek, M. Pilch, A. Ślebarski, J. Goraus, P. Zajdel, Z. Stokłosa, E. Pietrasik, T. Goryczka, M. Fijałkowski, Z. Barsova, J. Jampilek, Preparation, structure and magnetic, electronic and thermal properties of Dy3+-doped ZnCr2Se4 with unique geometric type spin-glass. J Solid State Chem 298, 122114 (2021). https://doi.org/10.1016/j.jssc.2021.12211410.1016/j.jssc.2021.122114 ↗
16. G.G. Shabunina, E.V. Busheva, P.N. Vasilev, A.D. Denishchenko, S.V. Golodukhina, N.N. Efimov, Magnetic properties of Co1-xFexCr2S4 (x = 0–0.4) solid solutions. Physica B: Condensed Matter 691, 416361 (2024). https://doi.org/10.1016/j.physb.2024.41636110.1016/j.physb.2024.416361 ↗
17. A.S. Cameron, Y.V. Tymoshenko, P.Y. Portnichenko, J. Gavilano, V. Tsurkan, V. Felea, A. Loidl, S. Zherlitsyn, J. Wosnitza, D.S. Inosov, Magnetic phase diagram of the helimagnetic spinel compound ZnCr2Se4 revisited by small-angle neutron scattering. J. Phys. Condens. Matter 28, 146001 (2016). https://doi.org/10.1088/0953-8984/28/14/14600110.1088/0953-8984/28/14/146001 ↗
18. R. Fichtl, V. Tsurkan, P. Lunkenheimer, J. Hemberger, V. Fritsch, H.-A. von Nidda, E.-W. Scheidt, A. Loidl, Orbital freezing and orbital glass state in FeCr2S4. Phys. Rev. Lett. 94, 027601 (2005). https://doi.org/10.1103/PhysRevLett.94.02760110.1103/PhysRevLett.94.027601 ↗
19. Krimmel, M. Mücksch, V. Tsurkan, M.M. Koza, H. Mutka, A. Loidl, Vibronic and magnetic excitations in the spin-orbital liquid state of FeSc2S4. Phys. Rev. Lett. 94, 237402 (2005). https://doi.org/10.1103/PhysRevLett.94.23740210.1103/PhysRevLett.94.237402 ↗
20. A.D. Denishchenko, E.V. Busheva, G.G. Shabunina, P.N. Vasilev, S.V. Golodukhina, N.N. Efimov, Magnetic and structural properties of Co-doped chalcogenide spinel Ga0.67Cr2S4. J. Mater. Sci. 60, 811–822 (2025). https://doi.org/10.1007/s10853-024-10573-z10.1007/s10853-024-10573-z ↗
21. J. Bertinshaw, C. Ulrich, A. Günther, F. Schrettle, M. Wohlauer, S. Krohns, M. Reehuis, A.J. Studer, M. Avdeev, D.V. Quach, J.R. Groza, V. Tsurkan, A. Loidl, J. Deisenhofer, FeCr2S4 in magnetic fields: possible evidence for a multiferroic ground state. Sci. Rep. 4, 6079 (2014). https://doi.org/10.1038/srep0607910.1038/srep06079 ↗
22. O. Hartmann, G.M. Kalvius, R. Wäppling, A. Günther, V. Tsurkan, A. Krimmel, A. Loidl, Magnetic properties of the multiferroic chromium thio-spinels CdCr2S4 and HgCr2S4. Eur. Phys. J. B. 86, 148 (2013). https://doi.org/10.1140/epjb/e2013-31094-410.1140/epjb/e2013-31094-4 ↗
23. L. Balents, Spin liquids in frustrated magnets. Nature 464, 199–208 (2010). https://doi.org/10.1038/nature0891710.1038/nature08917 ↗
24. D. Reig-i-Plessis, A.M. Hallas, Frustrated magnetism in fluoride and chalcogenide pyrochlore lattice materials. Phys. Rev. Mater. 5, 030301 (2021). https://doi.org/10.1103/PhysRevMaterials.5.03030110.1103/PhysRevMaterials.5.030301 ↗
25. P. Gibart, J.-L. Dormann, Y. Pellerin, Magnetic properties of FeCr2S4 and CoCr2S4. Physica Status Solidi (b) 36, 187–194 (1969). https://doi.org/10.1002/pssb.1969036012010.1002/pssb.19690360120 ↗
26. T. Watanabe, Electrical properties of FeCr2S4 and CoCr2S4. Solid State Commun. 12, 355–358 (1973). https://doi.org/10.1016/0038-1098(73)90772-210.1016/0038-1098(73)90772-2 ↗
27. K. Dey, A. Karmakar, A. Indra, S. Majumdar, U. Rütt, O. Gutowski, M. Zimmermann, S. Giri, Thermally assisted and magnetic field driven isostructural distortion of spinel structure and occurrence of polar order in CoCr2S4. Phys. Rev. B 92, 024401 (2015). https://doi.org/10.1103/PhysRevB.92.02440110.1103/PhysRevB.92.024401 ↗
28. K. Dey, A. Indra, A. Karmakar, S. Giri, Multicaloric effect in multiferroic sulpho spinel MCr2S4 (M = Fe & Co). J. Magn. Magn. Mater. 498, 166090 (2020). https://doi.org/10.1016/j.jmmm.2019.16609010.1016/j.jmmm.2019.166090 ↗
29. D. Brasen, J.M. Vandenberg, M. Robbins, R.H. Willens, W.A. Reed, R.C. Sherwood, X.J. Pinder, Magnetic and crystallographic properties of spinels of the type AxB2S4 where A = Al, Ga, and B = Mo, V, Cr. J. Solid State Chem. 13, 298–303 (1975). https://doi.org/10.1016/0022-4596(75)90141-310.1016/0022-4596(75)90141-3 ↗
30. V. Petříček, L. Palatinus, J. Plášil, M. Dušek, Jana2020 – a new version of the crystallographic computing system Jana. Z. Kristallogr. Crystalline Mater. 238, 271–282 (2023). https://doi.org/10.1515/zkri-2023-000510.1515/zkri-2023-0005 ↗
31. V. Petříček, M. Dušek, L. Palatinus, Crystallographic computing system JANA2006: general features. Z. Kristallogr. Crystalline Mater. 229, 345–352 (2014). https://doi.org/10.1515/zkri-2014-173710.1515/zkri-2014-1737 ↗
32. R. Saha, R. Dhanya, C. Bellin, K. Béneut, A. Bhattacharyya, A. Shukla, C. Narayana, E. Suard, J. Rodríguez-Carvajal, A. Sundaresan, Magnetostructural coupling and magnetodielectric effects in the A-site cation-ordered spinel LiFeCr4O8. Phys. Rev. B 96, 214439 (2017). https://doi.org/10.1103/PhysRevB.96.21443910.1103/PhysRevB.96.214439 ↗
33. N. Kumar, A. Sundaresan, On the observation of negative magnetization under zero-field-cooled process. Solid State Commun. 150, 1162–1164 (2010). https://doi.org/10.1016/j.ssc.2010.03.01610.1016/j.ssc.2010.03.016 ↗
34. D. Harrabi, S. Hcini, I. Ghiloufi, A. Mimouni, J. Dhahri, K. Khirouni, Studies of the microstructural, magnetic, electrical, and dielectric properties of Mg0.6T0.4Cr2O4 (T = Ni, Cu) spinel chromites for magnetic, high frequency, and microwave applications. J. Magn. Magn. Mater. 582, 171040 (2023). https://doi.org/10.1016/j.jmmm.2023.17104010.1016/j.jmmm.2023.171040 ↗
35. M.D. Hossain, M.A. Hossain, S.S. Sikder, Hysteresis loop properties of rare earth doped spinel ferrites: a review. J. Magn. Magn. Mater. 564, 170095 (2022). https://doi.org/10.1016/j.jmmm.2022.17009510.1016/j.jmmm.2022.170095 ↗
36. S.R. Daf, D.S. Badwaik, S.M. Suryawanshi, V.S. Harode, B.R. Balbudhe, Physical, spectroscopic and antibacterial investigation of Mg0.3Zn0.5Mn0.2Fe2O4 via temperature dependent hydrothermal approach. J. Magn. Magn. Mater. 567, 170346 (2023). https://doi.org/10.1016/j.jmmm.2022.17034610.1016/j.jmmm.2022.170346 ↗
37. R.C. Kambale, K.M. Song, Y.S. Koo, N. Hur, Low temperature synthesis of nanocrystalline Dy3+ doped cobalt ferrite: structural and magnetic properties. J. Appl. Phys. 110, 053910 (2011). https://doi.org/10.1063/1.363298710.1063/1.3632987 ↗
38. E.C. Stoner, E.P. Wohlfarth, A mechanism of magnetic hysteresis in heterogeneous alloys. Philos. Trans. R. Soc. Lond. Ser. A Math. Phys. Sci. 240, 599–642 (1948). https://doi.org/10.1098/rsta.1948.000710.1098/rsta.1948.0007 ↗
39. P. Bag, P.R. Baral, R. Nath, Cluster spin-glass behavior and memory effect in Cr0.5Fe0.5Ga. Phys. Rev. B 98, 144436 (2018). https://doi.org/10.1103/PhysRevB.98.14443610.1103/PhysRevB.98.144436 ↗
40. R. Hissariya, V.G. Sathe, S.K. Mishra, Antisite disorder mediated exchange bias effect and spin-glass state in La2-xSmxNiMnO6. J. Magn. Magn. Mater. 578, 170769 (2023). https://doi.org/10.1016/j.jmmm.2023.17076910.1016/j.jmmm.2023.170769 ↗
41. G. Benka, A. Bauer, P. Schmakat, S. Säubert, M. Seifert, P. Jorba, C. Pfleiderer, Interplay of itinerant magnetism and spin-glass behavior in FeCr1-x. Phys. Rev. Mater. 6, 044407 (2022). https://doi.org/10.1103/PhysRevMaterials.6.04440710.1103/PhysRevMaterials.6.044407 ↗
42. J.A. Mydosh, Spin glasses: redux: an updated experimental/materials survey. Rep. Prog. Phys. 78, 052501 (2015). https://doi.org/10.1088/0034-4885/78/5/05250110.1088/0034-4885/78/5/052501 ↗
43. S. Kundu, T. Dey, A.V. Mahajan, N. Büttgen, LiZn2V3O8: a new geometrically frustrated cluster spin-glass. J. Phys. Condens. Matter 32, 115601 (2019). https://doi.org/10.1088/1361-648X/ab58dc10.1088/1361-648X/ab58dc ↗
44. M. Roy-Chowdhury, M.S. Seehra, S. Thota, Optimized analysis of the AC magnetic susceptibility data in several spin-glass systems using the Vogel–Fulcher and Power laws. AIP Adv. 13, 115020 (2023). https://doi.org/10.1063/5.016980010.1063/5.0169800 ↗
45. T. Chakrabarty, A.V. Mahajan, S. Kundu, Cluster spin glass behavior in geometrically frustrated Zn3V3O8. J. Phys. Condens. Matter 26, 405601 (2014). https://doi.org/10.1088/0953-8984/26/40/40560110.1088/0953-8984/26/40/405601 ↗
46. S. Chatterjee, S. Giri, S.K. De, S. Majumdar, Reentrant-spin-glass state in Ni2Mn1.36Sn0.64 shape-memory alloy. Phys. Rev. B 79, 092410 (2009). https://doi.org/10.1103/PhysRevB.79.09241010.1103/PhysRevB.79.092410 ↗
47. S. Lal, C.S. Yadav, K. Mukherjee, Effect of (Cu/Fe)O5 bipyramid size and separation on magnetic and dielectric properties of rare earth layered perovskite LaBaCuFeO5 and LuBaCuFeO5. J. Appl. Phys. 126, 144101 (2019). https://doi.org/10.1063/1.509661110.1063/1.5096611 ↗
48. S. Ghosh, T. Paramanik, Evidence of cluster glass-like behavior in (Dy0.6Gd0.4)5Pd2. J. Supercond. Nov. Magn. 38, 119 (2025). https://doi.org/10.1007/s10948-025-06961-410.1007/s10948-025-06961-4 ↗
49. M.K. Singh, W. Prellier, M.P. Singh, R.S. Katiyar, J.F. Scott, Spin-glass transition in single-crystal BiFeO3. Phys. Rev. B 77, 144403 (2008). https://doi.org/10.1103/PhysRevB.77.14440310.1103/PhysRevB.77.144403 ↗
50. B. Aslibeiki, P. Kameli, H. Salamati, M. Eshraghi, T. Tahmasebi, Superspin glass state in MnFe2O4 nanoparticles. J. Magn. Magn. Mater. 322, 2929–2934 (2010). https://doi.org/10.1016/j.jmmm.2010.05.00710.1016/j.jmmm.2010.05.007 ↗
51. R. Lu, Y. Ji, Y. Wang, X. Ke, F. Tian, C. Zhou, Y. Zhang, C. Liu, S. Yang, X. Ren, X. Song, Evidence for a Griffiths phase to cluster spin glass transition in the La2/3Sr1/3(Mn1-3xAl2xTix)O3 system. Adv. Sci. 11, 2408517 (2024). https://doi.org/10.1002/advs.20240851710.1002/advs.202408517 ↗
52. S. Tiwari, A. Yadav, S. Kamali, A. Williams, J.S. Anandhi, J. Johnson, C. Johnson, A. Eyal, S. Kumar, Unravelling coexistence of superparamagnetism- soft ferrimagnetism, super-spin glass and Griffith phases in an assembly of greenly synthesized Zn0.5Fe2.5O4 nanopolygons and their magnetic hyperthermia efficiency. J. Magn. Magn. Mater. 627, 173118 (2025). https://doi.org/10.1016/j.jmmm.2025.17311810.1016/j.jmmm.2025.173118 ↗
53. P. Kearins, E. Solana-Madruga, K. Ji, C. Ritter, J.P. Attfield, Cluster spin glass formation in the double double perovskite CaMnFeTaO6. J. Phys. Chem. C 125, 9550–9555 (2021). https://doi.org/10.1021/acs.jpcc.1c0217210.1021/acs.jpcc.1c02172 ↗
54. S. Chatterjee, S. Chattopadhyay, S. Giri, S. Majumdar, Nature of the glassy magnetic state in the Cu2.84Mn0.44Al0.72 shape memory alloy. EPL (Europhysics Letters) 104, 47014 (2013). https://doi.org/10.1209/0295-5075/104/4701410.1209/0295-5075/104/47014 ↗
55. H.K. Dara, P.D. Babu, G. Markandeyulu, Cluster glass behaviour in MnMn0.25Sb. Intermetallics 131, 107113 (2021). https://doi.org/10.1016/j.intermet.2021.10711310.1016/j.intermet.2021.107113 ↗
56. M. Nasir, S. Kumar, A.K. Bera, M. Khan, S.M. Yusuf, S. Sen, Cluster spin-glass-like dynamics in Mn-rich La2Ni0.5Mn1.5O6 ferromagnetic insulator. J. Phys. Condens. Matter 33, 225803 (2021). https://doi.org/10.1088/1361-648X/abf38010.1088/1361-648X/abf380 ↗
57. A.K. Grover, S.K. Malik, C. Radhakrishnamurty, R. Vijayaraghavan, A.C. susceptibility measurements in the presence of D.C. magnetic fields in CoGa alloys — a cluster spin glass system. Solid State Commun. 32, 1323–1325 (1979). https://doi.org/10.1016/0038-1098(79)90894-910.1016/0038-1098(79)90894-9 ↗
58. J. Dho, W.S. Kim, N.H. Hur, Reentrant spin glass behavior in Cr-doped perovskite manganite. Phys. Rev. Lett. 89, 027202 (2002). https://doi.org/10.1103/PhysRevLett.89.02720210.1103/PhysRevLett.89.027202 ↗
59. J.K. Clark, X. Tan, V.O. Garlea, A.A. Arico, A.P. Ramirez, V. Yannello, C.M. Thompson, K. Kovnir, M. Shatruk, Reentrant spin glass state induced by structural phase transition in La0.4Ce0.6Co2P2. Phys. Rev. Mater. 4, 074412 (2020). https://doi.org/10.1103/PhysRevMaterials.4.07441210.1103/PhysRevMaterials.4.074412 ↗