journal article·2026-04

Enhanced photocatalytic degradation of methylene blue from aqueous solution by a copper ferrite (CuFe2O4) thin films under solar light irradiation: efficiency, stability and kinetic studies

I. Saafi, J. Ben naceur, S. Lazzez, M. Amlouk, R. Chtourou

Applied Physics A· Volume 132· Issue 4
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (78)

Show source-provided references
1. G. Palanisamy, K. Bhuvaneswari, G. Bharathi, T. Pazhanivel, M. Dhanalakshmi, Improved photocatalytic performance of magnetically recoverable Bi2Te3/ CdS/CuFe2O4 nanocomposite for MB dye under visible light exposure. Solid State Sci. 115, 106584 (2021)10.1016/j.solidstatesciences.2021.106584 ↗
2. I. Khan, K. Saeed, I. Zekker, B. Zhang, A.H. Hendi, A. Ahmad, S. Ahmad, N. Zada, H. Ahmad, L.A. Shah, T. Shah, I. Khan, Review on methylene blue: its properties, uses, toxicity and photodegradation. Water 14, 242 (2022)
3. M. Wang, X.X. Song, X.L. Cheng, X. Zhou, X.F. Zhang, Z. Cai, Y.M. Xu, S. Gao, H. Zhao, L.H. Huo, Highly selective and efficient adsorption dyes self-assembled by 3D hierarchical architecture of molybdenum oxide. RSC Adv. 5, 85248–85255 (2015)10.1039/C5RA18442H ↗
4. S. Jorfi, G. Barzegar, M. Ahmadi, R. Darvishi Cheshmeh Soltani, N. Alah Jafarzadeh Haghighifard, A. Takdastan, R. Saeedi, M. Abtahi, Enhanced coagulationphotocatalytic treatment of acid red 73 dye and real textile wastewater using UVA/ synthesized MgO nanoparticles. J. Environ. Manage. 177, 111–118 (2016)10.1016/j.jenvman.2016.04.005 ↗
5. Y.Y. Lau, Y.S. Wong, T.T. Teng, N. Morad, M. Rafatullah, S.A. Ong, Degradation of cationic and anionic dyes in coagulation-flocculation process using bifunctionalized silica hybrid with aluminum-ferric as auxiliary agent. RSC Adv. 5, 34206–34215 (2015)10.1039/C5RA01346A ↗
6. F. Jose Alguacil, M. Alonso, J. Ignacio Robla, Removal of hazardous organic dyes from liquid wastes using advanced nanomaterials. Int. J. Mol. Sci. 25, 9671 (2024)
7. E. Guivarch, S. Trevin, C. Lahitte, M.A. Oturan, Degradation of azo dyes in water by electro-Fenton process. Environ. Chem. Lett. 1, 38–44 (2003)10.1007/s10311-002-0017-0 ↗
8. J. Shamshad, R.U. Rehman, Innovative approaches to sustainable wastewater treatment: a comprehensive exploration of conventional and emerging technologies. Environ. Sci.: Adv. 4, 189–222 (2025)
9. R. Andreozzi, V. Caprio, A. Insola, R. Marotta, Advanced oxidation processes (AOP) for water purification and recovery. Catal. Today (1999). https://doi.org/10.1016/s0920-5861(99)00102-910.1016/s0920-5861(99)00102-9 ↗
10. M.A. Oturan, J. Aaron, Advanced oxidation processes in water/wastewater treatment: principles and applications. Environ. Sci. Technol. 44, 2577–2641 (2014)
11. A.E. Prol, Mechanisms of disposal of acid and alkali in rabbit duodenum. Am. J. Physiol. 229, 1641–1648 (1975)10.1152/ajplegacy.1975.229.6.1641 ↗
12. K. Atacan, N. Güy, S. Çakar, M. Ozacar, Efficiency of glucose oxidase immobilized on tannin modified NiFe2O4 nanoparticles on decolorization of dye in the Fenton and photo-biocatalytic processes. J. Photochem. Photobiol. A Chem. 382, 111935 (2019)10.1016/j.jphotochem.2019.111935 ↗
13. A. Aboudalle, H. Djelal, F. Fourcade, L. Domergue, A.A. Assadi, T. Lendormi, S. Taha, A. Amrane, Metronidazole removal by means of a combined system coupling an electro-Fenton process and a conventional biological treatment: byproducts monitoring and performance enhancement. J. Hazard. Mater. 359, 85–95 (2018)10.1016/j.jhazmat.2018.07.006 ↗
14. E.C. Severo, G.L. Dotto, S. Silvestri, I. Nunes, J. Salla, A.M. M.-dl Cruz, K.B. Martinello, E.L. Foletto, Improved catalytic activity of EDTA–modified BiFeO3 powders for remarkable degradation of procion red by heterogeneous photo–Fenton process. J. Environ. Chem. Eng. 38, 101664 (2020)
15. K. Nadeem, G.T. Guyer, N. Dizge, Polishing of biologically treated textile wastewater through AOPs and recycling for wet processing. J. Water Process. Eng. 20, 29–39 (2017)10.1016/j.jwpe.2017.09.011 ↗
16. E. Bazrafshan, T.J. Al-Musawi, M.F. Silva, A.H. Panahi, M. Havangi, F.K. Mostafapur, Photocatalytic degradation of catechol using ZnO nanoparticles as catalyst: optimizing the experimental parameters using the Box-Behnken statistical methodology and kinetic studies. Microchemical Journal. J 147, 643–653 (2019)10.1016/j.microc.2019.03.078 ↗
17. M. Karami, K. Sharafi, A. Asadi, A. Bagheri, F. Yosefvand, S.S. Charganeh, N. Mirzaei, A. Velayati, Degradation of Reactive Red 198 (RR198) from aqueous solutions by advanced oxidation processes (AOPS): O3, H2O2/O3 and H2O2/ultrasonic. Bulg. Chem. Commun. 48, 43–49 (2016)
18. N. Rastkari, A. Eslami, S. Nasseri, E. Piroti, A. Asadi, Optimizing parameters on nanophotocatalytic degradation of Ibuprofen using UVC/ZnO processes by response surface methodology. Pol. J. Environ. Stud. 26, 785–794 (2017)10.15244/pjoes/64931 ↗
19. H. Kamani, E. Bazrafshan, M.G. Ghozikali, M. Askari, R. Ameri, Photocatalyst Decolorization of C. I. Sulphur Red 14 From Aqueous Solution by UV Irradiation in the Presence of ZnO Nanopowde. Health Scope. 4, 22248 (2015)10.17795/jhealthscope-22248 ↗
20. H. Kamani, S. Nasseri, M. Khoobi, R.N. Nodehi, A.H. Mahvi, Sonocatalytic degradation of humic acid by N-doped TiO2 nano-particle in aqueous solution. J. Environ. Health Sci. Eng. 14, 3 (2016)10.1186/s40201-016-0242-2 ↗
21. S.V. Bhosale, D.D. La, Nanoscale porphyrin superstructures: properties, self-assembly and photocatalytic applications. Nanoscience, 5 92018057–92018085
22. J. Du, J. Bao, Y. Liu, S.H. Kim, D.D. Dionysiou, Facile preparation of porous Mn/Fe3O4 cubes as peroxymonosulfate activating catalyst for effective bisphenol A degradation. Chem. Eng. J. 376, 119193 (2019)
23. X. Zhu, W. Yuan, M. Lang, G. Zhen, X. Zhang, X. Lu, Novel methods of sewage sludge utilization for photocatalytic degradation of tetracycline-containing wastewater. Fuel. 252, 148–156 (2019)10.1016/j.fuel.2019.04.093 ↗
24. Y. Piña-Pérez, F. Tzompantzi-Morales, R. Pérez-Hernández, R. Arroyo-Murillo, P. Acevedo-Peña, R. Gómez-Romero, Photocatalytic activity of Al2O3 improved by the addition of Ce3+/Ce4 + synthesized by the sol-gel method. Photodegradation of phenolic compounds using UV light. Fuel 198, 11–21 (2017)10.1016/j.fuel.2016.12.040 ↗
25. S. Yan, Z. Li, Z. Zou, Photodegradation of rhodamine B and methyl orange over borondoped g-C3N4 under visible light irradiation. Langmuir 26, 3894–3901 (2010)10.1021/la904023j ↗
26. D.D. La, S.V. Bhosale, L.A. Jones, N. Revaprasadu, S.V. Bhosale, Fabrication of a Graphene@ TiO2@ Porphyrin hybrid material and its photocatalytic properties under simulated sunlight irradiation. ChemistrySelect 2, 3329–3333 (2017)10.1002/slct.201700473 ↗
27. W.J. Chung, D.D. Nguyen, X.T. Bui et al., A magnetically separable and recyclable Agsupported magnetic TiO2 composite catalyst: fabrication, characterization, and photocatalytic activity. J. Environ. Manage. 213, 541 (2018)10.1016/j.jenvman.2018.02.064 ↗
28. G. Francis, J. Oliver, M. Sujatha, Non-toxic jatropha plants as a potential multipurpose multi-use oilseed crop. Ind. Crops Prod. 42, 397–401 (2013)10.1016/j.indcrop.2012.06.015 ↗
29. M. Zangiabadi, A. Saljooqi, T. Shamspur, A. Mostafavi, Evaluation of GO nanosheets decorated by CuFe2O4 and CdS nanoparticles as photocatalyst for the degradation of dinoseb and imidacloprid pesticides. Ceram. Int. 46, 6124–6128 (2019)10.1016/j.ceramint.2019.11.076 ↗
30. M.N. Arifin, K.M.R. Karim, H. Abdullah, M.R. Khan, Synthesis of titania doped copper ferrite photocatalyst and its photoactivity towards methylene blue degradation under visible light irradiation. Bull. Chem. React. Eng. Catal. 14, 219–227 (2019)10.9767/bcrec.14.1.3616.219-227 ↗
31. A. Al-Hunaiti, N. Al-Said, L. Halawani, M. Abu Haija, R. Baqaien, D. Taher. Synthesis of Magnetic CuFe2O4 Nanoparticles as Green Catalyst for Toluene Oxidation under Solvent-Free Conditions, (2020).10.1016/j.arabjc.2020.01.017 ↗
32. L. Zhang, Zhao, Y. Xu, T. Zhu, Copper ferrite (CuFe₂O₄) as a visible-light-responsive photocatalyst for environmental remediation. Journal of Hazardous Materials, (2012) 215–21610.1016/j.jhazmat.2012.02.030 ↗
33. M. Kooti, M. Afshari, Magnetic CuFe₂O₄ nanoparticles as an efficient catalyst. Mater. Res. Bull. 47, 3473–3478 (2012)10.1016/j.materresbull.2012.07.001 ↗
34. J. Deng, X. Wen, Q. Wang, Visible-light-driven photocatalytic degradation of organic pollutants by spinel CuFe₂O₄. Appl. Catal. B, (2012)111–112
35. S. Ben Ameura, A. Barhoumi, H. Bel hadjltaief, R. Mimouni, B. Duponchel, G. Leroye, M. Amlouk, H. Guermazi, Physical investigations on undoped and Fluorine doped SnO2 nanofilms on flexible substrate along with wettability and photocatalytic activity tests. Mater. Sci. Semicond. Process. 61, 17–26 (2017)10.1016/j.mssp.2016.12.019 ↗
36. I. Saafi, R. Dridi, A. Mami, J. Ben Naceur, A. Amlouk, R. Chtourou, M. Amlouk, Some physical investigations on NiCo2O4 thin flms for potential applications. Appl. Phys. A 127, 651 (2021)10.1007/s00339-021-04804-2 ↗
37. A. Mills, J. Wang, Photobleaching of methylene blue sensitised by TiO2: an ambiguous system. J. Photochem. Photobiol. A Chem. (1999). https://doi.org/10.1016/S1010-6030(99)00143-410.1016/S1010-6030(99)00143-4 ↗
38. F. Chen, Q. Yang, Y. Zhong, H. An, J. Zhao, Photocatalytic degradation of methylene blue using TiO₂–ZnO nanocomposites. Appl. Surf. Sci. 255, 3659–3666 (2009)10.1016/j.apsusc.2008.10.014 ↗
39. M.A. Rauf, S.S. Ashraf, Fundamental principles and application of heterogeneous photocatalytic degradation of dyes in solution. Chem. Eng. J. 151, 10–18 (2009)10.1016/j.cej.2009.02.026 ↗
40. S. Boudiaf, N. Nasrallah, M. Mellal, B. Belhamdi, C. Belabed, M.A. Djilali, M. Trari, Kinetic studies of Congo Red photodegradation on the hetero-system CoAl2O4/ZnO with a stirred reactor under solar light. J. Environ. Chem. Eng. 9, 105572 (2021)10.1016/j.jece.2021.105572 ↗
41. E. Ranjith kumar, R. Jayaprakash, M.S. Seehra, T. Prakash, S. Kumar, Effect of α-Fe₂O₃ phase on structural, magnetic and dielectric properties of Mn–Zn ferrite nanoparticles. J. Phys. Chem. Solids. 74, 943–949 (2013)10.1016/j.jpcs.2013.02.013 ↗
42. K. Winiarska, I. Szczygieł, R. Klimkiewicz, Manganese–Zinc Ferrite Synthesis by the Sol–Gel Autocombustion Method. Effect of the Precursor on the Ferrite’s Catalytic Properties, (2012)10.1021/ie301658q ↗
43. J. Kacher, C. Landon, B.L. Adams, D. Fullwood, Bragg’s law diffraction simulations for electron backscatter diffraction analysis. Ultramicroscopy 109, 1148–1156 (2009)10.1016/j.ultramic.2009.04.007 ↗
44. A. Mami, I. Saafi, T. Larbi, K. Ben Messaoud, N. Yacoubi, M. Amlouk, Unraveling the effect of thickness on the structural, morphological, opto-thermal and DFT calculation of hematite Fe2O3 thin films for photo-catalytic application. J. Mater. Sci. Mater. Electron. 32, 17974–17989 (2021)10.1007/s10854-021-06336-0 ↗
45. O. Kamoun, A. Mami, M.A. Amara, R. Vidu, M. Amlouk, Nanostructured Fe,Co-codoped MoO3 thin films. Micromachines 10, 138 (2019)10.3390/mi10020138 ↗
46. A. Mohseni-Bandpei, S.M. Ghasemi, A. Eslami, M. Rafiee, M. Sadani, F. Ghanbari, Degradation of atenolol by CuFe2O4 /visible light/oxidant: effects of electron acceptors, synergistic effects, degradation pathways, and mechanism. J. Photochem. Photobiol. A, Chem. 418, 113425 (2021)10.1016/j.jphotochem.2021.113425 ↗
47. D. Duong La, C.V. Tran, N.T. Hoang, M.D. Doan Ngoc, T.P. Nguyen, H.T. Vo, P.H. Ho, T.A. Nguyeng, S.V. Bhosale, X.C. Nguyen, S.W. Chang, W.J. Chung, D.D. Nguyen, Efficient photocatalysis of organic dyes under simulated sunlight irradiation by a novel magnetic CuFe2O4 @porphyrin nanofiber hybrid material fabricated via self-assembly. Fuel 281, 118655 (2020)
48. B. Janani, A. Syed, A.M. Thomas, S. Al-Rashed, A.M. Elgorban, L.L. Raju, S. Sudheer Khan, A Simple Approach for the Synthesis of bi-functional p-n Type ZnO@ CuFe 2O4 Heterojunction Nanocomposite for Photocatalytic and Antimicrobial Application, vol. 130 (Low-dimensional Systems and Nanostructures, Physica E, 2021), p.11466410.1016/j.physe.2021.114664 ↗
49. Z. Remeš, Z. Hubička, P. Hubík, Optical and transport properties of ZnO thin films prepared by reactive pulsed mid-frequency sputtering combined with RF ECWR plasma. Nanomaterials 15, 590 (2009)
50. X. Meng, H. Deng, L. Sun, P. Yang, J. Chu, Sulfurization temperature dependence of the structural transition in Cu2FeSnS4-based thin films. Mater. Lett. 161, 427–430 (2015)10.1016/j.matlet.2015.09.013 ↗
51. D. Beena, K.J. Lethy, R. Vinodkumar, V.P. Mahadevan Pillai, V. Ganesan, D.M. Phase, S.K. Sudheer, Effect of substrate temperature on structural, optical and electrical properties of pulsed laser ablated nanostructured indium oxide films. Appl. Surf. Sci. 255, 8334–8342 (2009)10.1016/j.apsusc.2009.05.057 ↗
52. G. Palanisamy, K. Bhuvaneswari, G. Bharathi, T. Pazhanivel, M. Dhanalakshmi, Improved photocatalytic performance of magnetically recoverable Bi2Te3/ CdS/ CuFe2O4 nanocomposite for MB dye under visible light exposure. Solid State Sci. 115, 106584 (2021)10.1016/j.solidstatesciences.2021.106584 ↗
53. L. Krushitha Shettya, H.P. Renuka, H. Nagaswarupa, K.S. Nagabhushana, D. Anantharajud, S.C. Rangappa, K. Prashantha, Ashwini, A comparative study on CuFe2O4, ZnFe2O4 and NiFe2O4: Morphology, Impedance and Photocatalytic studies, Materials Today: Proceedings 4 (2017) 11806–1181510.1016/j.matpr.2017.09.098 ↗
54. T.S. Moss, Optical properties of semiconductors. J. Phys. Chem. Solids i. 10, 345–346 (1961)
55. S. Belgacem, R. Bennaceur, Propriétés optiques des couches minces de SnO2 et CuInS2 airless spray. J. Phys. III 25, 1245–1258 (1990)
56. A.B. Nawale, N.S. Kanhe, S.A. Rout, S.V. Bhoraskar, A.K. Das, V.L. Mathe, Investigation of structural, optical and magnetic properties of thermal plasma synthesized Ni-Co spinel ferrite nanoparticles. Ceram. Int. 43, 6637–6647 (2017)10.1016/j.ceramint.2017.02.022 ↗
57. R. Dridi, I. Saafi, A. Mami, A. Amlouk, M. Amlouk, Physical study on NiFe2O4/ α- Fe2O3 composite-thin films for potential applications. Surfaces and Interfaces 21, 100743 (2020)10.1016/j.surfin.2020.100743 ↗
58. R.A.P. Ribeiro, M.C. Oliveira, M.R.D. Bomio, S.R. de Lazaro, J. Andrés, E. Longo, Connecting the surface structure, morphology and photocatalytic activity of Ag2O: an in depth and unified theoretical investigation. Applied Surface Science 509, 145321 (2020)
59. N.O. Etafo, A. Okmi, S. Dey, H. Alzahrani, A. Bamisaye, Influence and applications of refractive index on the catalytic performance of photo-responsive materials. Environmental Surfaces and Interfaces 3, 237–264 (2025)10.1016/j.esi.2025.09.004 ↗
60. X. Zhang, S. John, Photonic crystal light trapping for photocatalysis. Opt. Express. 29, 22376–22402 (2021)10.1364/OE.427218 ↗
61. J. Yu, J. Low, W. Xiao, P. Zhou, M. Jaroniec, Enhanced photocatalytic CO₂-reduction activity of anatase TiO2 by co‐exposed {001} and {101} facets. Journal of the American Chemical Society 136, 8839–8842 (2014)10.1021/ja5044787 ↗
62. K. Maeda, K. Domen, Photocatalytic water splitting: recent progress and future challenges. J. Phys. Chem. Lett. 1, 2655–2661 (2010)10.1021/jz1007966 ↗
63. N. Zhang, M.-Q. Yang, Z.-R. Tang, Y.-J. Xu, Understanding charge carrier separation and transfer in photocatalysis. ACS Nano 8, 623–633 (2014)10.1021/nn405242t ↗
64. J. Low, J. Yu, M. Jaroniec, S. Wageh, A.A. Al-Ghamdi, Heterojunction photocatalysts. Adv. Mater. 29, 1601694 (2017)
65. M. Irandost, R. Akbarzadeh, M. Pirsaheb, A. Asadi, P. Mohammadi, M. Sillanpää, Fabrication of highly visible active N, S co-doped TiO2@MoS2 heterojunction with synergistic effect for photocatalytic degradation of diclofenac: mechanisms, modeling and degradation pathway. J. Mol. Liq. 291, 111342 (2019)10.1016/j.molliq.2019.111342 ↗
66. N. Nasseh, A.H. Panahi, M. Esmati, N. Daglioglu, A. Asadi, H. Rajati, F. Khodadoost, Enhanced photocatalytic degradation of tetracycline from aqueous solution by a novel magnetically separable FeNi3/SiO2/ZnO nano-composite under simulated sunlight: efficiency, stability, and kinetic studies. J. Mol. Liq. 301, 112434 (2020)10.1016/j.molliq.2019.112434 ↗
67. A. Mohseni-Bandpei, S.M. Ghasemi, A. Eslami, M. Rafiee, M. Sadani, F. Ghanbari, Degradation of atenolol by CuFe2O4 /visible light/oxidant: effects of electron acceptors, synergistic effects, degradation pathways, and mechanism. J. Photochem. Photobiol. A, Chem. 418, 113425 (2021)10.1016/j.jphotochem.2021.113425 ↗
68. R.-R. Ding, W.-Q. Li, C.-S. He, Y.-R. Wang, X.-C. Liu, G.-N. Zhou, Yang Mu Appl. Catal. B: Environ. 291, 120069 (2021)10.1016/j.apcatb.2021.120069 ↗
69. M. Zangiabadi, A. Saljooqi, T. Shamspur, A. Mostafavi, Evaluation of GO nanosheets decorated by CuFe2O4 and CdS nanoparticles as photocatalyst for the degradation of dinoseb and imidacloprid pesticides. Ceram. Int. 46, 6124–6128 (2020)10.1016/j.ceramint.2019.11.076 ↗
70. U. Hisashi, T. Naoyuki, K. Minoru, The reactivities and the stabilities of the paramagnetic species formed on the surface of Al2O3, MoO3, CoO and SiO2. Journal of the Less Common Metals 36, 387–394 (1974)10.1016/0022-5088(74)90123-4 ↗
71. B. Janani, A. Syed, A.M. Thomas, S. Al-Rashed, A.M. Elgorban, L.L. Raju, S. Sudheer Khan, A simple approach for the synthesis of bi-functional p-n type ZnO@ CuFe2O4/ heterojunction nanocomposite for photocatalytic and antimicrobial application, 130 (2021) 11466410.1016/j.physe.2021.114664 ↗
72. A. Aslam, M.Z. Abid, K. Rafiq, A. Rauf, E. Hussain, Tunable sulphur doping on CuFe2O4/ nanostructures for the selective elimination of organic dyes from water. Sci. Rep. (2023). https://doi.org/10.1038/s41598-023-33185-010.1038/s41598-023-33185-0 ↗
73. A. Nurhaqi, B. Tamam Ibnu Ali, R. Subagyo, H. Rasyid, R. Maharani, D. Umaningrum, S. Fatma ati, R. Ediati, T. Gunawan, R. Asih, S. Akhlus, Y. Kusumawati, Visible light-driven removal of methylene blue through photocatalytic reaction using CuFe2O4/N-TiO2. Environ. Challenges 20, 101180 (2025)10.1016/j.envc.2025.101180 ↗
74. G. Zhang, Y. Liu, L. Wang, C. Zhou, Visible-light-driven photocatalytic activity of CuFe₂O₄ for organic pollutant degradation, Journal of Alloys and Compounds, 509 (2011)
75. N. Zhang, M.-Q. Yang, Z.-R. Tang, Y.J. Xu, Understanding charge carrier separation and transfer in photocatalysis, ACS Nano, 8 (2014) 623–63310.1021/nn405242t ↗
76. Y. Hou, X. Li, Q. Zhao, X.Quan, Spinel ferrite photocatalysts for visible-light-driven degradation of organic pollutants. Applied Catalysis B: Environmental, (2013) 142–143
77. N. Wang, L, Zhu, K. Deng, Y. She, Visible light photocatalysis of CuFe₂O₄: Synergistic effect of Fe³⁺/Fe²⁺ and Cu²⁺/Cu⁺ redox couples, Applied Catalysis B: Environmental, 95 (2010) 400–40710.1016/j.apcatb.2010.01.019 ↗
78. M.Z. Anam Aslam, K. Abid, Rafiq, Abdul Rauf & Ejaz Hussain Tunable sulphur doping on CuFe₂O₄ nanostructures for the selective elimination of organic dyes from water. Sci. Rep. 13, 6306 (2023)10.1038/s41598-023-33185-0 ↗