journal article·2026-04

Structure and magnetodielectric properties of the BiFe1-xCoxO3 solid solutions in the range x = 0–0.15

A. O. Galatova, D. I. Rudsky, D. V. Volkov, I. A. Verbenko, Yu. I. Yurasov, A. V. Nazarenko, Yu. V. Kabirov, K. P. Andryshin, I. N. Andryshina, L. A. Reznichenko, A. G. Rudskaya

Applied Physics A· Volume 132· Issue 4
Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Multiferroics and related materials · Magnetic Properties and Synthesis of Ferrites · Dielectric properties of ceramics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. S.Y. Yang, F. Zavaliche, L. Mohaddes-Ardabili, V. Vaithyanathan, D.G. Schlom, Y.J. Lee, Y.H. Chu, M.P. Cruz, Q. Zhan, T. Zhao, R. Ramesh, Metalorganic chemical deposition of lead-free ferroelectric films for memory application. Appl. Phys. Lett. 87, 102903 (2005)10.1063/1.2041830 ↗
2. B. Sun, G. Zhou, L. Sun, H. Zhao, Y. Chen, F. Yang, Y. Zhao, Q. Song, ABO3 multiferroic materials for memristive memory and neuromorphic computing. Nanoscale Horiz. 6, 939 (2021)10.1039/D1NH00292A ↗
3. H. Khan, T. Ahmad, Perspectives and scope of ABO3 type multiferroic rare-earth perovskites. Chin. J. Phys. 91, 199–219 (2024)10.1016/j.cjph.2024.07.004 ↗
4. V.G. Shrimali, K. Gadani, K.N. Rathod, B. Rajyaguru, A.D. Joshi, D.D. Pandya, P.S. Solanki, N.A. Shah, Sintering effect and magnetodielectric studies on nanostructured BiFe0. 95Co0. 05O3. Mater. Chem. Phys. 228, 98–109 (2019)10.1016/j.matchemphys.2019.02.040 ↗
5. F.L. Wang, Y. Li, N. Wang, L. Zhu, A. Jain, Y.G. Wang, F.G. Chen, Enhanced magnetic, ferroelectric and optical properties of Sr and Co co-doped BiFeO3 powders. J. Alloys Compd. 810, 151941 (2019)10.1016/j.jallcom.2019.151941 ↗
6. R.Q. Yin, B.W. Dai, P. Zheng, J.J. Zhou, W.F. Bai, F. Wen, J.X. Deng, L. Zheng, J. Du, H.B. Qin, Pure-phase BiFeO3 ceramics with enhanced electrical properties prepared by two-step sintering. Ceram. Int. 43(8), 6467–71 (2017)10.1016/j.ceramint.2017.02.063 ↗
7. J. Li, D.Z. Yan, Low-temperature synthesis of pure BiFeO3 phase and variation in its morphology with temperature. Ceram. Int. 44(15), 18271–18278 (2018)10.1016/j.ceramint.2018.07.038 ↗
8. G. Catalan, J.F. Scott, Physics and applications of bismuth ferrite. Adv. Mater. 21(24), 2463–2485 (2009)10.1002/adma.200802849 ↗
9. F. Gao, X.Y. Chen, K.B. Yin, S. Dong, Z.F. Ren, F. Yuan, T. Yu, Z.G. Zou, J.M. Liu, Visible-light photocatalytic properties of weak magnetic BiFeO3 nanoparticles. Adv. Mater. 19(19), 2889–92 (2007)10.1002/adma.200602377 ↗
10. Y. Guo, Y. Pu, Y. Cui, C. Hui, J. Wan, C. Cui, A simple method using citric acid as the template agent to improve photocatalytic performance of BiFeO3 nanoparticles. Mater. Lett. 196, 57–60 (2017)10.1016/j.matlet.2017.03.023 ↗
11. T. Gao, Z. Chen, F. Niu, D. Zhou, Q. Huang, Y. Zhu, L. Qin, X. Sun, Y. Huang, Shape-controlled preparation of bismuth ferrite by hydrothermal method and their visible-light degradation properties. J Alloys Compd 648, 564e570 (2015)10.1016/j.jallcom.2015.07.059 ↗
12. I.O. Krasnyakova, E.N. Sidorenko, A.O. Galatova, D.I. Rudsky, E.V. Glazunova, Y.A. Kuprina, A.V. Nazarenko, N.B. Kofanova, A.G. Rudskaya, Features of the structure, microstructure, radio-emitting and radio-absorbing properties of mechanically activated and non-mechanically activated ceramics BiFeO3. Solid State Phys. 65(4), 551–557 (2023)10.21883/PSS.2023.04.55994.543 ↗
13. A.P. Pyatakov, A.K. Zvezdin, Magnetoelectric and multiferroic media. Physics-Uspekhi 55(6), 557–581 (2012). https://doi.org/10.3367/UFNe.0182.201206b.059310.3367/UFNe.0182.201206b.0593 ↗
14. P. Royen, K. Swars, Das System Wismutoxyd-Eisenoxydim Bereich von 0 bis 55 Mol. % Eisenoxyd. Angew. Chem. 69(24), 779–779 (1957). https://doi.org/10.1002/ange.1957069240710.1002/ange.19570692407 ↗
15. A.I. Zaslavsky, A.G. Tutov, Structure of the new antiferromagnet BiFeO3. Dokl. AN SSSR 135(4), 815–817 (1960)
16. G.A. Smolenskii, V.A. Bokov, V.A. Isupov, N.N. Krainik, G.H. Nedlin, Magnetically ordered ferroelectrics. Helv. Phys. Acta 41, 1187–1198 (1968)
17. C. Michel, J.-M. Moreau, G.D. Achenbach, R. Gerson, W.J. James, The atomic structure of BiFeO3. Solid State Commun. 7(9), 701–704 (1969). https://doi.org/10.1016/0038-1098(69)90597-310.1016/0038-1098(69)90597-3 ↗
18. G. Catalan, J.F. Scott, Physics and applications of bismuth ferrite. Adv. Mater. 21, 2463–2485 (2009). https://doi.org/10.1002/adma.20080284910.1002/adma.200802849 ↗
19. V.M. Denisov, N.V. Belousova, V.P. Zhereb, L.T. Denisova, V.M. Skorikov, Oxide compounds of the bismuth(III) oxide–iron(III) oxide system. Obtaining and phase equilibrium. J. Sib. Fed. Univ. Chem. 2(5), 146–167 (2012)
20. M. Kubota, K. Oka, H. Yabuta, K. Miura, M. Azuma, Structure and magnetic properties of BiFe1-xCoxO3 and Bi0.9Sm0.1Fe1-xCoxO3. Inorg. Chem. 52, 10698–10704 (2013). https://doi.org/10.1021/ic402041p10.1021/ic402041p ↗
21. A.J. Mincache, D.Z. Montanher, D.M. Silva, I.A. Santos, R. Guo, A.S. Bhalla, Synthesis and study of ferroic properties BiFe1-yCoyO3 compositions. Integr. Ferroelectr. 166, 175–179 (2015). https://doi.org/10.1080/10584587.2015.109262510.1080/10584587.2015.1092625 ↗
22. G.L. Ye, J. Xu, J.A. Alonso, Z. Wang, Preparation of BiFe1-xCoxO3 ceramics via a simple solid method and enhanced multiferroic properties. Adv Mater Res 631, 452–457 (2013). https://doi.org/10.4028/www.scientific.net/AMR.631-632.45210.4028/www.scientific.net/AMR.631-632.452 ↗
23. L. Weston, X.Y. Cui, S.P. Ringer, C. Stampfl, Multiferroic crossover in perovskite oxides. Phys. Rev. B 93, 165210 (2016)10.1103/PhysRevB.93.165210 ↗
24. I.B. Bersuker, V. Polinger, Perovskite crystals: unique pseudo-Jahn-Teller origin of ferroelectricity, multiferrocity, permittivity, flexoelectricity, and polar nanoregions. Condensed Matter 5, 68 (2020). https://doi.org/10.3390/condmat504006810.3390/condmat5040068 ↗
25. W. Kraus, G. Nolze, Powder cell – a program for the representation and manipulation of crystal structures and calculation of the resulting X-ray powder patterns. J. Appl. Crystallogr. 29, 301–303 (1996). https://doi.org/10.1107/s002188989501492010.1107/s0021889895014920 ↗
26. Rusakov A.A. Radiography of metals. M.: Atomizdat, 1977. p. 480.
27. A.V. Turik, A.V. Pavlenko, A.V. Makhiboroda, L.A. Reznichenko, Dielectric relaxations, magnetodielectric and magnetoelectric interactions in Bi0. 6La0. 4MnO3 ceramics. Phys. Solid State 58(1), 97–101 (2016)10.1134/S1063783416010327 ↗
28. Y.I. Yurasov, A.V. Nazarenko, Parameter of dielectric loss distribution in the new model for complex conductivity based on Havriliak–Negami formula. J. Adv. Dielectr. 10(1, 2), 2060006 (2020). https://doi.org/10.1142/S2010135X2060006110.1142/S2010135X20600061 ↗
29. Y. Yurasov, A.V. Nazarenko, A new approach to dielectric spectra description based on the Havriliak–Negami model. Nauka Yuga Rossii 14(4), 35 (2018). https://doi.org/10.7868/S2500064018040510.7868/S25000640180405 ↗
30. Certificate of the state registration of the computer program No. 2019610938 RF. Program for predicting the frequency dependences of the dielectric spectra and electrical conductivity of ferro-piezomaterials depending on temperature and activation energy, taking into account the Gavriljak-Negami model: No. 2018665450: Appl. 12/28/2018: publ. January 18, 2019 / Yu. I. Yurasov, A. V. Pavlenko, A. V. Nazarenko; applicant SSC RAS.
31. J.M. Moreau, C. Michel, R. Gerson, W.J. James, Ferroelectric BiFeO3X-ray and neutron diffraction study. J. Phys. Chem. Solids 32, 1315–1320 (1971). https://doi.org/10.1016/S0022-3697(71)80189-010.1016/S0022-3697(71)80189-0 ↗
32. C.E. Infante, B. Carrasco, Stoichiometry and oxygen structure of Fe sillenite. Mater. Lett. 4(4), 194–197 (1986). https://doi.org/10.1016/0167-577x(86)90095-910.1016/0167-577x(86)90095-9 ↗
33. A.G. Tutov, V.N. Markin, The X-ray structural analysis of the antiferromagnetic Bi2Fe4O9 and the isotypical combinations Bi2Ga4O9 and Bi2Al4O9. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy IVNMA 6, 2014–2017 (1970)
34. I.K. Batttisha, I.S.A. Farag, M. Kamal, M.A. Ahmed, E. Girgis, H.A. el Meegi, F. el Desouki, Dielectric and magnetic properties of nano-structure BiFeO3 doped with different concentrations of Co ions prepared by sol-gel method. New J. Glass Ceram. 5, 59–73 (2015). https://doi.org/10.4236/njgc.2015.5300810.4236/njgc.2015.53008 ↗
35. E.I. Speranskaya, V.M. Skorikov, E.Y. Rud, V.A. Terekhova, Phase diagram of the bismuth oxide –iron oxide system. Izv. AN SSSR. Ser. Khim. 5, 905–906 (1965)
36. A. Maitre, M. Francois, J.C. Gachon, Experimental study of the Bi2O3-Fe2O3 pseudo-binary system. J. Phase Equilib. Diffus. 25(1), 59–67 (2004)10.1007/s11669-004-0171-0 ↗
37. Kh.A. Sadykov, E.D. Yatskovsky, L.A. Shilkina, I.A. Verbenko, S.I. Dudkina, K.P. Andryushin, G.M. Konstantinov, L.A. Reznichenko, Influence of oxides of 3d-metals and highly charged elements on the thermal stability of bismuth ferrite and its dielectric stability, In: Physics of lead-free piezoactive and related materials (Analysis of the current state and development prospects) ("LFPM-2018"). Proc. Seventh Int. Interdisc. Youth Symp. 2, 295–299 (2018).
38. L.A. Shilkina, K.P. Andryushin, S.I. Dudkina, I.N. Andryushina, L.A. Reznichenko X-ray studies of high-temperature multiferroic bismuth ferrite, unmodified and modified with rare earth elements, Sb. Mater, Russian-Ukrainian Intern. Symposium "Anomalous Properties of Solid Solutions from the Morphotropic Region of Multicomponent Oxides Containing 36 Metals", (2011) pp. 16–20.
39. G.-L. Song, X.-H. Zhou, J. Su, H.-G. Yang, T.-X. Wang, F.-G. Chang, Effects of Gd and Co doping on the electrical and ferromagnetism properties of BiFeO3 ceramics. Acta Phys. Sin. 61(17), 177501 (2012). https://doi.org/10.7498/aps.61.17750110.7498/aps.61.177501 ↗
40. L. Bai, M. Sun, W. Ma, J. Yang, J. Zhang, Y. Liu, Enhanced magnetic properties of Co-doped BiFeO3 thin films via structural progression. Nanomaterials 10, 1798 (2020). https://doi.org/10.3390/nano1009179810.3390/nano10091798 ↗
41. D.V. Thang, N.M. Hung, Effect of (Gd, Co) Co-Doping on Ferroelectric and Ferromagnetic Properties of BiFeO3 Material. ECS J. Solid State Sci. Technol. 14(5), 053002 (2025). https://doi.org/10.1149/2162-8777/adcc5210.1149/2162-8777/adcc52 ↗
42. I. Batttisha, I. Farag, M. Kamal, M. Ahmed, E. Girgis, F. Desouki, H. Meleegi, F. Desouki, Dielectric and magnetic properties of nano-structure BiFeO3 doped with different concentrations of Co ions prepared by sol-gel method. New J. Glass Ceram. 5, 59–73 (2015). https://doi.org/10.4236/njgc.2015.5300810.4236/njgc.2015.53008 ↗
43. A.I. Miller, A.A. Gusev, I.A. Verbenko, L.A. Shilkina, L.A. Reznichenko, Properties of mechanically activated bismuth ferrite. Bull. Russ. Acad. Sci. Phys. 76(7), 798–800 (2012). https://doi.org/10.3103/S106287381207025810.3103/S1062873812070258 ↗
44. V.A. Khomchenko, D.A. Kiselev, I.K. Bdikin, V.V. Shvartsman, P. Borisov, W. Kleemann, J.M. Vieira, A.L. Kholkin, Crystal structure and multiferroic properties of Gd-substituted BiFeO3. Appl. Phys. Lett. 93, 262905 (2008). https://doi.org/10.1063/1.305870810.1063/1.3058708 ↗
45. M. Masud, B.K. Chaudhuri, H.D. Yang, High dielectric permittivity and room temperature magneto-dielectric response of charge disproportionate La0.5Ba0.5FeO.3 perovskite. J. Phys. D Appl. Phys. 44, 255403 (2011). https://doi.org/10.1088/0022-3727/44/25/25540310.1088/0022-3727/44/25/255403 ↗
46. K.P. Andryushin, A.V. Turik, L.A. Shilkina, I.N. Andryushina, S.I. Dudkina, L.A. Reznichenko, Anisotropic magnetodielectric effect in the Bi1-xEuxFeO3 ceramics. Proceedings of the International Scientific and Technical Conference, 14-17 November 2011.
47. A.A. Pavelko, K.P. Andryushin, G.G. Gadzhiev, Z.M. Omarov, S.V. Khasbulatov, V.A. Aleshin, L.A. Shilkina, Phase and grain structure, dielectric and thermophysical properties of magnetoelectric solid solutions of the Bi1-xEuxFeO3 system, Proceedings of the International Scientific and Technical Conference, 1–5 December 2014.
48. S.V. Khasbulatov, A.A. Pavelko, G.G. Gadzhiev, L.A. Shilkina, L.A. Reznichenko, A.G. Bakmaev, V.A. Alyoshin, Z.M. Omarov, Phase transitions, thermophysical properties and dielectric spectroscopy of bismuth ferrite with small-dimensional REE. Bull. Causasian Technol. Univ. 17(20), 142–146 (2014)
49. S.N. Kallaev, S.A. Sadykov, Z.M. Omarov, A.Y. Kurbaitaev, L.A. Reznichenko, S.V. Khasbulatov, Dielectric properties and heat capacity of Bi1-xSmxFeO3 multiferroic. FTT 58(4), 664–666 (2016)