DataVXApplied Physics APaper
journal article·2026-02

Mechanistic Insights into Ta/Mn Co-Modification for Stable X9R 0.88BaTiO3-0.12Bi1/2Na1/2TiO3 Dielectrics with Reduced High-Temperature Dielectric Loss

Weilin Yang, Yongxing Wei, Bin Yang, Changqing Jin, Zhong Yang, Changpeng Guan, Haotian Zhou, Siyuan Dong, Ruihua Nan, Lin Hu, Ling Gao, Gang Xu, Zhonghua Dai

Applied Physics A· Volume 132· Issue 2
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OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Dielectric properties of ceramics

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References (44)

Show source-provided references
1. A. Zeb, S. Milne, High temperature dielectric ceramics: a review of temperature-stable high-permittivity perovskites. J. Mater. Sci. Mater. Electron. 26(12), 9243–9255 (2015). https://doi.org/10.1007/s10854-015-3707-710.1007/s10854-015-3707-7 ↗
2. L. Li, Y. Han, P. Zhang, C. Ming, X. Wei, Synthesis and characterization of BaTiO3-based X9R ceramics. J. Mater. Sci. 44(20), 5563–5568 (2009). https://doi.org/10.1007/s10853-009-3779-y10.1007/s10853-009-3779-y ↗
3. W. Jia, Y. Hou, M. Zheng, Y. Xu, M. Zhu, K. Yang, H. Cheng, S. Sun, J. Xing, Advances in lead-free high‐temperature dielectric materials for ceramic capacitor application. IET Nanodielectr. 1(1), 3–16 (2018). https://doi.org/10.1049/iet-nde.2017.000310.1049/iet-nde.2017.0003 ↗
4. X. He, F. Han, M. Liu, Z. Yuan, X. Jiang, C. Hu, S. Ren, X. Lei, L. Liu, High-temperature dielectric and relaxation behavior of tantalum-doped sodium bismuth titanate–barium titanate ceramics. J. Electron. Mater. 49(11), 6643–6655 (2020). https://doi.org/10.1007/s11664-020-08441-y10.1007/s11664-020-08441-y ↗
5. W. Zhang, J. Yang, F. Wang, X. Chen, H. Mao, Enhanced dielectric properties of La-doped 0.75BaTiO3–0.25Bi(Mg0.5Ti0.5)O3 ceramics for X9R-MLCC application. Ceramics Int. 47(4), 4486–4492 (2021). https://doi.org/10.1016/j.ceramint.2020.10.00910.1016/j.ceramint.2020.10.009 ↗
6. B. Jin, X. Xu, Forecasts of China mainland new energy index prices through Gaussian process regressions. J. Clean Energy Energy Storage 1, 2450006 (2024). https://doi.org/10.1142/S2811034X2450006010.1142/S2811034X24500060 ↗
7. B. Jin, X. Xu, Regional steel price index predictions for North China through machine learning. Int. J. Min. Miner. Eng. 15(3), 314–350 (2024). https://doi.org/10.1504/IJMME.2024.14069710.1504/IJMME.2024.140697 ↗
8. B. Jin, X. Xu, Forecasts of coking coal futures price indices through Gaussian process regressions. Min. Econ. 38(1), 203–217 (2025). https://doi.org/10.1007/s13563-024-00472-910.1007/s13563-024-00472-9 ↗
9. J. Yin, Z. Lv, J. He, J. Wu, W. Chen, X. Fang, T. Li, Enhancing dielectric stability in lead-free (Na0.25Ca0.25Sr0.25Bi0.25)TiO3 ceramics via Zr doping: microstructural and electrical property modulation. Ceram. Int. (2025). https://doi.org/10.1016/j.ceramint.2025.04.18210.1016/j.ceramint.2025.04.182 ↗
10. T. Li, Z. Qiao, R. Zuo, Ceram. Int. 48(2), 2533–2537 (2022). https://doi.org/10.1016/j.ceramint.2021.10.03510.1016/j.ceramint.2021.10.035 ↗
11. L. Li, J. Xie, M. Wang, K. Zhang, Colossal permittivity (Nb, Mg) co-doped BaTiO3 ceramics with excellent temperature stability and high insulation resistivity. Ceram. Int. 47(7), 10072–10078 (2021). https://doi.org/10.1016/j.ceramint.2020.12.15410.1016/j.ceramint.2020.12.154 ↗
12. Z. Lv, T. Lu, Z. Liu, T. Hu, Z. Hong, S. Guo, Z. Xu, Y. Song, Y. Chen, X. Zhao, Z. Lin, D. Yu, Y. Liu, G. Wang, NaNbO₃-based multilayer ceramic capacitors with ultrahigh energy storage performance. Adv. Energy Mater. 14(12), 2304291 (2024). https://doi.org/10.1002/aenm.20230429110.1002/aenm.202304291 ↗
13. L. Zhang, B. Cui, R. Ma, L. Li, Y. Wang, W. Yan, Z. Chang, High permittivity of Ba(Ti1-xZrx)O3-based Y5V-type nanopowders and ceramics synthesized using a one-step sol–gel method. J. Adv. Dielectrics. 3(04), 1350018 (2013). https://doi.org/10.1142/S2010135X1350018510.1142/S2010135X13500185 ↗
14. K. Xue, J. Xie, M. Wang, L. Li, Defect structure and dielectric properties of Mn-doped X8R BaTiO3-based ceramics with high permittivity: experiments and first-principles calculations. Ceram. Int. 49(11), 16514–16523 (2023). https://doi.org/10.1016/j.ceramint.2022.12.04310.1016/j.ceramint.2022.12.043 ↗
15. H. Zhao, W. Cao, C. Liang, C. Wang, C. Wang, High energy-storage performance in X9R-type Na0.5Bi0.5TiO3-based lead-free ceramics. Ceram. Int. 49(10), 15939–15946 (2023). https://doi.org/10.1016/j.ceramint.2023.01.18910.1016/j.ceramint.2023.01.189 ↗
16. X. Cheng, Y. Zhen, M. Xiao, P. Zhao, K. Hui, W. Zhang, Y. Jiang, L. Guo, Z. Fu, X. Cao, H. Wang, X. Wang, Diffusion and defect chemistry of temperature-stable BaTiO3-based ceramics: experiment and theoretical calculations. J. Eur. Ceram. Soc. 45(1), 116825 (2025). https://doi.org/10.1016/j.jeurceramsoc.2024.11682510.1016/j.jeurceramsoc.2024.116825 ↗
17. L. Chen, H. Wang, P. Zhao, Z. Shen, C. Zhu, Z. Cen, L. Li, X. Wang, Effect of MnO2 on the dielectric properties of Nb-doped BaTiO3-(Bi0.5Na0.5)TiO3 ceramics for X9R MLCC applications. J. Am. Ceram. Soc. 102(5), 2781–2790 (2019). https://doi.org/10.1111/jace.1615710.1111/jace.16157 ↗
18. B. Tang, S. Zhang, X. Zhou, Y. Yuan, L. Yang, Preparation and modification of high Curie point BaTiO3-based X9R ceramics. J. Electroceram. 25(1), 93–97 (2010). https://doi.org/10.1007/s10832-009-9594-710.1007/s10832-009-9594-7 ↗
19. S.V. Grabovsky, I.V. Shnaidshtein, M. Takesada, A. Onodera, B.A. Strukov, Calorimetric study of ferroelectric BaTiO3 in cubic phase. J. Adv. Dielectr. 3(04), 1350032 (2013). https://doi.org/10.1142/S2010135X1350032X10.1142/S2010135X1350032X ↗
20. X. Zhou, G. Xue, H. Luo, Chris R.. Bowen, D. Zhang, Phase structure and properties of sodium bismuth titanate lead-free piezoelectric ceramics. Prog. Mater. Sci. 122, 100836 (2021). https://doi.org/10.1016/j.pmatsci.2021.10083610.1016/j.pmatsci.2021.100836 ↗
21. W. Jia, Y. Hou, M. Zheng, M. Zhu, High-temperature dielectrics based on (1 − x)[0.94Bi0.5Na0.5TiO3–0.06BaTiO3]–xNaNbO₃ system. J. Alloys Compd. 724, 306–315 (2017). https://doi.org/10.1016/j.jallcom.2017.07.03010.1016/j.jallcom.2017.07.030 ↗
22. Y. Jiao, S. Song, F. Chen, X. Zeng, X. Wang, C. Song, G. Liu, Y. Yan, Energy storage performance of 0.55Bi0.5Na0.5TiO3–0.45SrTiO3 ceramics doped with lanthanide elements (Ln = La, Nd, Dy, Sm) using a viscous polymer processing route. Ceram. Int. 48(8), 10885–10894 (2022). https://doi.org/10.1016/j.ceramint.2021.12.30510.1016/j.ceramint.2021.12.305 ↗
23. Y. Zhang, X. Xu, Machine learning the lattice constant of cubic pyrochlore compounds. Int. J. Appl. Ceram. Technol. 18(3), 661–676 (2021). https://doi.org/10.1007/s00269-020-01108-410.1007/s00269-020-01108-4 ↗
24. Y. Zhang, X. Xu, Gaussian process modeling of doped-lanthanum manganites Curie temperature from compositions and ionic radii. Solid State Commun. 360, 115025 (2023). https://doi.org/10.1016/j.ssc.2022.11502510.1016/j.ssc.2022.115025 ↗
25. Y. Zhang, X. Xu, Curie temperature modeling of magnetocaloric lanthanum manganites using Gaussian process regression. J. Magn. Magn. Mater. 512, 166998 (2020). https://doi.org/10.1016/j.jmmm.2020.16699810.1016/j.jmmm.2020.166998 ↗
26. Y. Zhang, X. Xu, Modeling oxygen ionic conductivities of ABO3 perovskites through machine learning. Chem. Phys. 558, 111511 (2022). https://doi.org/10.1016/j.chemphys.2022.11151110.1016/j.chemphys.2022.111511 ↗
27. Y. Zhang, X. Xu, Machine learning lattice constants from ionic radii and electronegativities for cubic perovskite A2XY6 compounds. Phys. Chem. Miner. 47(9), 39 (2020). https://doi.org/10.1007/s00269-020-01108-410.1007/s00269-020-01108-4 ↗
28. S. Wang, Y. Hsu, Y. Hung, Y. Liu, Effect of Ta2O5 and Nb2O5 dopants on the stable dielectric properties of BaTiO3–(Bi0.5Na0.5)TiO3-based materials. Appl. Sci. 5(4), 1221–1234 (2015). https://doi.org/10.3390/app504122110.3390/app5041221 ↗
29. G. Yao, X. Wang, Y. Wu, L. Li, Nb-doped 0.9BaTiO3–0.1(Bi0.5Na0.5)TiO3 ceramics with stable dielectric properties at high temperature. J. Am. Ceram. Soc. 95(2), 614–618 (2012). https://doi.org/10.1111/j.1551-2916.2011.04793.x10.1111/j.1551-2916.2011.04793.x ↗
30. Y. Wu, M. Lu, C. Huang, Y. Yeh, P. Chen, K. Feng, Microstructures and dielectric properties analysis of BaTiO3–Bi0.5Na0.5TiO3–Nb2O5–MgO-based dielectric ceramics. Mater. Res. Bull. 179, 112963 (2024). https://doi.org/10.1016/j.materresbull.2024.11296310.1016/j.materresbull.2024.112963 ↗
31. Z. Shen, X. Wang, L. Li, Dielectric properties and microstructures of Ta-doped BaTiO3–(Bi0.5Na0.5)TiO3 ceramics for X9R applications. J. Mater. Sci. Mater. Electron. 28(4), 3768–3773 (2017). https://doi.org/10.1007/s10854-016-5986-z10.1007/s10854-016-5986-z ↗
32. Z. Shen, X. Wang, L. Li, Nb-doped BaTiO3-(Bi0.5Na0.5)TiO3 ceramics with core-shell structure for high-temperature dielectric applications. Adv. Appl. Ceram. 115(7), 435–442 (2016). https://doi.org/10.1080/17436753.2016.118181410.1080/17436753.2016.1181814 ↗
33. L. Li, J. Chen, D. Guo, N. Zhang, M. Wang, Y. Liu, An ultra-broad working temperature dielectric material obtained with Praseodymium doped BaTiO3–(Bi0.5Na0.5)TiO3–Nb2O5 based ceramics. Ceram. Int. 40(8), 12539–12543 (2014). https://doi.org/10.1016/j.ceramint.2014.03.09110.1016/j.ceramint.2014.03.091 ↗
34. Y. Zheng, Z. Dai, C. Liu, X. Li, X. Zhao, Y. Cong, S. Gu, Enhancing energy storage performance of BT-based ceramics by doping modification. Mater. Sci. Semicond. Process. 196, 109656 (2025). https://doi.org/10.1016/j.mssp.2025.10965610.1016/j.mssp.2025.109656 ↗
35. S. Mo, S. Hu, N. Wang, H. Zhang, P. Zhu, X. Wen, S. Dai, F. Zhang, T. Li, J. Liu, X. Zheng, Temperature-stable dielectric properties of Nb2O5-doped BaTiO3-based ceramics with fine grain via controlling grain growth. Ceram. Int. 51(18), 26791–26798 (2025). https://doi.org/10.1016/j.ceramint.2025.03.36010.1016/j.ceramint.2025.03.360 ↗
36. J. Pokorný, U. Pasha, L. Ben, O. Thakur, D. Sinclair, I.M. Reaney, J. Appl. Phys. 109(11), 114110 (2011). https://doi.org/10.1063/1.359219210.1063/1.3592192 ↗
37. B. Begg, K. Finnie, E. Vance, Raman study of the relationship between room-temperature tetragonality and the curie point of barium titanate. J. Am. Ceram. Soc. 79(10), 2666–2672 (1996). https://doi.org/10.1111/j.1151-2916.1996.tb09032.x10.1111/j.1151-2916.1996.tb09032.x ↗
38. G. Yang, Z. Yue, T. Sun, J. Zhao, Z. Yang, L. Li, Investigation of ferroelectric phase transition for modified barium titanate in multilayer ceramic capacitors by in situ Raman scattering and dielectric measurement. Appl. Phys. A 91(1), 119–125 (2008). https://doi.org/10.1007/s00339-007-4370-510.1007/s00339-007-4370-5 ↗
39. Y. Wei, J. Niu, S. Dong, L. Xia, C. Jin, R. Nan, Z. Jian, Z. Xi, Z. Dai, L. Jin, Ultra-high electrostrain in flux-grown (Bi0.5Na0.5)TiO3-0.06BaTiO3-0.03(K0.5Na0.5)NbO3 single crystals around the nonergodic/ergodic crossover region. Scripta Mater. 250, 116201 (2024). https://doi.org/10.1016/j.scriptamat.2024.11620110.1016/j.scriptamat.2024.116201 ↗
40. C. Guan, Y. Wei, C. Jin, J. Niu, Y. Deng, R. Nan, Z. Jian, Z. Xi, Z. Dai, R.G. Burkovsky, L. Jin, Temperature-Driven evolution of Polar States and phase transitions in 92(Bi0.5Na0.5)TiO3-8BiAlO3 single crystals near the morphotropic phase boundary. 45 (16), 117702 (2025). https://doi.org/10.1016/j.jeurceramsoc.2025.11770210.1016/j.jeurceramsoc.2025.117702 ↗
41. C. Guan, Y. Wei, S. Dong, L. Xia, C. Jin, R. Nan, L. Hu, L. Gao, Enhanced piezoelectric performance and improved polarization in 0.9(Na0.5Bi0.5)TiO3–0.1SrTiO3 single crystals via flux growth method. J. Alloys Compd. 1007, 176365 (2024). https://doi.org/10.1016/j.jallcom.2024.17636510.1016/j.jallcom.2024.176365 ↗
42. C. Guan, Y. Wei, S. Dong, C. Jin, W. Yang, Z. Dai, W. Liu, L. Jin, Insights into the structure and electrical properties of Bi0.5Na0.5TiO3–PbTiO3 single crystals near the morphotropic phase boundary. Cryst. Growth Des. 25(9), 3048–3057 (2025). https://doi.org/10.1021/acs.cgd.5c0010410.1021/acs.cgd.5c00104 ↗
43. V. Schmidt, N. Archer, C. Tu, Impedance spectroscopy of bismuth sodium titanate–barium titanate ceramics with manganese doping. J. Am. Ceram. Soc. 101(2), 713–722 (2018). https://doi.org/10.1111/jace.1523610.1111/jace.15236 ↗
44. S. Bouzidi, A. Ben Hassen, J. Dhahri, K. Khirouni, Structural and dielectric properties of BaTi0.5(Co0.33Mo0.17)O3 perovskite ceramic. J. Alloys Compd. 781, 936–944 (2019). https://doi.org/10.1016/j.jallcom.2018.11.02610.1016/j.jallcom.2018.11.026 ↗