DataVXApplied Physics APaper
journal article·2025-04

Studies on morphology, conduction mechanism and dielectric properties of Li2ZrO3 prepared using solid-state reaction

Imen Ibrahmi, Samia Aydi, Sondes Hajlaoui, Raja Naouari, Iskandar Chaabane, Abderrazek Oueslati

Applied Physics A· Volume 131· Issue 4
Publisher page
Bibliographic record

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (66)

Show source-provided references
1. E.E. Hellstrom, W. Van Gool, ChemInform Abstract: constraints for the selection of lithium solid electrolytes. Chemischer Informationsdienst 12(14), 1–52 (1981). https://doi.org/10.1002/chin.19811436010.1002/chin.198114360 ↗
2. I. Abrahams, P. Lightfoot, P.G. Bruce, Li6Zr2O7, a new anion vacancy ccp based structure, determined by ab initio powder diffraction methods. J. Solid State Chem. 104(2), 397–403 (1993). https://doi.org/10.1006/jssc.1993.117510.1006/jssc.1993.1175 ↗
3. Y. Dong, Y. Zhao, H. Duan, J. Huang, Electrochemical performance and lithium-ion insertion/extraction mechanism studies of the novel Li2ZrO3 anode materials. Electrochim. Acta 161, 219–225 (2015). https://doi.org/10.1016/j.electacta.2015.01.22010.1016/j.electacta.2015.01.220 ↗
4. G.P. Wyers, E.H.P. Cordfunke, Phase relations in the system Li2O-ZrO2. J. Nucl. Mater. 168(1–2), 24–30 (1989). https://doi.org/10.1016/0022-3115(89)90560-610.1016/0022-3115(89)90560-6 ↗
5. P. Quintana, A.R. West, Compound formation and phase equilibria in the system Li4SiO4-LiGaSiO4. J. Solid State Chem. 81(2), 257–270 (1989). https://doi.org/10.1016/0022-4596(89)90013-310.1016/0022-4596(89)90013-3 ↗
6. E. Hellstrom, W. Vangool, Li ion conduction in Li2ZrO3, Li4ZrO4, and LiScO2. Solid State Ionics 2(1), 59–64 (1981). https://doi.org/10.1016/0167-2738(81)90021-710.1016/0167-2738(81)90021-7 ↗
7. M.I. Pantyukhina, G.V. Zelyutin, N.N. Batalov, V.P. Obrosov, Effect of substituting 6Li for 7Li on ionic conductivity of α-Li3BO3. Russ. J. Electrochem. 36(7), 792–795 (2000). https://doi.org/10.1007/bf0275768310.1007/bf02757683 ↗
8. M.I. Pantyukhina, PYu. Shevelin, E.A. Suslov, N.N. Batalov, Synthesis and electrochemical properties of lithium-vanadium LixV2O5 (x = 0.1–0.3) bronzes. Russ. Metall. (Metally) 2018(2), 205–207 (2018). https://doi.org/10.1134/s003602951802015510.1134/s0036029518020155 ↗
9. E.A. Sherstobitova, A.F. Gubkin, I.A. Bobrikov, A.V. Kalashnova, M.I. Pantyukhina, Bottle-necked ionic transport in Li2ZrO3: high temperature neutron diffraction and impedance spectroscopy. Electrochim. Acta 209, 574–581 (2016). https://doi.org/10.1016/j.electacta.2016.05.11310.1016/j.electacta.2016.05.113 ↗
10. S. Zhang, H. Zhao, J. Wang, T. Xu, K. Zhang, Z. Du, Enhanced densification and ionic conductivity of Li-garnet electrolyte: efficient Li2CO3 elimination and fast grain-boundary transport construction. Chem. Eng. J. 393, 124797 (2020). https://doi.org/10.1016/j.cej.2020.12479710.1016/j.cej.2020.124797 ↗
11. B. Wu et al., Good practices for rechargeable lithium metal batteries. J. Electrochem. Soc. 166(16), A4141–A4149 (2019). https://doi.org/10.1149/2.0691916jes10.1149/2.0691916jes ↗
12. D.H.S. Tan, A. Banerjee, Z. Chen, Y.S. Meng, From nanoscale interface characterization to sustainable energy storage using all-solid-state batteries. Nat. Nanotechnol. 15(3), 170–180 (2020). https://doi.org/10.1038/s41565-020-0657-x10.1038/s41565-020-0657-x ↗
13. J.C. Bachman et al., Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction. Chem. Rev. 116(1), 140–162 (2015). https://doi.org/10.1021/acs.chemrev.5b0056310.1021/acs.chemrev.5b00563 ↗
14. J. Li, C. Ma, M. Chi, C. Liang, N.J. Dudney, Lithium-ion batteries: solid electrolyte: the key for high-voltage lithium batteries (Adv. Energy Mater. 4/2015). Adv. Energy Mater. (2015). https://doi.org/10.1002/aenm.20157001810.1002/aenm.201570018 ↗
15. M.Q. Li, M.Z. Qu, X.Y. He, Z.L. Yu, Electrochemical properties of Li2ZrO3-coated silicon/graphite/carbon composite as anode material for lithium ion batteries. J. Power. Sources 188(2), 546–551 (2009). https://doi.org/10.1016/j.jpowsour.2008.12.01010.1016/j.jpowsour.2008.12.010 ↗
16. B. Song, W. Li, S.-M. Oh, A. Manthiram, Long-life nickel-rich layered oxide cathodes with a uniform Li2ZrO3 surface coating for lithium-ion batteries. ACS Appl. Mater. Interfaces 9(11), 9718–9725 (2017). https://doi.org/10.1021/acsami.7b0007010.1021/acsami.7b00070 ↗
17. X. Zhan, Y. Cheng, M. Shirpour, Nonstoichiometry and Li-ion transport in lithium zirconate: the role of oxygen vacancies. J. Am. Ceram. Soc. 101(9), 4053–4065 (2018). https://doi.org/10.1111/jace.1558310.1111/jace.15583 ↗
18. S. Hao, H. Zhang, W. Yao, J. Lin, Solid-state lithium battery chemistries achieving high cycle performance at room temperature by a new garnet-based composite electrolyte. J. Power. Sources 393, 128–134 (2018). https://doi.org/10.1016/j.jpowsour.2018.05.02810.1016/j.jpowsour.2018.05.028 ↗
19. Q. Xiao, X. Tang, Y. Liu, Y. Zhong, W. Zhu, Citrate route to prepare K-doped Li2ZrO3 sorbents with excellent CO2 capture properties. Chem. Eng. J. 174(1), 231–235 (2011). https://doi.org/10.1016/j.cej.2011.09.00510.1016/j.cej.2011.09.005 ↗
20. C. Vincent, Lithium batteries: a 50-year perspective, 1959–2009. Solid State Ionics 134(1–2), 159–167 (2000). https://doi.org/10.1016/s0167-2738(00)00723-210.1016/s0167-2738(00)00723-2 ↗
21. L. Montanaro, A. Negro, J.P. Lecompte, Lithium metazirconate for nuclear application: physical and mechanical properties. J. Mater. Sci. 30(17), 4335–4338 (1995). https://doi.org/10.1007/bf0036151310.1007/bf00361513 ↗
22. L. Pang, D. Zhou, Microwave dielectric properties of low-firing Li2MO3 (M=Ti, Zr, Sn) ceramics with B2O3–CuO addition. J. Am. Ceram. Soc. 93(11), 3614–3617 (2010). https://doi.org/10.1111/j.1551-2916.2010.04152.x10.1111/j.1551-2916.2010.04152.x ↗
23. J.J. Bian, Y.F. Dong, New high Q microwave dielectric ceramics with rock salt structures: (1–x)Li2TiO3+xMgO system (0≤x≤0.5). J. Eur. Ceram. Soc. 30(2), 325–330 (2010). https://doi.org/10.1016/j.jeurceramsoc.2009.04.03010.1016/j.jeurceramsoc.2009.04.030 ↗
24. C.L. Huang, Y.W. Tseng, J.Y. Chen, High-Q dielectrics using ZnO-modified Li2TiO3 ceramics for microwave applications. J. Eur. Ceram. Soc. 32(12), 3287–3295 (2012). https://doi.org/10.1016/j.jeurceramsoc.2012.03.03010.1016/j.jeurceramsoc.2012.03.030 ↗
25. J. Liang, W.Z. Lu, J.M. Wu, J.G. Guan, Microwave dielectric properties of Li2TiO3 ceramics sintered at low temperatures. Mater. Sci. Eng. B 176(2), 99–102 (2011). https://doi.org/10.1016/j.mseb.2010.09.00910.1016/j.mseb.2010.09.009 ↗
26. Y.Z. Hao, H. Yang, G.H. Chen, Q.L. Zhang, Microwave dielectric properties of Li2TiO3 ceramics doped with LiF for LTCC applications. J. Alloy. Compd. 552, 173–179 (2013). https://doi.org/10.1016/j.jallcom.2012.10.11010.1016/j.jallcom.2012.10.110 ↗
27. T. Kulsartov et al., Studies of two-phase lithium ceramics Li4SiO4-Li2TiO3 under conditions of neutron irradiation. Nuclear Materials and Energy 30, 101129 (2022). https://doi.org/10.1016/j.nme.2022.10112910.1016/j.nme.2022.101129 ↗
28. G. Tan, S. Song, X. Hu, L. Cai, Y. Li, Y. Zhang, Efficient fabrication of high strength Li2TiO3 ceramic pebbles via improved rolling ball method assisted by sesbania gum binder. Ceram. Int. 47(19), 26978–26990 (2021). https://doi.org/10.1016/j.ceramint.2021.06.11110.1016/j.ceramint.2021.06.111 ↗
29. L. Yang et al., Li2ZrO3 based Li-ion conductors doped with halide ions & sintered in oxygen-deficient atmosphere. Ceram. Int. 47(22), 31907–31914 (2021). https://doi.org/10.1016/j.ceramint.2021.08.07610.1016/j.ceramint.2021.08.076 ↗
30. J.X. Bi, C.F. Xing, C.H. Yang, H.T. Wu, Phase composition, microstructure and microwave dielectric properties of rock salt structured Li2ZrO3–MgO ceramics. J. Eur. Ceram. Soc. 38(11), 3840–3846 (2018). https://doi.org/10.1016/j.jeurceramsoc.2018.04.03410.1016/j.jeurceramsoc.2018.04.034 ↗
31. L. Yang, H. Zhang, J. Chen, H. Chen, Z. Li, Electrical conductivity of Al-doped Li2ZrO3 ceramics for Li-ion conductor electrolytes. Ceram. Int. 47(13), 17950–17955 (2021). https://doi.org/10.1016/j.ceramint.2021.03.10810.1016/j.ceramint.2021.03.108 ↗
32. D. Chattaraj, Structural, electronic, elastic and thermodynamic properties of Li2ZrO3: a comprehensive study using DFT formalism. J. Nucl. Mater. 496, 286–292 (2017). https://doi.org/10.1016/j.jnucmat.2017.09.04010.1016/j.jnucmat.2017.09.040 ↗
33. D.I. Shlimas, A.L. Kozlovskiy, M.V. Zdorovets, A.A. Khametova, Study of radiation damage processes caused by hydrogen embrittlement in lithium ceramics under high-temperature irradiation. Ceramics 5(3), 447–458 (2022). https://doi.org/10.3390/ceramics503003410.3390/ceramics5030034 ↗
34. B. Rasneur, M. Boncoeur, A.M. Lejus, R. Collongues, Doping of porous lithium aluminate for a fusion reactor blanket. Fusion Technol. 1990, 929–933 (1991). https://doi.org/10.1016/b978-0-444-88508-1.50171-710.1016/b978-0-444-88508-1.50171-7 ↗
35. H. Pfeiffer, P. Bosch, Thermal stability and high-temperature carbon dioxide sorption on hexa-lithium zirconate (Li6Zr2O7). Chem. Mater. 17(7), 1704–1710 (2005). https://doi.org/10.1021/cm047897+10.1021/cm047897+ ↗
36. Q. Wang, L. Qi, Y. Jia, H. Li, Electromagnetic absorption properties of sibcnoxzr ceramics with high-temperature oxidation resistance (2023). https://doi.org/10.2139/ssrn.445106610.2139/ssrn.4451066 ↗
37. R.P. Rao, M.V. Reddy, S. Adams, B.V.R. Chowdari, Preparation and mobile ion transport studies of Ta and Nb doped Li6Zr2O7 Li-fast ion conductors. Mater. Sci. Eng. B 177(1), 100–105 (2012). https://doi.org/10.1016/j.mseb.2011.09.01510.1016/j.mseb.2011.09.015 ↗
38. S. Huang, B.E. Wilson, W.H. Smyrl, D.G. Truhlar, A. Stein, Transition-metal-doped M-Li8ZrO6 (M = Mn, Fe Co, Ni, Cu, Ce) as high-specific-capacity li-ion battery cathode materials: synthesis, electrochemistry, and quantum mechanical characterization. Chem. Mater. 28(3), 746–755 (2016). https://doi.org/10.1021/acs.chemmater.5b0355410.1021/acs.chemmater.5b03554 ↗
39. S. Huang et al., Y-doped Li8ZrO6: a li-ion battery cathode material with high capacity. J. Am. Chem. Soc. 137(34), 10992–11003 (2015). https://doi.org/10.1021/jacs.5b0469010.1021/jacs.5b04690 ↗
40. M. Zocchi, I.N. Sora, L.E. Depero, R.S. Roth, A single-crystal X-ray diffraction study of lithium zirconate, Li6Zr2O7, a solid-state ionic conductor. J. Solid State Chem. 104(2), 391–396 (1993). https://doi.org/10.1006/jssc.1993.117410.1006/jssc.1993.1174 ↗
41. Y. Liao, P. Singh, K.-S. Park, W. Li, J.B. Goodenough, Li6Zr2O7 interstitial lithium-ion solid electrolyte. Electrochim. Acta 102, 446–450 (2013). https://doi.org/10.1016/j.electacta.2013.04.02910.1016/j.electacta.2013.04.029 ↗
42. Y.V. Baklanova et al., Synthesis and physicochemical properties of Li2MexZr1-xO3 − δ (Me = Nb, Ti; x = 0.05, 0.1) solid solutions. Bull. Russ. Acad. Sci. Phys. 78(4), 320–322 (2014). https://doi.org/10.3103/s106287381404005410.3103/s1062873814040054 ↗
43. K. Mukai, M. Yashima, K. Hibino, T. Terai, Experimental visualization of interstitialcy diffusion of li ion in β-Li2TiO3. ACS Appl. Energy Mater. 2(8), 5481–5489 (2019). https://doi.org/10.1021/acsaem.9b0063910.1021/acsaem.9b00639 ↗
44. W. Liu, R. Zuo, A novel Li2TiO3–Li2CeO3 ceramic composite with excellent microwave dielectric properties for low-temperature cofired ceramic applications. J. Eur. Ceram. Soc. 38(1), 119–123 (2018). https://doi.org/10.1016/j.jeurceramsoc.2017.07.03210.1016/j.jeurceramsoc.2017.07.032 ↗
45. T. Hoshino, Pebble fabrication of super advanced tritium breeders using a solid solution of Li2+xTiO3+y with Li2ZrO3. Nucl. Mater. Energy 9, 221–226 (2016). https://doi.org/10.1016/j.nme.2016.05.00410.1016/j.nme.2016.05.004 ↗
46. R.M. Arons, R.B. Poeppel, M. Tetenbaum, C.E. Johnson, Preparation, characterization, and chemistry of solid ceramic breeder materials. J. Nucl. Mater. 103, 573–577 (1981). https://doi.org/10.1016/0022-3115(82)90660-210.1016/0022-3115(82)90660-2 ↗
47. H. Kleykamp, Enthalpies and heat capacities of Li2SiO3 and Li2ZrO3 between 298 and 1400 K by drop calorimetry. Thermochim. Acta 237(1), 1–12 (1994). https://doi.org/10.1016/0040-6031(94)85178-610.1016/0040-6031(94)85178-6 ↗
48. H. Pfeiffer, K.M. Knowles, Reaction mechanisms and kinetics of the synthesis and decomposition of lithium metazirconate through solid-state reaction. J. Eur. Ceram. Soc. 24(8), 2433–2443 (2004). https://doi.org/10.1016/s0955-2219(03)00630-710.1016/s0955-2219(03)00630-7 ↗
49. Y. Takahashi, T. Ohsato, T. Terai, Anomalous behavior in thermal properties of lithium metazirconate (Li2ZrO3). Fusion Eng. Des. 17, 25–29 (1991). https://doi.org/10.1016/0920-3796(91)90031-k10.1016/0920-3796(91)90031-k ↗
50. W. Zuo et al., Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques. Energy Environ. Sci. 13(12), 4450–4497 (2020). https://doi.org/10.1039/d0ee01694b10.1039/d0ee01694b ↗
51. R. Marom, S.F. Amalraj, N. Leifer, D. Jacob, D. Aurbach, A review of advanced and practical lithium battery materials. J. Mater. Chem. 21(27), 9938 (2011). https://doi.org/10.1039/c0jm04225k10.1039/c0jm04225k ↗
52. J. Rodriguez-Carvajal, Magnetic structure determination from powder diffraction using the program FullProf. Appl. Crystallogr. (2001). https://doi.org/10.1142/9789812811325_000510.1142/9789812811325_0005 ↗
53. M. Wu, B. Xu, C. Ouyang, Physics of electron and lithium-ion transport in electrode materials for Li-ion batteries. Chin. Phys. B 25(1), 018206 (2016). https://doi.org/10.1088/1674-1056/25/1/01820610.1088/1674-1056/25/1/018206 ↗
54. I. Gharbi, A. Oueslati, A. Bulou, M. Gargouri, Using Raman spectroscopy and structural properties in understanding the ferroelectric nature of the RbMgPO4 phase transitions. Mater. Res. Bull. 139, 111250 (2021). https://doi.org/10.1016/j.materresbull.2021.11125010.1016/j.materresbull.2021.111250 ↗
55. M. Enneffati, B. Louati, K. Guidara, M. Rasheed, R. Barillé, Crystal structure characterization and AC electrical conduction behavior of sodium cadmium orthophosphate. J. Mater. Sci. Mater. Electron. 29(1), 171–179 (2017). https://doi.org/10.1007/s10854-017-7901-710.1007/s10854-017-7901-7 ↗
56. N. Xu et al., Dependence of critical radius of the cubic perovskite ABO3 oxides on the radius of A- and B-site cations. Int. J. Hydrogen Energy 35(14), 7295–7301 (2010). https://doi.org/10.1016/j.ijhydene.2010.04.14910.1016/j.ijhydene.2010.04.149 ↗
57. Y. Moualhi et al., Magnetic properties and impedance spectroscopic analysis in Pr0.7Ca0.3Mn0.95Fe0.05O3 perovskite ceramic. J. Mater. Sci. Mater. Electron. 31(23), 21046–21058 (2020). https://doi.org/10.1007/s10854-020-04617-810.1007/s10854-020-04617-8 ↗
58. M. Okutan, E. Basaran, H.I. Bakan, F. Yakuphanoglu, AC conductivity and dielectric properties of Co-doped TiO2. Physica B 364(1–4), 300–305 (2005). https://doi.org/10.1016/j.physb.2005.04.02710.1016/j.physb.2005.04.027 ↗
59. N. Kumar, A. Dutta, S. Prasad, T.P. Sinha, Dielectric relaxation of complex perovskite Sm(Ni1/2Zr1/2)O3. Physica B 405(21), 4413–4417 (2010). https://doi.org/10.1016/j.physb.2010.08.00510.1016/j.physb.2010.08.005 ↗
60. M.B. Bechir, M.H. Dhaou, Study of charge transfer mechanism and dielectric relaxation of CsCuCl3 perovskite nanoparticles. Mater. Res. Bull. 144, 111473 (2021). https://doi.org/10.1016/j.materresbull.2021.11147310.1016/j.materresbull.2021.111473 ↗
61. A.K. Jonscher, The ‘universal’ dielectric response. Nature 267(5613), 673–679 (1977). https://doi.org/10.1038/267673a010.1038/267673a0 ↗
62. A. Kahouli, A. Sylvestre, F. Jomni, B. Yangui, J. Legrand, Experimental and theoretical study of AC electrical conduction mechanisms of semicrystalline parylene C thin films. J. Phys. Chem. A 116(3), 1051–1058 (2012). https://doi.org/10.1021/jp207114u10.1021/jp207114u ↗
63. H. Ohno, S. Konishi, T. Nagasaki, T. Kurasawa, H. Katsuta, H. Watanabe, Correlation behavior of lithium and tritium in some solid breeder materials. J. Nucl. Mater. 133–134, 181–185 (1985). https://doi.org/10.1016/0022-3115(85)90130-810.1016/0022-3115(85)90130-8 ↗
64. B. Rasneur, J. Charpin, Chemical properties of lithium ceramics: reactivity with water and water vapour. J. Nucl. Mater. 155–157, 461–465 (1988). https://doi.org/10.1016/0022-3115(88)90290-510.1016/0022-3115(88)90290-5 ↗
65. A. Zheltikov, Impedance spectroscopy: theory, experiment, and applications second edition. Evgenij Barsoukov and J. Ross Macdonald (eds). John Wiley & Sons, Inc., Hoboken, New Jersey, 2005, pp. 595. J. Raman Spectrosc. 38(1), 122–122 (2006). https://doi.org/10.1002/jrs.155810.1002/jrs.1558 ↗
66. S.S.N. Bharadwaja, P. Victor, P. Venkateswarulu, S.B. Krupanidhi, ac transport studies of La-modified antiferroelectric lead zirconate thin films. Phys. Rev. B (2002). https://doi.org/10.1103/physrevb.65.17410610.1103/physrevb.65.174106 ↗