journal article·2023-11

Reactive magnetron sputtered aluminum titanate high-к dielectric films for MIM devices

Suresh Addepalli, S. V. Jagadeesh Chandra, E. V. Krishna Rao, Uthanna Suda

Applied Physics A· Volume 129· Issue 11
Publisher page

Abstract

Metal–insulator–metal (MIM) devices were fabricated with Al/Al2TiO5 stack on Pt/Ti coated SiO2/Si substrates and studied the effect of synthesized oxygen flow rate on their composition, structural and electrical properties. X-ray photoelectron spectroscopy revealed that the presence of aluminum, titanium and oxygen with the ratio 2:1:5, respectively in the projected mixed insulator Al2TiO5. XRD spectra showed that the Al2TiO5 high-k films were amorphous in nature. The average grain size observed from atomic force micrograph of the deposited high-k layer could be 25 nm. The capacitance–voltage curves showed reasonably accepted accumulation capacitance values. The films showed the dielectric constant of 19.3 and the leakage current density of 4 × 10–7 A/cm2 with good break down behavior. The leakage current in the films can be attributed to the Fowler–Nordheim mechanism due to tunneling of electron at higher electric field and Poole–Frenkel emission in the medium field region since the dielectric films contained the defects and traps.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Semiconductor materials and devices · Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. M. Kumar, S.V. Jagadeesh Chandra, M. Ju, D. Subhajit et al., Effects of post deposition annealing atmosphere on interfacial and electrical properties of HfO2/Ge3N4 gate stacks. Thin Solid Films 675, 16 (2019)10.1016/j.tsf.2019.02.034 ↗
2. G.F. Dong, Y. Qiu, Pentacene thin-film transistors with Ta2O5 as the gate dielectric. J. Korean Phys. Soc. 54(1), 493–497 (2009)10.3938/jkps.54.493 ↗
3. S.V. Jagadeesh Chandra, E. Fortunato, R. Martins, C.J. Choi, Modulations in effective work function of platinum gate electrode in metal-oxide-semiconductor devices. Thin Solid Films 520, 4556 (2012)10.1016/j.tsf.2011.10.137 ↗
4. International Technology Roadmap for Semiconductors. http://public.itrs.net/
5. M. Rahmani, M.T. Ahmadi, H.K.F. Abadi, M. Saeidmanesh, E. Akbari, R. Ismail, Analytical modeling of trilayer graphene nanoribbon Schottky-barrier FET for high-speed switching applications. Nanoscale Res. Lett. 8, 55 (2013)10.1186/1556-276X-8-55 ↗
6. S.J. Ding, H.B. Chen, X.M. Cui, S. Chen, Q.Q. Sun, P. Zhou, H.L. Lu, D.W. Zhang, C. Shen, Atomic layer deposition of high-density Pt nanodots on Al2O3 film using (MeCp)Pt(Me)3 and O2 precursors for nonvolatile memory applications. Nanoscale Res. Lett. 8, 80 (2013)10.1186/1556-276X-8-80 ↗
7. P.R. Chalker, M. Werner, S. Romani, R.J. Potter, K. Black, H.C. Aspinall, A.C. Jones, C.Z. Zhao, S. Taylor, P.N. Heys, Permittivity enhancement of hafnium dioxide high-k films by cerium doping. Appl. Phys. Lett. 93, 182911 (2008)10.1063/1.3023059 ↗
8. G. Dalapati, T.S. Wong, Y. Li, C. Chia, A. Das, C. Mahata, H. Gao, S. Chattopadhyay, M. Kumar, H. Seng, C. Maiti, D. Chi, Characterization of epitaxial GaAs MOS capacitors using atomic layer-deposited TiO2/Al2O3 gate stack: study of Ge auto-doping and p-type Zn doping. Nanoscale Res. Lett. 7, 99 (2012)10.1186/1556-276X-7-99 ↗
9. Y.T. An, C. Labbé, L. Khomenkova, M. Morales, X. Portier, F. Gourbilleau, Microstructure and optical properties of Pr3+-doped hafnium silicate films. Nanoscale Res. Lett. 8, 43 (2013). https://doi.org/10.1186/1556-276X-8-4310.1186/1556-276X-8-43 ↗
10. P. Zhou, L. Ye, Q.Q. Sun, P.F. Wang, A.Q. Jiang, S.J. Ding, D.W. Zhang, Effect of concurrent joule heat and charge trapping on RESET for NbAlO fabricated by atomic layer deposition. Nanoscale Res. Lett. 8, 91 (2013). https://doi.org/10.1186/1556-276X-8-9110.1186/1556-276X-8-91 ↗
11. S.H. Chen, W.S. Liao, H.C. Yang, S.J. Wang, Y.G. Liaw, H. Wang, H.S. Gu, M.C. Wang, High-performance III-V MOSFET with nano-stacked high- k gate dielectric and 3D fin-shaped structure. Nanoscale Res. Lett. 7, 431 (2012). https://doi.org/10.1186/1556-276X-7-43110.1186/1556-276X-7-431 ↗
12. J.C. Wang, C.T. Lin, C.H. Chen, Gadolinium oxide nanocrystal nonvolatile memory with HfO2/Al2O3 nanostructure tunneling layers. Nanoscale Res. Lett. 7, 177 (2012). https://doi.org/10.1186/1556-276X-7-17710.1186/1556-276X-7-177 ↗
13. L. Shi, Z.G. Liu, Characterization upon electrical hysteresis and thermal diffusion of TiAl3Ox dielectric film. Nanoscale Res. Lett. 6, 557 (2011). https://doi.org/10.1186/1556-276X-6-55710.1186/1556-276X-6-557 ↗
14. L. Khomenkova, B.S. Sahu, A. Slaoui, F. Gourbilleau, Hf-based high-k materials for Si nanocrystal floating gate memories. Nanoscale Res. Lett. 6, 172 (2011). https://doi.org/10.1186/1556-276X-6-17210.1186/1556-276X-6-172 ↗
15. F.H. Chen, J.L. Her, Y.H. Shao, Y.H. Matsuda, T.M. Pan, Structural and electrical characteristics of high-k Er2O3 and Er2TiO5 gate dielectrics for a-IGZO thin-film transistors. Nanoscale Res. Lett. 8, 18 (2013). https://doi.org/10.1186/1556-276X-8-1810.1186/1556-276X-8-18 ↗
16. M.H. Jang, K.S. Jeong, K.B. Chung, J.W. Lee, M.H. Lee, M.-H. Cho, Surf. Sci. 606, 164 (2012)10.1016/j.susc.2012.04.010 ↗
17. C. Ye, C. Zhan, J. Zhang, H. Wang, T. Deng, S. Tang, Microelectron. Reliab.. Reliab. 54, 388 (2014)10.1016/j.microrel.2013.10.014 ↗
18. T. Das, C. Mahata, C.K. Maiti, E. Miranda, G. Sutradar, P.K. Bose, Appl. Phys. Lett. 98, 022901 (2011)10.1063/1.3536520 ↗
19. G. Zhou, B. Wo, Z. Li, Z. Xiao, S. Li, P. Li, Curr. Appl. Phys.. Appl. Phys. 15, 279 (2015)10.1016/j.cap.2014.12.024 ↗
20. K. Sato, T. Nango, T. Miyagawa, T. Katagiri, K.S. Seolang, K. Ohki, J. Appl. Phys. 92, 1106 (2002)10.1063/1.1507821 ↗
21. O. Auciello, W. Fan, B. Kabius, S. Saha, J.A. Carlisle, R.P.H. Chang, C. Lopez, E.A. Irene, R.A. Baragiola, Hybrid titanium–aluminum oxide layer as alternative high- gate dielectric for the next generation of complementary metal–oxide–semiconductor devices. Appl. Phys. Lett. 86, 042904 (2005)10.1063/1.1856137 ↗
22. J.A. Kittl et al., High-k dielectrics for future generation memory devices. Microelectron. Eng.. Eng. 86, 1789–1795 (2009)10.1016/j.mee.2009.03.045 ↗
23. D. Afouxenidis, R. Mazzocco, G. Vourlias, P.J. Livesley, A. Krier, W.I. Milne, O. Kolosov, G. Adamopoulos, ZnO-based thin film transistors employing aluminum titanate gate dielectrics deposited by spray pyrolysis at ambient air. ACS Appl. Mater. Interfaces 7, 7334–7341 (2015)10.1021/acsami.5b00561 ↗
24. S.Y. Lee, K.S. Bang, J.W. Lim, Sputter-deposited AlTiO thin films for semi-transparent silicon thin film solar cells. J. Electron. Mater. 43(9), 3204–3210 (2014)10.1007/s11664-014-3286-z ↗
25. H. Lei, W.S. Mao, J.-L. Jun, X. Peng, L.H. Ling, L. Zhinian, Chin. Sci. Bull. 54, 1451–1454 (2009)10.1007/s11434-009-0354-5 ↗
26. I. Heras, E. Guillen, F. Lungwitz, G.R. Liorente, F. Munnik, E. Schumann, I. Arkona, M. Krouse, R.E. Galind, Solar Energy Mater. Solar Cells 176, 81–91 (2018)10.1016/j.solmat.2017.10.015 ↗
27. H.C. Barshilia, N. Selvakumar, K.S. Rajam, D.V. Sridhara Rao, K. Muralidharan, Thin Solid Films 516, 6071–6078 (2008)10.1016/j.tsf.2007.10.113 ↗
28. D.H. Kuo, K.H. Tzeng, Growth and properties of titania and aluminum titanate thin films obtained by RF Magnetron sputtering. Thin Solid Films 420–421, 497–502 (2002)10.1016/S0040-6090(02)00945-8 ↗
29. D.H. Kuo, C.N. Shueh, Properties of aluminum titanate films prepared by chemical vapor deposition under different aluminum butoxide inputs. Thin Solid Films 478, 109–115 (2005)10.1016/j.tsf.2004.10.021 ↗
30. M. Andrianainarivelo, R.J.P. Corriu, D. Leclercq, P.H. Mutin, A. Vioux, Nonhydrolytic sol-gel process: aluminum titanate gels. Chem. Mater. 9(5), 1098–1102 (1997)10.1021/cm960405b ↗
31. L. Shi, Y.D. Xia, B. Xu, J. Yin, Z.G. Liu, Thermal stability and electrical properties of titanium–aluminum oxide ultra thin films as high-k gate dielectric materials. J. Appl. Phys. 101, 034102 (2007)10.1063/1.2432401 ↗
32. C.D. Wagner, L.E. Davis, M.V. Zeller, J.A. Taylor, R.H. Raymond, L.H. Gale, Surf. Interface Anal. 3, 211 (1981)10.1002/sia.740030506 ↗
33. J. Koo, S. Kim, S. Jeon, H. Jeon, Y. Kim, Y. Won, J. Korean Phys. Soc. 48, 131 (2006)
34. R. Sanjines, H. Tang, H. Berger, F. Gozze, G. Margaritnado, F. Levy, J. Appl. Phys. 75, 2945 (1994)10.1063/1.356190 ↗
35. S.V. Jagadeesh Chandra, J. Myung-Il, Y.C. Park, J.W. Yoon, C.J. Choi, Effect of annealing ambient on structural and electrical properties of Ge metal-oxide-semiconductor capacitors with Pt gate electrode and HfO2 date dielectric. Mater. Trans. 52(1), 118 (2011)10.2320/matertrans.M2010324 ↗
36. M. Chandra Sekhar, N. Nanda Kumar Reddy, B. Venkata Rao, G. Mohan Rao, S. Uthanna, Surf. Interface Anal. 46, 465 (2014)10.1002/sia.5538 ↗
37. S. Chakraborty, M.K. Bera, S. Bhattacharya, C.K. Maiti, Microelectron. Eng.. Eng. 81, 188 (2005)10.1016/j.mee.2005.03.005 ↗
38. A. Suresh, K.L. Ganapathi, S. Uthanna, Mater. Sci. Semi. Process. 57, 137–146 (2017)10.1016/j.mssp.2016.10.019 ↗
39. A. Dimitrios, M. Riccardo, V. Georgios, J.L. Peter, K. Anthony, I.M. William, K. Oleg, A. George, ZnO-based thin film transistors employing aluminum titanate gate dielectrics deposited by spray pyrolysis at ambient air. ACS Appl. Mater. Interfaces 7, 7334 (2015)10.1021/acsami.5b00561 ↗
40. S. Vikas, K.S. Jyoti, Synthesis, densification, and phase evolution studies of Al2O3–Al2TiO5–TiO2 nanocomposites and measurement of their electrical properties. J. Am. Ceram. Soc. 90(8), 2372–2378 (2007)10.1111/j.1551-2916.2007.01797.x ↗
41. G. Fisichella, E. Schiliro, S. Di Franco, P. Fiorenza, R. Lo Nigro, F. Roccaforte, S. Ravesi, F. Giannazzo, Interface electrical properties of Al2O3 thin films on graphene obtained by atomic layer deposition with an in situ seedlike layer. ACS Appl. Mater. Interfaces 9, 7761–7771 (2017)10.1021/acsami.6b15190 ↗
42. F.M. Li, B.C. Bayer, S. Hofmann, J.D. Dutson, S.J. Wakeham, M.J. Thwaites, W.I. Milne, A.J. Flewitt, High-k amorphous hafnium oxide films from high rate room temperature deposition. Appl. Phys. Lett. 98, 252903 (2011)10.1063/1.3601487 ↗
43. J. Mu, X. Chou, Z. Ma, J. He, J. Xiong, High performance MIM capacitors for a secondary power supply application. Micromachines 9, 69 (2018)10.3390/mi9020069 ↗
44. K.F. Albertin, M.A. Valle, I. Pereyra, Study of MOS capacitors with TiO2 and SiO2/TiO2 gate dielectric. J. Integr. Circuits Syst. 2(2), 89–93 (2007)10.29292/jics.v2i2.272 ↗
45. S.V. Jagadeesh Chandra, J.S. Kim, K.W. Moon, C.J. Choi, Effect of post metallization annealing on structural and electrical properties of Ge metal-oxide-semiconductor (MOS) capacitors with Pt/HfO2 gate stack. Microelectron. Eng.. Eng. 89, 76 (2012)10.1016/j.mee.2011.03.156 ↗
46. P. Kondaiah, S.V. Jagadeesh Chandra, E. Fortunato, C.J. Choi, G.M. Rao, D.V.R.K. Reddy, S. Uthanna, Substrate temperature influenced ZrO2 films for MOS devices. Surf. Int. Anal. 52(9), 541 (2020)10.1002/sia.6775 ↗
47. E. Robertson, Phys. J. Appl. Phys. 28, 265 (2004)10.1051/epjap:2004206 ↗
48. S.M. Sze, Physics of Semiconductor Devices (Wiley, New York, 2007)