journal article·2022-08

Novel green-emitting phosphor Na2CaGe6O14: Tb3+ with high thermal stability by assistant of carriers from traps

Biaojie Liu, Guoren Yang, Xianwei Meng, Yunfei Si

Applied Physics A· Volume 128· Issue 8
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Abstract

Thermal stability is the main problem affecting the application of inorganic fluorescent materials in high-power LED devices. Here, we have synthesized a green light-emitting phosphor Na2Ca1-xGe6O14: xTb3+ with high luminescence thermal stability mainly through high temperature solid-state reaction. By changing the concentration of doping ions, the traps concentration of the material can be increased, so that the thermal stability of the material can be improved, which is attributed to the traps compensating greater than the thermal quenching effect. This method of utilizing traps to improve thermal stability provides a potential synthesis strategy for improving high-power white LED used in automotive.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Microwave Dielectric Ceramics Synthesis · Radiation Detection and Scintillator Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (20)

Show source-provided references
1. M.N.S. Viswanath, G.K. Grandhi, H.T. Huu, H. Choi, H.J. Kim, S.M. Kim, H.Y. Kim, C.J. Park, W.B. Im, Chem. Eng. J. 420, 127664 (2021)10.1016/j.cej.2020.127664 ↗
2. Y. l. Chen, B. X. Yu, J. Gou, S. Z. Liu., J. Mater. Chem. C. 40, 10687–10692 (2018)
3. X.T. Fan, W.B. Chen, S.Y. Xin, Z.C. Liu, M. Zhou, X. Yu, D.C. Zhou, X.H. Xu, J.B. Qiu, J. Mater. Chem. C. 12, 2978–2982 (2018)10.1039/C8TC00511G ↗
4. D. Liu, Y.H. Jin, Y. Lv, G.F. Ju, C.L. Wang, L. Chen, W.W. Luo, Y.H. Hu, J. Am. Ceram. Soc. 12, 5627–5639 (2018)10.1111/jace.15877 ↗
5. Y. Wei, L. Cao, L.M. Lv, G.G. Li, J.R. Hao, J.S. Gao, C.C. Su, C.C. Lin, H.S. Jang, P.P. Dang, J. Lin, Chem. Mater. 7, 2389–2399 (2018)10.1021/acs.chemmater.8b00464 ↗
6. S.X. Li, Y.H. Xia, M. Amachraa, N.T. Hung, Z.B. Wang, S.P. Ong, R., J. Xie. Chem. Mater. 16, 6286–6294 (2019)10.1021/acs.chemmater.9b02505 ↗
7. J.S. Zhong, D.Q. Chen, H.X. Xu, W.G. Zhao, J. Sun, Z.G. Ji, J. Alloys Compd. 695, 311–318 (2017)10.1016/j.jallcom.2016.10.211 ↗
8. A.J. Fu, L.Y. Zhou, S. Wang, Y.H. Li, Dyes Pigm. 148, 9–15 (2018)10.1016/j.dyepig.2017.08.050 ↗
9. C.Y. Ji, Z. Huang, X.Y. Tian, H.P. He, J. Wen, Y.X. Peng, J. Alloys Compd. 825, 154176 (2020)10.1016/j.jallcom.2020.154176 ↗
10. Y.H. Kim, P. Arunkumar, B.Y. Kim, S. Unithrattil, E. Kim, S.H. Moon, J.Y. Hyun, K.H. Kim, D. Lee, J.S. Lee, W.B. Im, Nat. Mater. 5, 543–550 (2017)10.1038/nmat4843 ↗
11. Z.Z. Wang, Z. Song, L.X. Ning, Q.L. Liu, J. Mater. Chem. C. 3, 1143–1150 (2020)10.1039/C9TC05880J ↗
12. J.W. Qiao, J. Zhao, Q.L. Liu, Z.G. Xia, J. Rare Earths 6, 565–572 (2019)10.1016/j.jre.2018.11.001 ↗
13. J.Y. Zhong, W.R. Zhao, F. Du, J. Wen, W.D. Zhuang, R.H. Liu, C.K. Duan, L.G. Wang, K. Lin, J. Phys. Chem. C 14, 7849–7858 (2018)10.1021/acs.jpcc.8b00683 ↗
14. M.L. Zhang, Z.G. Xia, Q.L. Liu, J. Mater. Chem. C. 30, 7489–7494 (2017)10.1039/C7TC02539D ↗
15. Z.G. Xia, Q.L. Liu, Prog. Mater. Sci. 84, 59–117 (2016)10.1016/j.pmatsci.2016.09.007 ↗
16. J.H. Zhou, Z.W. Long, J.B. Qiu, D.C. Zhou, J.A. Lai, X.H. Xu, S.H. Hu, X.Z. Li, Q. Wang, J. Rare Earths 39, 1520-1526 (2021)10.1016/j.jre.2020.12.004 ↗
17. Y.X. Zhuang, J. Ueda, S. Tanabe, J. Mater. Chem. C 1, 7849–7855 (2013)10.1039/c3tc31462f ↗
18. H.R. Li, Y.J. Liang, S.Q. Liu, W.L. Zhang, Y.Y. Bi, Y.M. Gong, Y.J. Chen, W. Lei, J. Mater. Chem. C. 7, 2569–2581 (2021)10.1039/D0TC04618C ↗
19. Y.H. Kim, P. Arunkumar, B.Y. Kim, S. Unithrattil, E. Kim, S.H. Moon, J.Y. Hyun, K.H. Kim, D. Lee, J.S. Lee, W.B. Im, Nat. mater. 16, 543–550 (2017)10.1038/nmat4843 ↗
20. X.T. Fan, W.B. Chen, S.Y. Xin, Z.C. Liu, M. Zhou, X. Yu, D.C. Zhou, X.H. Xu, J.B. Qiu, J. Mater. Chem. C. 6, 2978–2982 (2018)10.1039/C8TC00511G ↗