journal article·2019-06

Heterostructure of GeSe2−xSnx/n-Si solar cells: electronic properties and improvement of photoelectrical performance

S. R. Alharbi, A. A. A. Darwish

Applied Physics A· Volume 125· Issue 6
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Abstract

Heterostructures of GeSe2−xSnx/n-Si (0 ≤ x ≤ 0.8) solar cells were made by vacuum deposition. Electronic and photoelectrical performances of these cells were investigated in details. The effective transport mechanisms were observed to be the thermionic emanation and space-charge-limited current with a single trap level for low and high forward voltage, respectively. Under reverse bias, the effective conduction mechanism is the Poole–Frenkel effect in the low voltage and the Schottky effect in the higher voltage. From the capacitance–voltage measurement, it was found that the heterostructure with x = 0.8 showed the highest carrier concentration and lowest built-in voltage demonstrated that the Sn doping improved the GeSe2−xSnx/n-Si interface. The heterostructures demonstrated a decent reaction to the light where light influences the reverse current because of the making of photocurrent. The heterostructure with x = 0.8 displayed higher photoelectrical performance.
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Research context

OpenAlex topics: Phase-change materials and chalcogenides · Semiconductor materials and interfaces · Chalcogenide Semiconductor Thin Films

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References (28)

Show source-provided references
1. K.S. Albarkaty, E. Kumi-Barimah, C. Craig, D. Hewak, G. Jose, J. Chandrappan, Erbium-doped chalcogenide glass thin film on silicon using femtosecond pulsed laser with different deposition temperatures. Appl. Phys. A 125, 1 (2019)10.1007/s00339-018-2286-x ↗
2. Y. Imanishi, T. Nakaoka, Direct measurement of “ready-made” cations in a Ge2Sb3.4Te6.2 film. J. Mater. Sci. 54, 7072–7077 (2019)10.1007/s10853-019-03405-y ↗
3. M. Achimovičová, E. Dutková, E. Tóthová, Z. Bujňáková, J. Briančin, S. Kitazono, Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial mill. Front. Chem. Sci. Eng. 13, 164–170 (2019)10.1007/s11705-018-1755-2 ↗
4. N.S. Tezel, F.M. Tezel, İ.A. Kariper, Surface and electro-optical properties of amorphous Sb2S3 thin films. Appl. Phys. A 125, 198 (2019)10.1007/s00339-019-2475-2 ↗
5. K. Palka, J. Jancalek, S. Slang, M. Grinco, M. Vlcek, Comparison of optical and chemical properties of thermally evaporated and spin-coated chalcogenide AsS thin films targeting electron beam lithography applications. J. Non-Cryst. 508, 7–14 (2019)10.1016/j.jnoncrysol.2018.12.012 ↗
6. M. Mohamed, E.R. Abd-el Salam, M.N. Salam, A.Y. Abdel-Latief, S.A. Mahmoud, M.A. Abdel-Rahim, Investigation of the optical and electrical parameters of As47.5Se47.5Ag5 thin films with different thicknesses for optoelectronic applications. Optik 178, 1302–1312 (2019)10.1016/j.ijleo.2018.10.103 ↗
7. P.K. Sahu, R. Das, R. Lalwani, Incorporation of tin in nanocrystalline CdSe thin films: a detailed study of optoelectronic and microstructural properties. Appl. Phys. A 124, 665 (2018)10.1007/s00339-018-2094-3 ↗
8. K.A. Aly, H.H. Hegazy, A. Dahshan, K.S. Shaaban, Y. Saddeek, S.R. Alharbi, A.M. Ali, S.A. Amin, Study of the optical properties of amorphous As–Se–S thin films. Appl. Phys. A 124, 868 (2018)10.1007/s00339-018-2278-x ↗
9. Q.M. Liu, X.J. Zhao, K. Tanaka, A. Narazaki, K. Hirao, F.X. Gan, Second-harmonic generation in Ge–As–S glasses by electron beam irradiation and analysis of the poling mechanism. Opt. Commun. 198, 187–192 (2001)10.1016/S0030-4018(01)01483-3 ↗
10. I. Haruvi-Busnach, J. Dror, N. Croitoru, Chalcogenide glasses Ge–Sn–Se, Ge–Se–Te, and Ge–Sn–Se–Te for infrared optical fibers. J. Mater. Res. 5, 1215–1223 (1989)10.1557/JMR.1990.1215 ↗
11. A.A.A. Darwish, M. Rashad, A.E. Bekheet, M.M. El-Nahass, Linear and nonlinear optical properties of GeSe2−xSnx (0 ≤ x ≤ 0.8) thin films for optoelectronic applications. J. Alloys Compd. 709, 640–645 (2017)10.1016/j.jallcom.2016.08.280 ↗
12. A.A.A. Darwish, S.R. Alharbi, S.E. Al Garni, K.F. Abd El-Rahman, M.M. El-Nahass, Investigation of composition effect on electrical properties of noncrystalline GeSe2−xSnx (0 ≤ x ≤ 0.8)thin films. J. Alloys Compd. 710, 349–354 (2017)10.1016/j.jallcom.2017.03.282 ↗
13. K.F. Abd-El-Rahman, A.A.A. Darwish, Fabrication and electrical characterization of p-Sb2S3/n-Si heterojunctions for solar cells application. Curr. Appl. Phys. 11, 1265–1268 (2011)10.1016/j.cap.2010.12.006 ↗
14. K.F. Abd-El-Rahman, Charge conduction mechanisms and photovoltaic properties of n-(Ga2S3–Ga2Se3)/p-Si heterojunctions. Eur. Phys. J. Appl. Phys. 37, 143–147 (2007)10.1051/epjap:2007004 ↗
15. K.F. Abd-El-Rahman, A.A.A. Darwish, E.A.A. El-Shazly, Electrical and photovoltaic properties of SnSe/Si heterojunction. Mater. Sci. Semicond. Process. 25, 123–129 (2014)10.1016/j.mssp.2013.10.003 ↗
16. R.K. Joshi, S. Mohan, S.K. Agarwal, H.K. Sehgal, Photovoltaic effect in nanocrystalline Pb1−xFexS single crystal silicon heterojunctions. Thin Solid Films 447–448, 80–84 (2004)10.1016/j.tsf.2003.09.026 ↗
17. M.M. El-Nahass, H.E.A. El-Sayed, A.M.A. El-Barry, Transport mechanisms and photovoltaic characteristics of p-SxSe100-x/n-Si heterojunctions. Solid-State Electron. 50, 355–361 (2006)10.1016/j.sse.2006.01.011 ↗
18. A.A. Yadav, Effect of Fe-incorporation on photovoltaic characteristics of nanostructured CdSe thin films. J. Alloys Compd. 552, 318–323 (2013)10.1016/j.jallcom.2012.10.127 ↗
19. M. Ahmad, P. Kumar, R. Thangaraj, Effect of isoelectronic substitution of Bi on the photoelectrical properties in amorphous Sn–Sb–Se films. Thin Solid Films 517, 5965–5968 (2009)10.1016/j.tsf.2009.03.130 ↗
20. C.A. Hurni, H. Kroemer, U.K. Mishra, J.S. Speck, Capacitance–voltage profiling on polar III-nitride heterostructures. J. Appl. Phys. 112, 083704 (2012)10.1063/1.4757940 ↗
21. M.S. Sze, Physics of Semiconductor Devices, 2nd edn. (Wiley, New York, 1981)
22. A.A.A. Darwish, E.A.A. El-Shazly, A.A. Attia, K.F. Abd-El-Rahman, Dark electrical properties and photovoltaic performance of organic/inorganic (SnPcCl2/p-Si) solar cells. J. Mater. Sci. Mater. Electron. 27, 8786–8792 (2016)10.1007/s10854-016-4903-9 ↗
23. Ö. Güllü, Ş. Aydoğan, A. Türüt, Fabrication and electrical properties of Al/Safranin T/n-Si/AuSb structure. Semicond. Sci. Technol. 23, 075005 (2008)10.1088/0268-1242/23/7/075005 ↗
24. F. Yakuphanoglu, Controlling of electrical and interface state density properties of ZnO:Co/p-silicon diode structures by compositional fraction of cobalt dopant. Microelectron. Reliab. 51, 2195–2199 (2011)10.1016/j.microrel.2011.05.013 ↗
25. S. Senthilarasu, R. Sathyamoorthy, S. Lalitha, A. Subbarayan, Space charge limited current conduction in zinc phthalocyanine (ZnPc) thin films. Solid-State Electron. 49, 813–817 (2005)10.1016/j.sse.2005.01.007 ↗
26. M.M. El-Nahass, K.F. Abd-El-Rahman, A.A.A. Darwish, Dark electrical and photovoltaic properties of Schottky device based on organic thin film of 4-tricyanovinyl-N,N-diethylaniline. Eur. Phys. J. Appl. Phys. 48, 30403 (2009)10.1051/epjap/2009175 ↗
27. F. Yakuphanoglu, Electrical and photovoltaic properties of cobalt-doped zinc oxide nanofiber/n-silicon diode. J. Alloys Compd. 494, 451–455 (2010)10.1016/j.jallcom.2010.01.075 ↗
28. K. Shimakawa, A. Kolobov, S.R. Elliott, Photoinduced effects and metastability in amorphous semiconductors and insulators. Adv. Phys. 44, 475–588 (1995)10.1080/00018739500101576 ↗