Structural, dielectric and electric modulus analysis of praseodymium-substituted SrPrxFe12-X O19 nanoparticles synthesized via micro-emulsion
Source abstract
Abstract
Praseodymium (III)-doped M-type SrPrxFe12-xO19 (x = 0.00, 0.25, 0.50, 0.75, 1.00) hexa-ferrites were synthesized via micro-emulsion process followed by annealing of samples at 800 °C for 4 h. The effects of praseodymium particles on properties such as electrical, magnetic, and dielectric were studied. Via TGA the phase formation was observed to be started at 900 °C, and weight reduced to 5.27% at 1010 °C. Through X-ray diffraction (XRD), hexagonal structure was confirmed and structural properties were studied: the crystalline size, lattice constant, bulk and X-rays densities, i.e., 4.446 nm, 5.90 Å, 4.167 g·cm−3 and 6.46 g·cm−3, respectively. The cation dispersion and shifting of frequencies were observed by FTIR at frequencies 430–590 cm−1 because of dopant of higher radii. Surface morphology, grain structure, and porosity were studied by scanning electron microscopy (SEM). Electrical properties were determined by impedance spectroscopy. The impact of Pr3+ doping on distinct metrics, i.e. dielectric constants, dielectric loss, tan loss, A.C conductivity, was studied: 1.890, 0.023, 0.012, 0.001, respectively. The effects of Pr3+ doping on retentivity, coercivity, saturation magnetization, and anisotropy were investigated by the vibrating sample magnetometer (VSM). The increase in saturation and remanence is due to the increase of Pr3+ that retuned extra Fe3+ ions from the lattice plot. The prepared materials offer valuable potential for applications of high-density recording medium applications and high-frequency devices.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Multiferroics and related materials · Electromagnetic wave absorption materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (51)
Show source-provided references
1. M. Khaleeq-ur-Rahman, K.A. Bhatti, M.S. Rafique, A. Latif, S. fou-uz-Zia, Deposition and characterization of strontium hexa ferrite (SrFe12O19) by PLD technique. Opt. Laser Technol. 47, 361–365 (2013). https://doi.org/10.1016/j.optlastec.2012.07.02510.1016/j.optlastec.2012.07.025 ↗
2. M. Ginting, P. Sebayang, M. Rianna, M. Situmorang, H. Fujiati, A.P. Tetuko, A.M.S. Sebayang, Effect of Co and Ni additions as doping materials on the micro-structures and the magnetic properties of barium hexa-ferrites. Case Stud. Therm. Eng. 18, 100589 (2020). https://doi.org/10.1016/j.csite.2020.10058910.1016/j.csite.2020.100589 ↗
3. S. Said, S. Mikhail, M. Riad, Recent processes for the production of alumina nano-particles. Mater. Sci. Energy Technol. (2020). https://doi.org/10.1016/j.mset.2020.02.00110.1016/j.mset.2020.02.001 ↗
4. N. Yasmin, S. Yasmin, M. Zahid, S.F. Gillani, M.U. Islam, M. Altaf, M. Mirza, Impact of Ho-Ni substitution on structural, morphological and dielectrical characteristics of BaFe12O19 M-type hexagonal ferrite. Phys. B: Condens. Matter 581, 411950 (2020). https://doi.org/10.1016/j.physb.2019.41195010.1016/j.physb.2019.411950 ↗
5. E. Marek, W. Hu, M. Gaultois, C.P. Grey, S.A. Scott, The use of strontium ferrite in chemical looping systems. Appl. Energy 223, 369–382 (2018). https://doi.org/10.1016/j.apenergy.2018.04.09010.1016/j.apenergy.2018.04.090 ↗
6. J. Singh, C. Singh, D. Kaur, S.B. Narang, R. Joshi, S.R. Mishra, C.C. Chauhan, Tunable microwave absorption in CoAl substituted M-type BaSr hexagonal ferrite. Mater. Des. 110, 749–761 (2016). https://doi.org/10.1016/j.matdes.2016.08.04910.1016/j.matdes.2016.08.049 ↗
7. J. Singh, C. Singh, D. Kaur, S. Bindra Narang, R. Jotania, R. Joshi, Investigation on structural and microwave absorption property of Co2+ and Y3+ substituted M-type Ba-Sr hexagonal ferrites prepared by a ceramic method. J. Alloy. Compd. 695, 792–798 (2017). https://doi.org/10.1016/j.jallcom.2016.09.25110.1016/j.jallcom.2016.09.251 ↗
8. F.M.M. Pereira, C.A.R. Junior, R.P. Santos, M. Sohn, R. Aguiar Freire, F.N.J. Sasaki, S. Sombra, Structural and dielectric spectroscopy studies of the M-type barium strontium hexaferrite alloys (Ba x Sr1−x Fe12O19). J. Mater. Sci. Mater. Electron. 19, 627–638 (2008)10.1007/s10854-007-9411-5 ↗
9. A.U. Rehman, S.F. Shaukat, M.N. Akhtar, M. Ahmad, Evaluations of structural, magnetic and various dielectric parameters of Ni-substituted Zn2W-type hexagonal ferrites for high frequency (1–6 GHz) applications. Ceram. Int. 45(18), 24202–24211 (2019). https://doi.org/10.1016/j.ceramint.2019.08.12910.1016/j.ceramint.2019.08.129 ↗
10. S. Kumar, S.K. Das, S.K. Pattanayek, Evolution of nanostructure and mechanical properties of silver nano-particle in the confined region between graphene sheets: an atomistic investigation. Comput. Mater. Sci. 152, 393–407 (2018). https://doi.org/10.1016/j.commatsci.2018.06.02110.1016/j.commatsci.2018.06.021 ↗
11. C. Liu, X. Liu, S. Feng, K.M.U. Rehman, M. Li, C. Zhang, X. Meng, Microstructure and magnetic properties of M-type strontium hexagonal ferrites with Y-Co substitution. J. Magn. Magn. Mater. 436, 126–129 (2017). https://doi.org/10.1016/j.jmmm.2017.04.04010.1016/j.jmmm.2017.04.040 ↗
12. C. Liu, X. Liu, S. Feng, K.M.U. Rehman, M. Li, C. Zhang, X. Meng, Effect of Y-La-Co substitution on microstructure and magnetic properties of M-type strontium hexagonal ferrites prepared by ceramic method. J. Magn. Magn. Mater. 445, 1–5 (2018). https://doi.org/10.1016/j.jmmm.2017.08.07910.1016/j.jmmm.2017.08.079 ↗
13. A. Kanca, Investigation on pyrolysis and combustion characteristics of low quality lignite, cotton waste, and their blends by TGA-FTIR. Fuel 263, 116517 (2020). https://doi.org/10.1016/j.fuel.2019.11651710.1016/j.fuel.2019.116517 ↗
14. J. Liu, P. Liu, X. Zhang, D. Pan, P. Zhang, M. Zhang, Synthesis and properties of single domain sphere-shaped barium hexa-ferrite nano powders via an ultrasonic-assisted co-precipitation route. Ultrason. Sonochem. 23, 46–52 (2015). https://doi.org/10.1016/j.ultsonch.2014.08.00110.1016/j.ultsonch.2014.08.001 ↗
15. A.D. Bamburov, A.A. Markov, M.V. Patrakeev, I.A. Leonidov, The impact of Ba substitution in lanthanum-strontium ferrite on the mobility of charge carriers. Solid State Ion. 332, 86–92 (2019). https://doi.org/10.1016/j.ssi.2019.01.01310.1016/j.ssi.2019.01.013 ↗
16. A. Javidan, S. Rafizadeh, S. Mostafa Hosseinpour-Mashkani, Strontium ferrite nanoparticle study: thermal decomposition synthesis, characterization, and optical and magnetic properties. Mater. Sci. Semicond. Process. 27, 468–473 (2014). https://doi.org/10.1016/j.mssp.2014.07.02410.1016/j.mssp.2014.07.024 ↗
17. S. Vijayabhaskar, T. Rajmohan, T.K. Vignesh, H. Venkatakrishnan, Effect of nano SiC particles on properties and characterization of magnesium matrix nano composites. Mater. Today: Proc. 16, 853–858 (2019). https://doi.org/10.1016/j.matpr.2019.05.16810.1016/j.matpr.2019.05.168 ↗
18. H.F. Lu, R.Y. Hong, H.Z. Li, Influence of surfactants on co-precipitation synthesis of strontium ferrite. J. Alloy. Compd. 509(41), 10127–10131 (2011). https://doi.org/10.1016/j.jallcom.2011.08.05810.1016/j.jallcom.2011.08.058 ↗
19. S. Anjum, S. Hameed, M.S. Awan, E. Amed, A. Sattar, Effect of strontium doped M-Type barium hexa-ferrites on structural, magnetic and optical properties. Optik 131, 977–985 (2017). https://doi.org/10.1016/j.ijleo.2016.11.20510.1016/j.ijleo.2016.11.205 ↗
20. J. Liu, Y. Zeng, X. Zhang, M. Zhang, Effects of magnetic pre-alignment of nano-powders on formation of high textured barium hexa-ferrite quasi-single crystals via a magnetic forming and liquid participation sintering route. J. Magn. Magn. Mater. 382, 188–192 (2015). https://doi.org/10.1016/j.jmmm.2015.01.07810.1016/j.jmmm.2015.01.078 ↗
21. J. Du, T. Zhou, L. Lian, Y. Liu, Y. Du, Two-step sintering of M-type strontium ferrite with high coercivity. Ceram. Int. 45(6), 6978–6984 (2019). https://doi.org/10.1016/j.ceramint.2018.12.19710.1016/j.ceramint.2018.12.197 ↗
22. S. Xiang, L. Feng, X. Bian, G. Li, X. Chen, Evaluation of PLA content in PLA/PBAT blends using TGA. Polym. Test. 81, 106211 (2020). https://doi.org/10.1016/j.polymertesting.2019.10621110.1016/j.polymertesting.2019.106211 ↗
23. T. Mori, H. Imazeki, G. Tsutsui, M. Tanahashi, Evaluation of nano particle slurries by osmotic pressure measurement and its application to fabrication process of nano composite materials. Nano-Struct. Nano-Objects 18, 100306 (2019). https://doi.org/10.1016/j.nanoso.2019.10030610.1016/j.nanoso.2019.100306 ↗
24. M. Ayub, I.H. Gul, K. Nawaz, K. Yaqoob, Effect of rare earth and transition metal La-Mn substitution on electrical properties of co-precipitated M-type Ba-ferrites nanoparticles. J. Rare Earths 37(2), 193–197 (2019). https://doi.org/10.1016/j.jre.2018.08.00510.1016/j.jre.2018.08.005 ↗
25. H. Yu, Z. Liu, D. Zeng, TEM observation of sintered permanent magnetic strontium ferrite. Rare Met. 25(6, Supplement 1), 578–583 (2006). https://doi.org/10.1016/S1001-0521(07)60149-110.1016/S1001-0521(07)60149-1 ↗
26. Z. Durmus, B. Unal, M.S. Toprak, H. Sozeri, A. Baykal, Synthesis and characterization of poly(3-thiophenyl acetic acid) (P3TAA)–BaFe12O19 nanocomposite. Polyhedron 30(7), 1349–1359 (2011). https://doi.org/10.1016/j.poly.2011.02.04410.1016/j.poly.2011.02.044 ↗
27. C. Gao, L. Huang, L. Yan, R. Jin, H. Chen, Mechanical properties of recycled aggregate concrete modified by nano-particles. Constr. Build. Mater. 241, 118030 (2020). https://doi.org/10.1016/j.conbuildmat.2020.11803010.1016/j.conbuildmat.2020.118030 ↗
28. A. Ghafoor, M.A. Khan, M.U. Islam, Z.A. Gilani, A. Manzoor, H.M. Khan, M.F. Warsi, Structural and electromagnetic studies of Ni0.7Zn0.3Ho2xFe2−2xO4 ferrites. Ceram. Int. 42(12), 14252–14256 (2016). https://doi.org/10.1016/j.ceramint.2016.06.05410.1016/j.ceramint.2016.06.054 ↗
29. Z.A. Gilani, M.F. Warsi, M.N. Anjum, I. Shakir, S. Naseem, S. Riaz, M.A. Khan, Structural and electromagnetic behavior evaluation of Nd-doped lithium–cobalt nanocrystals for recording media applications. J. Alloy. Compd. 639, 268–273 (2015). https://doi.org/10.1016/j.jallcom.2015.03.17010.1016/j.jallcom.2015.03.170 ↗
30. Z.A. Gilani, M.F. Warsi, M.A. Khan, I. Shakir, M. Shahid, M.N. Anjum, Impacts of neodymium on structural, spectral and dielectric properties of LiNi0.5Fe2O4 nanocrystalline ferrites fabricated via micro-emulsion technique. Phys. E 73, 169–174 (2015). https://doi.org/10.1016/j.physe.2015.06.00110.1016/j.physe.2015.06.001 ↗
31. M.R. Gumaste, G.A. Kulkarni, K.N. Anuradha, Room temperature green luminescence and homogeneous distribution of TGA capped CdTe Nano-Rods. Mater. Today: Proc. (2019). https://doi.org/10.1016/j.matpr.2019.10.02210.1016/j.matpr.2019.10.022 ↗
32. S. Hussain, A. Maqsood, Influence of sintering time on structural, magnetic and electrical properties of Si–Ca added Sr-hexa ferrites. J. Magn. Magn. Mater. 316(1), 73–80 (2007). https://doi.org/10.1016/j.jmmm.2007.03.20610.1016/j.jmmm.2007.03.206 ↗
33. S. Hussain, A. Maqsood, Structural and electrical properties of Pb-doped Sr-hexa ferrites. J. Alloy. Compd. 466, 293–298 (2008). https://doi.org/10.1016/j.jallcom.2007.11.07410.1016/j.jallcom.2007.11.074 ↗
34. S. Hussain, A. Maqsood, Structural and electrical properties of Pb-doped Sr-hexa ferrites. J. Alloy. Compd. 466(1), 293–298 (2008). https://doi.org/10.1016/j.jallcom.2007.11.07410.1016/j.jallcom.2007.11.074 ↗
35. S. Hussain, N.A. Shah, A. Maqsood, A. Ali, M. Naeem, W.A.A. Syed, Characterization of Pb-doped Sr-ferrites at room temperature. J. Supercond. Novel Magn. 24(4), 1245–1248 (2011). https://doi.org/10.1007/s10948-010-1115-z10.1007/s10948-010-1115-z ↗
36. T.-Y. Hwang, J. Lee, H.-R. Lim, S.-J. Jeong, G.-H. An, J. Kim, Y.-H. Choa, Synthesis and magnetic properties of La3+-Co2+ substituted strontium ferrite particles using modified spray pyrolysis–calcination method. Ceram. Int. 43(4), 3879–3884 (2017). https://doi.org/10.1016/j.ceramint.2016.12.05110.1016/j.ceramint.2016.12.051 ↗
37. K.-B. Nie, Y.-C. Guo, P. Munroe, K.-K. Deng, X.-K. Kang, Microstructure and tensile properties of magnesium matrix nanocomposite reinforced by high mass fraction of nano-sized particles including TiC and MgZn2. J. Alloys Compd. 819, 153348 (2020). https://doi.org/10.1016/j.jallcom.2019.15334810.1016/j.jallcom.2019.153348 ↗
38. H. Kaur, A. Marwaha, C. Singh, S.B. Narang, R. Jotania, S. Jacobo, P. Dhruv, Investigation of structural, hysteresis and electromagnetic parameters for microwave absorption application in doped Ba–Sr hexagonal ferrites at X-band. J. Alloys Compd. 806, 1220–1229 (2019). https://doi.org/10.1016/j.jallcom.2019.07.03210.1016/j.jallcom.2019.07.032 ↗
39. M.N. Akhtar, S. Javed, M. Ahmad, A.B. Sulong, M.A. Khan, Sol gel derived MnTi doped Co2 W-type hexagonal ferrites: structural, physical, spectral and magnetic evaluations. Ceram. Int. (2019). https://doi.org/10.1016/j.ceramint.2019.12.00310.1016/j.ceramint.2019.12.003 ↗
40. M. Mohammadihooyeh, E. Karamian, R. Emadi, Effect of magnesium-aluminate spinel nano-particles on microstructure and properties behaviors of doloma-containing refractories. Ceram. Int. 46(2), 1662–1667 (2020). https://doi.org/10.1016/j.ceramint.2019.09.13810.1016/j.ceramint.2019.09.138 ↗
41. O. Opuchovic, G. Kreiza, J. Senvaitiene, K. Kazlauskas, A. Beganskiene, A. Kareiva, Sol-gel synthesis, characterization and application of selected sub-microsized lanthanide (Ce, Pr, Nd, Tb) ferrites. Dyes Pigm. 118, 176–182 (2015). https://doi.org/10.1016/j.dyepig.2015.03.01710.1016/j.dyepig.2015.03.017 ↗
42. T. Waki, K. Takao, Y. Tabata, H. Nakamura, Single crystal synthesis and magnetic properties of Co2+-substituted and non-substituted magnetoplumbite-type Na–La ferrite. J. Solid State Chem. 282, 121071 (2020). https://doi.org/10.1016/j.jssc.2019.12107110.1016/j.jssc.2019.121071 ↗
43. A. Majeed, M.A. Khan, M.Y. Lodhi, R. Ahmad, I. Ahmad, Structural, microwave permittivity, and complex impedance studies of cation (Cr, Bi, Al, In) substituted SrNi-X hexagonal nano-sized ferrites. Ceram. Int. 46(2), 1907–1915 (2020). https://doi.org/10.1016/j.ceramint.2019.09.16810.1016/j.ceramint.2019.09.168 ↗
44. H. Zheng, J. Luo, Q. Wu, P. Zheng, L. Zheng, M. Han, Y. Zhang, Hexagonal barium ferrite films on a Pt(1 1 1)/Si(0 0 1) substrate and their local magnetic properties. J. Magn. Magn. Mater. 479, 99–104 (2019). https://doi.org/10.1016/j.jmmm.2019.02.02410.1016/j.jmmm.2019.02.024 ↗
45. A. Majeed, M.A. Khan, R. Ahmad, M.Y. Lodhi, I. Ahmad, Influence of Cr and Zn substitution on structural, magnetic and dielectric properties of Sr2-xZnxNi2Fe28-yCryO46 X-type hexagonal ferrite. Solid State Sci. 100, 106090 (2020). https://doi.org/10.1016/j.solidstatesciences.2019.10609010.1016/j.solidstatesciences.2019.106090 ↗
46. Y.Y. Meng, M.H. He, Q. Zeng, D.L. Jiao, S. Shukla, R.V. Ramanujan, Z.W. Liu, Synthesis of barium ferrite ultrafine powders by a sol–gel combustion method using glycine gels. J. Alloy. Compd. 583, 220–225 (2014). https://doi.org/10.1016/j.jallcom.2013.08.15610.1016/j.jallcom.2013.08.156 ↗
47. J. Mohammed, H.Y. Hafeez, T.T. Tekou Carol, J. Sharma, U.T. Ismail, S. Kumar Godara, A.K. Srivastava, Structural, dielectric and magnetic properties of Al-Mn substituted nano-sized M-type strontium hexagonal ferrites. Mater. Today: Proc. 18, 533–541 (2019). https://doi.org/10.1016/j.matpr.2019.06.39210.1016/j.matpr.2019.06.392 ↗
48. G.P. Nethala, R. Tadi, G.R. Gajula, K.N. Chidambara Kumar, V. Veeraiah, Investigations on the structural, magnetic and Mossbauer properties of cerium doped strontium ferrite. Phys. B 550, 136–144 (2018). https://doi.org/10.1016/j.physb.2018.08.03510.1016/j.physb.2018.08.035 ↗
49. R.C. Pullar, Hexagonal ferrites: a review of the synthesis, properties and applications of hexaferrite ceramics. Prog. Mater. Sci. 57(7), 1191–1334 (2012). https://doi.org/10.1016/j.pmatsci.2012.04.00110.1016/j.pmatsci.2012.04.001 ↗
50. S. Ramesh, S. Vetrivel, P. Suresh, V. Kaviarasan, Characterization techniques for nano particles: a practical top down approach to synthesize copper nano particles from copper chips and determination of its effect on planes. Mater Today: Proc (2020). https://doi.org/10.1016/j.matpr.2020.01.15710.1016/j.matpr.2020.01.157 ↗
51. B. Bashir, M.F. Warsi, M.A. Khan, M.N. Akhtar, Z.A. Gilani, I. Shakir, A. Wadood, Rare earth Tb3+ doped LaFeO3 nanoparticles: new materials for high frequency devices fabrication. Ceram. Int. 41(7), 9199–9202 (2015). https://doi.org/10.1016/j.ceramint.2015.03.23510.1016/j.ceramint.2015.03.235 ↗