journal article·2009-06

Preparation of nanofibers consisting of MnO/Mn3O4 by using the electrospinning technique: the nanofibers have two band-gap energies

Nasser A. M. Barakat, Kee-Do Woo, S. G. Ansari, Jung-Ahn Ko, Muzafar A. Kanjwal, Hak Yong Kim

Applied Physics A· Volume 95· Issue 3
Publisher page

Abstract

In the present study, nanofibers consisting of manganese monoxide (MnO), which is hard to prepare because of the chemical activity of the manganese metal, and the popular Mn3O4 have been synthesized via the electrospinning technique. The nanofibers were obtained by electrospinning of an aqueous sol–gel consisting of manganese acetate tetra-hydrate and poly(vinyl alcohol). The obtained nanofiber mats were dried in vacuum at 80°C for 24 h and then calcined in argon atmosphere at 900°C for 5 h. According to X-ray diffraction results, the obtained nanofibers contain 65% MnO. Transmission electron microscope analysis reveals good crystallinity of the produced nanofibers. UV–visible spectroscopic analysis has indicated that the produced nanofibers have two band-gap energies, 2 and 3.7 eV, which enhances utilizing of the nanofibers in different applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (34)

Show source-provided references
1. M. Baldi, V.S. Escribano, J.M.G. Amores, F. Milella, G. Busca, Appl. Catal. B: Environ. 17, L175 (1998)10.1016/S0926-3373(98)00013-7 ↗
2. E.R. Stobbe, B.A. Boer, J.W. Geus, Catal. Today 47, 161 (1999)10.1016/S0920-5861(98)00296-X ↗
3. L. Dimesso, L. Heider, H. Hahn, Solid State Ionics 123, 39 (1999)10.1016/S0167-2738(99)00107-1 ↗
4. R.N. Reddy, R.G. Reddy, J. Power Sources 132, 315 (2004)10.1016/j.jpowsour.2003.12.054 ↗
5. M. Toupin, T. Brousse, D. Bélanger, Chem. Mater. 16, 3184 (2004)10.1021/cm049649j ↗
6. V. Subramanian, H. Zhu, R. Vajtai, P.M. Ajayan, B. Wei, J. Phys. Chem. B 109, 20207 (2005)10.1021/jp0543330 ↗
7. Y. Xia, P. Yang, Y. Sun, Y. Wu, B. Mayers, B. Gates, Y. Yin, F. Kim, H. Yan, Adv. Mater. 15, 353 (2003)10.1002/adma.200390087 ↗
8. M. Sugantha, P.A. Ramakrishnan, A.M. Hermann, C.P. Warmsingh, D.S. Ginley, Int. J. Hydrog. Energy 28, 597 (2003)10.1016/S0360-3199(02)00148-9 ↗
9. Y. Zheng, Y. Cheng, F. Bao, Y. Wang, Y. Qin, J. Cryst. Growth 289, 156 (2006)10.1016/j.jcrysgro.2005.09.012 ↗
10. X. Sun, C. Ma, Y. Wang, H. Li, Inorg. Chem. Commun. 5, 747 (2002)10.1016/S1387-7003(02)00544-0 ↗
11. P. Liu, S.H. Lee, Y. Yan, C.E. Tracy, J.A. Turner, J. Power Sources 158, 659 (2006)10.1016/j.jpowsour.2005.10.005 ↗
12. F.A. Al-Sagheer, M.I. Zaki, Colloids Surf. A 173, 193 (2000)10.1016/S0927-7757(00)00607-5 ↗
13. H. Wang, D. Qiana, Z. Lu, Y. Li, R. Chen, W. Zhang, J. Cryst. Growth (2008). doi: 10.1016/j.jcrysgro.2007.01.034
14. Z. Tian, Q. Feng, N. Sumida, Y. Makita, K. Ooi, Chem. Lett. 33, 952 (2004)10.1246/cl.2004.952 ↗
15. Z. Yang, Y. Zhang, W. Zhang, X. Wang, Y. Qian, X. Wen, S. Yang, J. Solid State Chem. 179, 679 (2006)10.1016/j.jssc.2005.11.028 ↗
16. A.G. Leyvaa, P. Stoliara, M. Rosenbuscha, V. Lorenzoa, P. Levya, C. Albonett, M. Cavallini, F. Biscarini, H.E. Troiani, J. Curialec, R.D. Sanchez, J. Solid State Chem. 177, 3949 (2004)10.1016/j.jssc.2004.08.015 ↗
17. S.L. Brock, M. Sanabria, S.L. Suib, V. Urban, P. Thiyagarajan, D.I. Potter, J. Phys. Chem. B 103, 7416 (1999)10.1021/jp991009u ↗
18. W. Sigmund, J. Yuh, H. Park, V. Maneeratana, G. Pyrgiotakis, A. Daga, J. Taylor, J.C. Nino, J. Am. Ceram. Soc. 89, 395 (2006)10.1111/j.1551-2916.2005.00807.x ↗
19. Q. Fan, M.S. Whittingham, Electrochem. Solid-State Lett. 10, A48 (2007)10.1149/1.2422749 ↗
20. C. Shao, H. Guan, Y. Liu, X. Li, X. Yang, J. Solid State Chem. 177, 2628 (2004)10.1016/j.jssc.2004.04.003 ↗
21. D.M. Fernandes, A.A.W. Hechenleitner, E.A.G. Pineda, Thermochim. Acta 441, 101 (2006)10.1016/j.tca.2005.11.006 ↗
22. L. Lua, V. Sahajwalla, C. Kong, D. Harris, Carbon 39, 1821 (2001)10.1016/S0008-6223(00)00318-3 ↗
23. M. Jercher, A. Pring, P.G. Jones, M.D. Raven, Archaeometry 40, 398 (1998)10.1111/j.1475-4754.1998.tb00845.x ↗
24. M. Afzal, P.K. Butt, H. Ahrnad, J. Therm. Anal. 37, 1015 (1991)10.1007/BF01932799 ↗
25. C.D.J. Juan, G. Ismael, Q. Angel, P. Tito, J. Mol. Catal. A: Chem. 228, 283 (2005)10.1016/j.molcata.2004.09.065 ↗
26. T.W. Jun, C.D. Hua, Chem. Pap. 61, 329 (2007)
27. F. Gu, S.F. Wang, M.K. Lu, G.J. Zhou, D. Xu, D.R. Yuan, J. Phys. Chem. B 108, 8119 (2004)10.1021/jp036741e ↗
28. F. Gu, S.F. Wang, M.K. Lu, X.F. Cheng, S.W. Liu, G.J. Zhou, D. Xu, D.R. Yuan, J. Cryst. Growth 262, 182 (2004)10.1016/j.jcrysgro.2003.10.028 ↗
29. F. Gu, C.Z. Li, Y.J. Hu, L.J. Zhang, J. Cryst. Growth 304, 369 (2007)10.1016/j.jcrysgro.2007.03.040 ↗
30. M.P. Dare-Edwards, A.H. Goodenough, A. Hammett, P.R.J. Trevellick, Chem. Soc. Faraday Trans. 9, 2027 (1983)10.1039/f19837902027 ↗
31. R. Xu, H.C. Zeng, Langmuir 20, 9780 (2004)10.1021/la049164+ ↗
32. N.A.M. Barakat, M.S. Khil, F.A. Sheikh, H.Y. Kim, J. Phys, Chem. C 112, 12225 (2008)10.1021/jp8027353 ↗
33. T. He, D.R. Chen, X.L. Jiao, Y.L. Wang, Y.Z. Duan, Chem. Mater. 17, 4023 (2005)10.1021/cm050727s ↗
34. C.S. Cheng, M. Serizawa, H. Sakata, T. Hirayama, Mater. Chem. Phys. 53, 225 (1998)10.1016/S0254-0584(98)00044-3 ↗