journal article·2018-08

Synthesis of carbon nano-spheres and nano-tubes by thermal plasma processing of polypropylene

Sina Mohsenian, Mahdieh Sadat Esmaeili, Jafar Fathi, Babak Shokri

Applied Physics A· Volume 124· Issue 8
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Abstract

Syntheses of carbon nano-spheres and nano-tubes has been experimentally investigated via thermal plasma treatment of polypropylene as a common plastic waste material. Samples were treated in a furnace fitted with a twin DC thermal plasma torch. The resultant solid products were analyzed to determine their composition and morphology by EDS, SEM and TEM analysis. EDS and SEM analysis indicated that if the arc current is more than 100 A, solid products mainly consist of carbon black nano-structures with no impurities. SEM images also showed that the most portion of solid carbons are nano-spheres, however, TEM analysis provided evidences for existing some carbon nano-tubes between nano-spheres. It also demonstrated that with increasing the arc current, diameter of nano-tubes decreases. This method for synthesis of carbon nano-structures may find a way to be considered in industrial waste disposal installation and enhance the economic efficiency of thermal plasma waste treatment technology. Since these valuable nano-structures can be produced from thermal plasma treatment of some non-useful and environmentally hazardous waste materials.
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Research context

OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Diamond and Carbon-based Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. C. Liu, Y.Y. Fan, M. Liu, H.T. Cong, H.M. Cheng, M.S. Dresselhaus, Hydrogen storage in single-walled carbon nanotubes at room temperature. Science 286, 1127–1129 (1999)10.1126/science.286.5442.1127 ↗
2. S.J. Tans, A.R.M. Verschueren, C. Dekker, Room-temperature transistor based on a single carbon nanotube. Nature 393, 49 (1998)10.1038/29954 ↗
3. H. Yoon, S. Ko, J. Jang, Nitrogen-doped magnetic carbon nanoparticles as catalyst supports for efficient recovery and recycling. Chem. Commun. 14, 1468–1470 (2007)10.1039/b616660a ↗
4. L. Zhao, M. Choi, H.S. Kim, S.H. Hong, The effect of multiwalled carbon nanotubes doping on the CO gas sensitivity of SnO2- based nanomaterials. Nanotechnology 18, 445501 (2007)10.1088/0957-4484/18/44/445501 ↗
5. A. Nieto-Márquez, J.L. Valverde, M.A. Keane, Selective low temperature synthesis of carbon nanospheres via the catalytic decomposition of trichloroethylene. Appl. Catal. A Gen. 352, 159–170 (2009)10.1016/j.apcata.2008.10.006 ↗
6. X. Zhao, M. Ohkohchi, M. Wang, S. Iijima, T. Ichihashi, Y. Ando, Preparation of high-grade carbon nanotubes by hydrogen arc discharge. Carbon 35, 775–781 (1997)10.1016/S0008-6223(97)00033-X ↗
7. S.K. Patra, G.M. Rao, Synthesis of carbon nanotubes by ECR plasma-assisted chemical vapor deposition. Appl. Phys. A 80(5), 1113–1115 (2005)10.1007/s00339-003-2426-8 ↗
8. M.R. Maschmann, P.B. Amama, A. Goyal, Z. Iqbal, R. Gat, T.S. Fisher, Parametric study of synthesis conditions in plasma-enhanced CVD of high-quality single-walled carbon nanotubes. Carbon 44, 10–18 (2006)10.1016/j.carbon.2005.07.027 ↗
9. S. Hofmann, C. Ducati, J. Robertson, B. Kleinsorge, Low-temperature growth of carbon nanotubes by plasma-enhanced chemical vapor deposition. Appl. Phys. Lett. 83, 135–137 (2003)10.1063/1.1589187 ↗
10. T. Nozaki, K. Ohnishi, K. Okazaki, U. Kortshagen, Fabrication of vertically aligned single-walled carbon nanotubes in atmospheric pressure non-thermal plasma CVD. Carbon 45, 364–374 (2007)10.1016/j.carbon.2006.09.009 ↗
11. H. Hesamzadeh, B. Ganjipour, S. Mohajerzadeh, A. Khodadadi, Y. Mortazavi, S. Kiani, PECVD-growth of carbon nanotubes using a modified tip-plate configuration. Carbon 42, 1043–1047 (2004)10.1016/j.carbon.2003.12.017 ↗
12. H. Huang, L. Tang, Treatment of organic waste using thermal plasma pyrolysis technology. Energy Convers. Manag. 48, 1331–1337 (2007)10.1016/j.enconman.2006.08.013 ↗
13. T. Charinpanitkul, K. Kanjanaprapakul, N. Leelaviwat, N. Kurukitkoson, K.S. Kim, Effect of arc current on characteristics of nanocarbons prepared by cryogenic arc discharge method. J. Ind. Eng. Chem. 16, 912–917 (2010)10.1016/j.jiec.2010.09.011 ↗
14. S. Mohsenian, M.S. Esmaili, J. Fathi, B. Shokri, Hydrogen and carbon black nano-spheres production via thermal plasma pyrolysis of polymers. Int. J. Hydrog. Energy 41, 16656–16663 (2016)10.1016/j.ijhydene.2016.05.150 ↗
15. F. Fabry, G. Flamant, L. Fulcheri, Carbon black processing by thermal plasma. Analysis of the particle formation mechanism. Chem. Eng. Sci. 56, 2123–2132 (2001)10.1016/S0009-2509(00)00486-3 ↗
16. E. Pfender, Fundamental studies associated with the plasma spray process. Surf. Coat. Technol. 34, 1–14 (1988)10.1016/0257-8972(88)90083-7 ↗
17. Y. Liao, Y. Zheng, Z. Zheng, Q. Li, Numerical simulation of zirconia splat formation and cooling during plasma spray deposition. Appl. Phys. A 122(7), 1–7 (2016)10.1007/s00339-016-0192-7 ↗
18. J. Hlína, J. Šonský, J. Gruber, Y. Cressault, Fast tomographic measurements of temperature in an air plasma cutting torch. J. Phys. D: Appl. Phys. 49(10), 105202 (2016)10.1088/0022-3727/49/10/105202 ↗
19. J. Heberlein, A.B. Murphy, Thermal plasma waste treatment. J. Phys. D: Appl. Phys. 41, 053001 (2008)10.1088/0022-3727/41/5/053001 ↗
20. J.R. Fincke, R.P. Anderson, T.A. Hyde, B.A. Detering, Plasma pyrolysis of methane to hydrogen and carbon black. Ind. Eng. Chem. Res. 41, 1425–1435 (2002)10.1021/ie010722e ↗
21. L. Tang, H. Huang, H. Hao, K. Zhao, Development of plasma pyrolysis/gasification systems for energy efficient and environmentally sound waste disposal. J. Electrostat. 71, 839–847 (2013)10.1016/j.elstat.2013.06.007 ↗
22. L. Tang, H. Huang, Z. Zhao, C.Z. Wu, Y. Chen, Pyrolysis of polypropylene in a nitrogen plasma reactor. Ind. Eng. Chem. Res. 42, 839–847 (2003)
23. M. Gautier, V. Rohani, L. Fulcheri, Direct decarbonization of methane by thermal plasma for the production of hydrogen and high value-added carbon black. Int. J. Hydrog. Energy 42, 28140–28156 (2017)10.1016/j.ijhydene.2017.09.021 ↗
24. Y. Xin, B. Sun, X. Zhu, Z. Yan, X. Zhao, X. Sun, Carbon nanoparticles production by pulsed discharge in liquid alcohols. Vacuum 151, 28140–28156 (2018)10.1016/j.vacuum.2018.02.006 ↗
25. H. Okuno, E. Grivei, F. Fabry, T.M. Gruenberger, J. Gonzalez-Aguilar, A. Palnichenko, L. Fulcheri, N. Probst, J.C. Charlier, Synthesis of carbon nanotubes and nano-necklaces by thermal plasma process. Carbon 42, 2543–2549 (2004)10.1016/j.carbon.2004.05.037 ↗
26. K.S. Kim, G. Cota-Sanchez, C.T. Kingston, M. Imris, B. Simard, G. Soucy, Large-scale production of single-walled carbon nanotubes by induction thermal plasma. J. Phys. D: Appl. Phys. 40, 2375 (2007)10.1088/0022-3727/40/8/S17 ↗
27. D. Harbec, J.L. Meunier, L. Guo, J. Jureidini, A parametric study of carbon nanotubes production from tetrachloroethylene using a supersonic thermal plasma jet. Carbon 45, 2054–2064 (2007)10.1016/j.carbon.2007.05.025 ↗
28. D. Harbec, J.L. Meunier, L. Guo, R. Gauvin, E. Mallah, Carbon nanotubes from the dissociation of C2Cl4 using a dc thermal plasma torch. J. Phys. D: Appl. Phys. 37, 2121 (2004)10.1088/0022-3727/37/15/011 ↗
29. R. Pristavita, J.L. Meunier, D. Berk, Carbon nano-flakes produced by an inductively coupled thermal plasma system for catalyst applications. Plasma Chem. Plasma Process. 31, 393–403 (2011)10.1007/s11090-011-9289-0 ↗
30. J. Hahn, J.H. Han, J.E. Yoo, H.Y. Jung, J.S. Suh, New continuous gas-phase synthesis of high purity carbon nanotubes by a thermal plasma jet. Carbon 42, 877–883 (2004)10.1016/j.carbon.2004.01.073 ↗
31. S. Mohsenian, M.S. Esmaili, B. Shokri, M. Ghorbanalilu, Physical characteristics of twin DC thermal plasma torch applied to polymer waste treatment. J. Electrostat. 76, 231–237 (2015)10.1016/j.elstat.2015.06.004 ↗
32. Z. Jiang, R. Song, W. Bi, J. Lu, T. Tang, Polypropylene as a carbon source for the synthesis of multi-walled carbon nanotubes via catalytic combustion. Carbon, 45, 449–458 (2007)10.1016/j.carbon.2006.08.012 ↗
33. P.K. Tripathi, S. Durbach, N.J. Coville, Synthesis of multi-walled carbon nanotubes from plastic waste using a stainless-steel CVD reactor as catalyst. Nanomaterials, 7, 284 (2017)10.3390/nano7100284 ↗
34. Y. Yao, X. Dai, R. Liu, J. Zhang, Z. Liu, Tuning the diameter of single-walled carbon nanotubes by temperature-mediated chemical vapor deposition. J. Phys. Chem. C 113, 13051–13059 (2009)10.1021/jp901366h ↗
35. X.K. Wang, X.W. Lin, V.P. Dravid, J.B. Ketterson, R.P.H. Chang, Carbon nanotubes synthesized in a hydrogen arc discharge. Appl. Phys. Lett. 66, 2430–2432 (1995)10.1063/1.113963 ↗