journal article·2016-05

Co-electrospinning fabrication and study of structural and electromagnetic interference-shielding effectiveness of TiO2/SiO2 core–shell nanofibers

Omolfajr Nakhaei, Nasser Shahtahmassebi, Mahmood Rezaee Roknabadi, Mohammad Behdani

Applied Physics A· Volume 122· Issue 5
Publisher page

Abstract

The present paper reports novel outcome comprising experimental results on electromagnetic interference (EMI) shielding and radar signal absorption characteristics of one-dimensional (1D) TiO2/SiO2 core–shell nanofibers. 1D TiO2/SiO2 core–shell nanofibers with various concentrations of nanoparticles (NPs) were fabricated using a single-nozzle co-electrospinning method. The core–shell structure of polyvinylpyrrolidone/polyacrylonitrile nanofibers with NPs have been electrospun from the homogeneous solution of polyvinylpyrrolidone (PVP and TiO2 NPs, as core) and polyacrylonitrile (PAN and SiO2 NPs, as shell). The morphologies and structures of TiO2/SiO2 core–shell nanofibers were characterized by XRD, FTIR, EDS, and SEM images. Microwave absorption properties of the synthesized nanofibers were studied using a vector network analyzer between 2 and 20 GHz at room temperature. The maximum EMI-shielding effectiveness of 150 dB is obtained with the dominant shielding mechanism of absorption of EM radiation. The excellent microwave absorption properties of the composites nanofibers are attributed to the special 1D fibrous structure and the effective dielectric loss.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Advanced Antenna and Metasurface Technologies · Dielectric materials and actuators

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. J. Yun, J.S. Im, Y.-S. Lee, H.-I. Kim, Effect of oxyfluorination on electromagnetic interference shielding behavior of MWCNT/PVA/PAAc composite microcapsules. Eur. Polym. J. 46(5), 900–909 (2010)10.1016/j.eurpolymj.2010.02.005 ↗
2. J.-M. Thomassin, C. Jérôme, T. Pardoen, C. Bailly, I. Huynen, C. Detrembleur, Polymer/carbon based composites as electromagnetic interference (EMI) shielding materials. Mater. Sci. Eng. R Rep. 74(7), 211–232 (2013)10.1016/j.mser.2013.06.001 ↗
3. M. Bayat, H. Yang, F.K. Ko, D. Michelson, A. Mei, Electromagnetic interference shielding effectiveness of hybrid multifunctional Fe3O4/carbon nanofiber composite. Polymer (Guildf) 55(3), 936–943 (2014)10.1016/j.polymer.2013.12.042 ↗
4. P. Saini, V. Choudhary, Enhanced electromagnetic interference shielding effectiveness of polyaniline functionalized carbon nanotubes filled polystyrene composites. J. Nanopart. Res. 15(1), 1415 (2013)10.1007/s11051-012-1415-2 ↗
5. D.-H. Kim, Y. Kim, J.-W. Kim, Transparent and flexible film for shielding electromagnetic interference. Mater. Des. 89, 703–707 (2016)10.1016/j.matdes.2015.09.142 ↗
6. L. Kong, X. Yin, Y. Zhang, X. Yuan, Q. Li, F. Ye, L. Cheng, L. Zhang, Electromagnetic wave absorption properties of reduced graphene oxide modified by maghemite colloidal nanoparticle clusters. J. Phys. Chem. C 117, 19701–19711 (2013)10.1021/jp4058498 ↗
7. O. Nakhaei, N. Shahtahmassebi, E. Azhir, Co-precipitation synthesis of CaF2: Er nanocomposites and photoluminescence characterizations of electrospun polyvinyl alcohol/CaF2: Er nanofibers. Indian J. Phys. 88(12), 1245–1250 (2014)10.1007/s12648-014-0574-7 ↗
8. M. Konno, Y. Kishi, M. Tanaka, H. Kawakami, Core/shell-like structured ultrafine branched nanofibers created by electrospinning. Polym. J. 46(11), 792–799 (2014)10.1038/pj.2014.74 ↗
9. M.H.M. Ara, H. Naderi, A. Mobasheri, M.H. Rajabi, R. Malekfar, E. Koushki, Characterization and nonlinear optical properties of PVP/TiO2 nano-fibers doping with Ag colloid nano-particles. Phys. E Low-dimens. Syst. Nanostruct. 48, 124–127 (2013)10.1016/j.physe.2012.11.027 ↗
10. S.-H. Lee, C. Tekmen, W.M. Sigmund, Three-point bending of electrospun TiO2 nanofibers. Mater. Sci. Eng. A 398(1–2), 77–81 (2005)10.1016/j.msea.2005.03.014 ↗
11. Y. Wang, D. Sun, G. Liu, W. Jiang, Synthesis of Fe3O4@SiO2@ZnO core–shell structured microspheres and microwave absorption properties. Adv. Powder Technol. 26, 1537–1543 (2015)10.1016/j.apt.2015.08.014 ↗
12. J. Zheng, Z. Yu, G. Ji, X. Lin, H. Lv, Y. Du, Reduction synthesis of FexOy@SiO2 core–shell nanostructure with enhanced microwave-absorption properties. J. Alloys Compd. 602, 8–15 (2014)10.1016/j.jallcom.2014.03.002 ↗
13. H. Zhou, J. Zhuang, Q. Yan, Q. Liu, Facile preparation and high microwave absorption of C/SiO2 composites with an ordered inter-filled string mesostructure. Mater. Lett. 85, 117–119 (2012)10.1016/j.matlet.2012.07.005 ↗
14. I.W. Nam, H.K. Kim, H.K. Lee, Influence of silica fume additions on electromagnetic interference shielding effectiveness of multi-walled carbon nanotube/cement composites. Constr. Build. Mater. 30, 480–487 (2012)10.1016/j.conbuildmat.2011.11.025 ↗
15. C.K. Hong, K.S. Yang, S.H. Oh, J.-H. Ahn, B.-H. Cho, C. Nah, Effect of blend composition on the morphology development of electrospun fibres based on PAN/PMMA blends. Polym. Int. 57(12), 1357–1362 (2008)10.1002/pi.2481 ↗
16. J.-F. Zhang, D.-Z. Yang, F. Xu, Z.-P. Zhang, R.-X. Yin, J. Nie, Electrospun core–shell structure nanofibers from homogeneous solution of poly(ethylene oxide)/chitosan. Macromolecules 42(14), 5278–5284 (2009)10.1021/ma900657y ↗
17. Y. Dror, W. Salalha, R. Avrahami, E. Zussman, A.L. Yarin, R. Dersch, A. Greiner, J.H. Wendorff, One-step production of polymeric microtubes by co-electrospinning. Small 3(6), 1064–1073 (2007)10.1002/smll.200600536 ↗
18. H. Zhidong, D. Limin, W. Ze, Z. Xianyou, Structure of BaLaxFe12−x O19/SiO2 synthesized by sol–gel method. J. Rare Earths 24(1), 75–77 (2006)10.1016/S1002-0721(07)60327-5 ↗
19. N. Bayal, P. Jeevanandam, Synthesis of TiO2–MgO mixed metal oxide nanoparticles via a sol–gel method and studies on their optical properties. Ceram. Int. 40(10), 15463–15477 (2014)10.1016/j.ceramint.2014.06.122 ↗
20. M. Dawson, C. Ribeiro, M.R. Morelli, Rutile supported anatase nanostructured films as photocatalysts for the degradation of water contaminants. Ceram. Int. 42(1), 808–819 (2016)10.1016/j.ceramint.2015.08.180 ↗
21. Y. Cheng, W. Huang, Y. Zhang, L. Zhu, Y. Liu, X. Fan, X. Cao, Preparation of TiO2 hollow nanofibers by electrospining combined with sol–gel process. CrystEngComm 12, 2256 (2010)10.1039/b922564a ↗
22. M.A. Behnajady, H. Eskandarloo, N. Modirshahla, M. Shokri, Investigation of the effect of sol–gel synthesis variables on structural and photocatalytic properties of TiO2 nanoparticles. Desalination 278(1–3), 10–17 (2011)10.1016/j.desal.2011.04.019 ↗
23. J.-T. Zou, Y.-S. Wang, W.-M. Pang, L. Shi, F. Lu, Synthesis and spectroscopic characterization of completely isotactic polyacrylonitrile. arXiv:1210.2530
24. A. Rawat, H.K. Mahavar, S. Chauhan, A. Tanwar, P.J. Singh, Optical band gap of polyvinylpyrrolidone/polyacrilamide blend thin films. Indian J. Pure Appl. Phys. 50(February), 100–104 (2012)
25. Y. Zhang, P. Li, Porous Zr-doped SiO2 shell/TiO2 core nanoparticles with expanded channels for photocatalysis. Mater. Des. 88, 1250–1259 (2015)10.1016/j.matdes.2015.09.093 ↗
26. E. Ukaji, T. Furusawa, M. Sato, N. Suzuki, The effect of surface modification with silane coupling agent on suppressing the photo-catalytic activity of fine TiO2 particles as inorganic UV filter. Appl. Surf. Sci. 254(2), 563–569 (2007)10.1016/j.apsusc.2007.06.061 ↗
27. Y. Qiu, J. Yin, H. Hou, J. Yu, X. Zuo, Preparation of nitrogen-doped carbon submicrotubes by coaxial electrospinning and their electrocatalytic activity for oxygen reduction reaction in acid media. Electrochim. Acta 96, 225–229 (2013)10.1016/j.electacta.2013.02.097 ↗
28. R. Farsani, S. Raissi, A. Shokuhfar, A. Sedghi, FT-IR study of stabilized PAN fibers for fabrication of carbon fibers. World Acad. Sci. 3, 319–322 (2009)
29. R. Fateh, R. Dillert, D. Bahnemann, Self-cleaning properties, mechanical stability, and adhesion strength of transparent photocatalytic TiO2–ZnO coatings on polycarbonate. ACS Appl. Mater. Interfaces 6(4), 2270–2278 (2014)10.1021/am4051876 ↗
30. T.-W. Shyr, J.-W. Shie, Electromagnetic shielding mechanisms using soft magnetic stainless steel fiber enabled polyester textiles. J. Magn. Magn. Mater. 324(23), 4127–4132 (2012)10.1016/j.jmmm.2012.07.037 ↗
31. B.J. Madhu, S.T. Ashwini, B. Shruthi, B.S. Divyashree, A. Manjunath, H.S. Jayanna, Structural, dielectric and electromagnetic shielding properties of Ni–Cu nanoferrite/PVP composites. Mater. Sci. Eng. B 186, 1–6 (2014)10.1016/j.mseb.2014.02.018 ↗
32. N.F. Colaneri, L.W. Shacklette, EMI shielding measurements of conductive polymer blends. IEEE Trans. Instrum. Meas. 41(2), 291–297 (1992)10.1109/19.137363 ↗
33. P.S. Liu, H.B. Qing, H.L. Hou, Y.Q. Wang, Y.L. Zhang, EMI shielding and thermal conductivity of a high porosity reticular titanium foam. Mater. Des. 92, 823–828 (2016)10.1016/j.matdes.2015.12.105 ↗
34. P. Verma, P. Saini, V. Choudhary, Designing of carbon nanotube/polymer composites using melt recirculation approach: effect of aspect ratio on mechanical, electrical and EMI shielding response. JMADE 88, 269–277 (2015)
35. M. Cao, Z. Hou, B. Wen, J. Yuan, The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon N. Y. 48(3), 788–796 (2009)10.1016/j.carbon.2009.10.028 ↗
36. M. Cao, J. Yang, W. Song, D. Zhang, B. Wen, H. Jin, Z. Hou, J. Yuan, Ferroferric oxide/multiwalled carbon nanotube vs polyaniline/ferroferric oxide/multiwalled carbon nanotube multiheterostructures for highly effective microwave absorption. ACS Appl. Mater. Interfaces 4(12), 6949–6956 (2012)10.1021/am3021069 ↗
37. B. Wen, M. Cao, Z. Hou, W. Song, L. Zhang, M. Lu, H. Jin, X. Fang, W. Wang, J. Yuan, Temperature dependent microwave attenuation behavior for carbon-nanotube/silica composites. Carbon N. Y. 65, 124–139 (2013)10.1016/j.carbon.2013.07.110 ↗