journal article·2004-06

Mechanisms controlling the efficiency of polymer solar cells

V. Dyakonov

Applied Physics A· Volume 79· Issue 1
Publisher page

Abstract

To improve the efficiency of polymer solar cells, it is vital to understand which mechanisms control the current–voltage characteristics of a given device. Temperature and light intensity dependence of the main solar cell parameters are very informative for analyzing losses. We report on the current–voltage characteristics and the external photogeneration quantum yield of ITO/PEDOT:PSS/OC1C10-PPV:PCBM/Al as well as of ITO/PEDOT:PSS/P3HT:PCBM/Al devices investigated in the broad temperature range 120–325 K under variable illumination, between 0.02 and 100 mW/cm2. We discuss the recombination on traps and the low mobility of charge carriers caused by poor morphology of active layers as possible mechanisms limiting the efficiency of these devices.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Thin-Film Transistor Technologies

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References (23)

Show source-provided references
1. C.J. Brabec, V. Dyakonov, J. Parisi, N.S. Sariciftci (Eds.): Organic Photovoltaics: Concepts and Realization, (Springer Verlag, Heidelberg, 2003)10.1007/978-3-662-05187-0 ↗
2. S.E. Shaheen, C.J. Brabec, F. Padinger, T. Fromherz, J.C. Hummelen, N.S. Sariciftci: Appl. Phys. Lett. 78, 841 (2001)10.1063/1.1345834 ↗
3. C.J. Brabec, N.S. Sariciftci, J.C. Hummelen: Adv. Funct. Mater. 11, 15 (2001)10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A ↗
4. F. Padinger, R. Rittberger, N.S. Sariciftci: Adv. Funct. Mater. 13, 85 (2003)10.1002/adfm.200390011 ↗
5. N.S. Sariciftci, L. Smilowitz, A.J. Heeger, F. Wudl: Science 258, 1474 (1992)10.1126/science.258.5087.1474 ↗
6. C.J. Brabec, G. Zerza, G. Cerullo, S. De Silvestri, S. Luzatti, J.C. Hummelen, N.S. Sariciftci: Chem. Phys. Lett. 340, 32 (2001)10.1016/S0009-2614(01)00431-6 ↗
7. I. Montanari, A.F. Nogueira, J. Nelson, J.R. Durrant, C. Winder, M.A. Loi, N.S. Sariciftci, C.J. Brabec: Appl. Phys. Lett. 81, 3001 (2002)10.1063/1.1512943 ↗
8. D. Vageneugden, R. Kiebooms, P. Adriaesens, D. Vanderzande: Acta Polym. 49, 687 (1998)10.1002/(SICI)1521-4044(199812)49:12<687::AID-APOL687>3.3.CO;2-L ↗
9. H. Bässler: Phys. Status Solidi B 175, 15 (1993)10.1002/pssb.2221750102 ↗
10. V.D. Mihailetchi, J.K.J. van Duren, P.W.M. Blom, J.C. Hummelen, R.A.J. Janssen, J.M. Kroon, M.T. Rispens, W.J.H. Verhees, M.M. Wienk: Adv. Funct. Mater. 13 (1), 43 (2003)10.1002/adfm.200390004 ↗
11. I. Riedel, J. Parisi, V. Dyakonov, L. Lutsen, D. Vanderzande, J.C. Hummelen: Adv. Funct. Mater. 14, 38 (2003)10.1002/adfm.200304399 ↗
12. P. Schilinsky, C. Waldauf, I. Riedel, V. Dyakonov, C.J. Brabec: Adv. Mater. (2003), in print
13. C.J. Brabec, A. Cravino, D. Meissner, N.S. Sariciftci, Th. Fromherz, M.T. Rispens, L. Sanchez, J.C. Hummelen: Adv. Funct. Mater. 11, 374 (2001)10.1002/1616-3028(200110)11:5<374::AID-ADFM374>3.0.CO;2-W ↗
14. V. Dyakonov: Physica E 14, 53 (2002)10.1016/S1386-9477(02)00359-4 ↗
15. V. Dyakonov, I. Riedel, C. Deibel, J. Parisi, C.J. Brabec, N.S. Sariciftci, J.C. Hummelen: Mater. Res. Soc. Symp. Proc. 605 (2001)
16. I.D. Parker: J. Appl. Phys. 75, 1656 (1994)10.1063/1.356350 ↗
17. V.D. Mihailetchi, P.W.M. Blom, J.C. Hummelen, M.T. Rispens: J. Appl. Phys. 94, 6849 (2003)10.1063/1.1620683 ↗
18. B.A. Gregg, M.C. Hanna: J. Appl. Phys. 93, 3605 (2003)10.1063/1.1544413 ↗
19. P. Würfel, G.-H. Bauer: In Organic Photovoltaics, Chapt. 4 (Springer, Heidelberg 2003)
20. R.H. Bube: Photoelectronic Properties of Semiconductors (University Press, Cambridge, UK 1992)
21. T.W. Lee, O.O. Park: Macromolecules 11, 801 (2000)
22. Taekyung Ahn, Haiwon Lee, Sien-Ho Han: Appl. Phys. Lett. 80, 392 (2002)10.1063/1.1429292 ↗
23. I. Riedel, N. Martin, F. Giacalone, J.L. Segura, D. Chirvase, J. Parisi, V. Dyakonov: Thin Solid Films (in print) (2004)