Reversible hydrogen-storage functions for mixtures of Li3N and Mg3N2
Source abstract
Abstract
The hydriding and dehydriding reactions occurring in mixtures of lithium and magnesium nitrides (Li3N and Mg3N2) were investigated for the first time in fixed composition ratios. A mixture of Li3N–20 at. % Mg3N2 after heat treatment at 833 K was hydrogenated at 523 K in 35 MPa according to the following overall reaction: 4Li3N+Mg3N2+12H2 $\Leftrightarrow$ 12LiH+3Mg(NH2)2. This reaction is one of the candidates for reversible hydrogen-storage functions in which 9.1 mass % of hydrogen can be stored in the solid state.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Hydrogen Storage and Materials · Ammonia Synthesis and Nitrogen Reduction · Muon and positron interactions and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (23)
Show source-provided references
1. B. Bogdanović, M. Schwickardi: J. Alloys Compd. 253, 1 (1997); Appl. Phys. A 72, 221 (2001)10.1016/S0925-8388(96)03049-6 ↗
2. C.M. Jensen, K.J. Gross: Appl. Phys. A 72, 231 (2001)10.1007/s003390100784 ↗
3. A. Zaluska, L. Zaluski, J.O. Strom-Olsen: Appl. Phys. A 72, 157 (2001)10.1007/s003390100783 ↗
4. G. Sandrock, K. Gross, G. Thomas: J. Alloys Compd. 339, 229 (2002)10.1016/S0925-8388(01)02014-X ↗
5. M.P. Balogh, G.G. Tibbetts, F.E. Pinkerton, G.P. Meisner, C.H. Olk: J. Alloys Compd. 350, 136 (2003)10.1016/S0925-8388(02)00996-9 ↗
6. T. Kiyabayashi, S.S. Srinivasan, D.L. Sun: J. Phys. Chem. A 107, 7671 (2003)10.1021/jp034543h ↗
7. M. Fichtner, O. Fuhr: J. Alloys Compd. 345, 286 (2002)10.1016/S0925-8388(02)00478-4 ↗
8. A. Züttel, S. Rentsch, P. Fischer, P. Wenger, P. Sudan, Ph. Mauron, C. Emmenegger: J. Alloys Compd. 356, 515 (2003)10.1016/S0925-8388(02)01253-7 ↗
9. S. Orimo, Y. Nakamori, A. Züttel: Mater. Sci. Eng. B 108, 51 (2004)10.1016/j.mseb.2003.10.045 ↗
10. K. Miwa, N. Ohba, S. Towata, Y. Nakamori, S. Orimo: Phys. Rev. B 69, 245120 (2004)10.1103/PhysRevB.69.245120 ↗
11. P. Chen, Z. Xiong, J. Luo, J. Lin, K.L. Tan: Nature 420, 302 (2002)10.1038/nature01210 ↗
12. P. Chen, Z. Xiong, J. Luo, J. Lin, K.L. Tan: J. Phys. Chem. 107, 10967 (2003)10.1021/jp034149j ↗
13. T. Ichikawa, S. Isobe, N. Hanada, H. Fujii: J. Alloys Compd. 365, 271 (2003)10.1016/S0925-8388(03)00637-6 ↗
14. Y.H. Hu, E. Ruckenstein: Ind. Eng. Chem. Res. 42, 5135 (2003)10.1021/ie030498o ↗
15. Y.H. Hu, E. Ruckenstein: J. Phys. Chem. A 107, 9737 (2003)10.1021/jp036257b ↗
16. Y. Nakamori, S. Orimo: J. Alloys Compd. 370, 271 (2004); Mater. Sci. Eng. B 108, 48 (2004)10.1016/j.jallcom.2003.08.089 ↗
17. S. Orimo, Y. Nakalmori, G. Kitahara, K. Miwa, N. Ohba, T. Noritake, S. Towata: Appl. Phys. A, DOI:10.1007/s00339-004-2927-0 (2004)10.1007/s00339-004-2927-0 ↗
18. L. Schlapbach, A. Züttel: Nature 414, 353 (2001)10.1038/35104634 ↗
19. B. Bogdanović, G. Sandrock: MRS Bull. 27, 712 (2002)10.1557/mrs2002.227 ↗
20. F.W. Dafert, R. Miklauz: Monatsh. Chem. 31, 981 (1910)10.1007/BF01518423 ↗
21. O. Ruff, H. Goeres: Chem. Ber. 44, 502 (1910)10.1002/cber.19110440178 ↗
22. H. Yamane, T.H. Okabe, O. Ishiyama, Y. Waseda, M, Shimada: J. Alloys Compd. 319, 124 (2001)10.1016/S0925-8388(01)00907-0 ↗
23. V.H. Jacobs, R. Juza: Z. anorg. allg. Chem. 370, 254 (1969)10.1002/zaac.19693700508 ↗