journal article·2026-01-23Open access

Effect of Mg on inclusions, microstructure, and mechanical properties of hot work die steel melted under pressurization

Yafeng Wang, Yang Li, Yuexu Liu, Tuo Wang, Jiaying Pei, Lin Bo, Zhouhua Jiang, Changyong Chen

Abstract

Abstract The influence of magnesium (Mg) treatment on the inclusions, microstructure, and mechanical properties of hot work die steel (5CrNiMo), a typical low alloy hot working die steel, was investigated in this paper. This steel is commonly used in the manufacturing of large and medium-sized forging dies, as well as various engineering components and mechanical parts. The experimental results show that the Mg treatment has a momentous influence on the refinement of the secondary dendritic arm spacing of as-cast steel samples. The secondary dendrite arm spacing decreased from 66.7 μm to 39.2 μm with the Mg content increased from 0.0007 wt% to 0.18 wt%. Furthermore, Mg treatment also contributed to the refinement of the interlamellar spacing of pearlite. The investigation of the quenched microstructure revealed that the Mg treatment led to a reduction in grain size, and the extent of refinement was higher with higher Mg content under the experimental conditions. The tensile properties of the steel exhibited a remarkable improvement due to the refining effect of Mg treatment. In detail, the addition of Mg can increase the tensile strength of the experimental steel from 1,043 MPa to 1,240 MPa and the impact energy from 10.8 J to 15.2 J, with the Mg content increasing from o to 0.069 wt%. A small amount of Mg played a beneficial role in enhancing the strength, plasticity, and toughness of the steel samples. However, excessive Mg content had a detrimental effect on these properties, leading to a decline in strength, plasticity, and toughness.
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Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · Microstructure and Mechanical Properties of Steels · Aluminum Alloy Microstructure Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemical Engineering and Technology, Key Laboratory for Green Chemical Technology of Ministry of Education, Tianjin University , Tianjin 300072 , China

Peric Special Gases Co., Ltd , Hebei 056002 , China

School of Metallurgy, Northeastern University , Shenyang 110819 , Liaoning , China

Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University , Hong Kong , China

School of Materials and Energy, Guangdong University of Technology , 510006 , China

References (37)

Show source-provided references
1. Huang, W, Lei, L, Fang, G. Microstructure evolution of hot work tool steel 5CrNiMoV throughout heating, deformation and quenching. Mater Char 2020;163:110307. https://doi.org/10.1016/j.matchar.2020.110307.10.1016/j.matchar.2020.110307 ↗
2. Emamverdian, AA, Sun, Y, Cao, C, Pruncu, C, Wang, Y. Current failure mechanisms and treatment methods of hot forging tools (dies)-a review. Eng Fail Anal 2021;129:105678. https://doi.org/10.1016/j.engfailanal.2021.105678.10.1016/j.engfailanal.2021.105678 ↗
3. Wang, J, Chen, Y, Zuo, L, Zhao, H, Ma, N. Evaluation of thermal fatigue life and crack morphology in brake discs of low-alloy steel for high-speed trains. Materials 2022;15:6837. https://doi.org/10.3390/ma15196837.10.3390/ma15196837 ↗
4. Shan, B, Chen, J, Chen, S, Ma, M, Ni, L, Shang, F, et al.. Laser cladding of Fe-based corrosion and wear-resistant alloy: genetic design, microstructure, and properties. Surf Coating Technol 2022;433:128117. https://doi.org/10.1016/j.surfcoat.2022.128117.10.1016/j.surfcoat.2022.128117 ↗
5. Lu, J, Gao, S, Sui, X, Long, F, Song, J, Zhao, Z. Synergistic enhancement of mechanical properties and corrosion resistance of 5CrNiMo steel by scanning electron beam irradiation. Vacuum 2025;241:114664. https://doi.org/10.1016/j.vacuum.2025.114664.10.1016/j.vacuum.2025.114664 ↗
6. Lu, J, Song, Z, Qin, H, Huang, H, Sui, X, Weng, Y, et al.. Surface nanocrystallization and mechanical properties of mold steel induced via scanning electron beam treatment. Vacuum 2023;218:112634. https://doi.org/10.1016/j.vacuum.2023.112634.10.1016/j.vacuum.2023.112634 ↗
7. Zhang, M, Wang, X, Qu, K, Liu, S. Effect of rare earth oxide on microstructure and high temperature oxidation properties of laser cladding coatings on 5CrNiMo die steel substrate. Opt Laser Technol 2019;119:105597. https://doi.org/10.1016/j.optlastec.2019.105597.10.1016/j.optlastec.2019.105597 ↗
8. He, X, Guo, H, Gao, W, Liu, J, He, Z. Effects of lanthanum on mechanical properties of 5CrNiMo forging die steel. Journal of Rare Earth Sciences 2007:254–7.
9. Zhang, Y, Wei, G, M Wang. Influence of vanadium-microalloying on microstructure and property of 5CrNiMo die steel. Iron Steel Vanadium Titanium 2022;43:146–51. (Chinese).
10. Ma, W, Q Cai, J Cheng, B Zhao, L Bing, B Liu. Influence of rare earths and titanium complex modification on the microstructures and properties of 5CrNiMo cast steel. Foundry Technol 2018;39:7–13. (Chinese).
11. Xi, Y, H Xing, W Gao. Development of 5CrNiMoV steel hot forming die. Heavy Cast Forg 2004;26:28–9. (Chinese).
12. Li, T, X Wang. Study on strengthening-toughening heat treatment process of 5CrNiMo die-steel. Foundry Technol 2017;38:2847–50. (Chinese).
13. Dong, G. Study on new heat treatment technology of 5CrNiMo die steel. Hot Work Technol 2016;45:170–3. (Chinese).
14. Li, Y, Chen, C, Wang, Q, Yang, H, Ma, S, Sun, M, et al.. Effect of magnesium on microstructure and properties of 440C stainless bearing steel melted under pressurized conditions. J Iron Steel Res Int 2023;30:808–24. https://doi.org/10.1007/s42243-023-00914-8.10.1007/s42243-023-00914-8 ↗
15. Li, Y, Chen, C, Lv, J, Yang, H, Ma, S, Sun, M, et al.. The effect of magnesium treatment on the inclusions, microstructure, and mechanical properties of M7 high-speed steel. J Mater Eng Perform 2024;33:5000–17. https://doi.org/10.1007/s11665-023-08282-w.10.1007/s11665-023-08282-w ↗
16. Lu, P, Feng, H, Li, H, Ling, M, Wang, H, Zhu, H, et al.. A strategy to overcome the negative effect of Mg treatment on localized corrosion and enhance the performance of high-nitrogen martensitic stainless steel by Mg & Ce composite treatment. Corros Sci 2025;249:112852.10.1016/j.corsci.2025.112852 ↗
17. Jiao, W, Li, H, Feng, H, Jiang, Z, Wang, H, Zhu, H, et al.. Significant improvement of cleanliness and macro/microstructure of as-cast AISI M42 high-speed steel by Mg treatment. Metall Mater Trans B 2022;53:1196–211. https://doi.org/10.1007/s11663-022-02436-2.10.1007/s11663-022-02436-2 ↗
18. Ren, J, Tian, J, Jiang, Z, Wang, L, Jiang, C. Effect of Mg–Ce treatment on cleanliness and primary carbides of H13 hot work die steel. Metall Mater Trans B 2025;56:5100–15. https://doi.org/10.1007/s11663-025-03632-6.10.1007/s11663-025-03632-6 ↗
19. Zhu, K, Yang, Z. Effect of Mg addition on the ferrite grain boundaries misorientation in HAZ of low carbon steels. J Mater Sci Technol 2011;27:252–6. https://doi.org/10.1016/s1005-0302(11)60058-3.10.1016/S1005-0302(11)60058-3 ↗
20. Xie, Y, Dong, C, Liu, Z, Yi, Y, Zhou, Y. The influence of rolling reduction on the mechanical, corrosion, osteogenic, and antibacterial properties of Zn–Mg alloys. ACS Omega 2025;10:37141–53. https://doi.org/10.1021/acsomega.5c01732.10.1021/acsomega.5c01732 ↗
21. Tomita, Y. Improved fracture toughness of ultrahigh strength steel through control of non-metallic inclusions. J Mater Sci 1993;28:853–9. https://doi.org/10.1007/bf00400864.10.1007/BF00400864 ↗
22. Jiang, Z, Guang, X, Li, Y, Li, H, Lv, J, Wang, Q. Effect of ultra-high magnesium on SKS51 liquid steel cleanliness and microstructure. ISIJ Int 2019;59:1234–41. https://doi.org/10.2355/isijinternational.isijint-2018-804.10.2355/isijinternational.ISIJINT-2018-804 ↗
23. Gong, W, Jiang, Z, Zhang, L, Chen, C, Dong, Y. Influence of Mg addition on inclusions and mechanical properties of Cr12Mo1V1 steel under high pressure. Mater Sci Eng A 2020;791:139410. https://doi.org/10.1016/j.msea.2020.139410.10.1016/j.msea.2020.139410 ↗
24. Ge, H, Chen, G. Study on nucleation entropy of carbide refinement effect of magnesium on cobalt base alloy. Shanghai Steel Res Inst 1995;4:1–9. (Chinese).
25. Fu, H Effect of RE Mg Ti modification on microstructure and properties of cast high speed steel. J Mater Metall 2002;1:307–10. (Chinese).
26. Yong, Q, Zheng, L. Precipitation of NbC in ferrite and its effect on precipitation-strengthening of microalloy steels. Acta Metall Sin 1984;20:14–21.
27. Gladman, T. Precipitation hardening in metals. Mater Sci Technol 1999;15:30–6. https://doi.org/10.1179/026708399773002782.10.1179/026708399773002782 ↗
28. Kim, B, Boucard, E, Sourmail, T, Martín, D, Gey, N, Castillo, P. The influence of silicon in tempered martensite: understanding the microstructure-properties relationship in 0.5–0.6 wt.% C steels. Acta Mater 2014;68:169–78. https://doi.org/10.1016/j.actamat.2014.01.039.10.1016/j.actamat.2014.01.039 ↗
29. Zener, C. Private communication to CS smith. Trans Am Inst Metal Petrol Eng 1949;175:15–21.
30. Gladman, T. On the theory of the effect of precipitate particles on grain growth in metals. Proc Roy Soc Lond 1966;294:298–309. https://doi.org/10.1098/rspa.1966.0208.10.1098/rspa.1966.0208 ↗
31. Lifshitz, I, Slyozov, V. The kinetics of precipitation from supersaturated solid solutions. J Phys Chem Solid 1961;19:35–50. https://doi.org/10.1016/0022-3697(61)90054-3.10.1016/0022-3697(61)90054-3 ↗
32. Wagner, C. Theory of precipitate change by redissolution. ISIJ Int 1961;65:581–91. https://doi.org/10.1002/bbpc.19610650704.10.1002/bbpc.19610650704 ↗
33. Li, W, L Huang, P Yan, H Ma, Z Pang. Growth behavior of austenite grain upon re-austenizing of low carbon microalloyed steel. Metal Heat Treat 2013;38:19–22. (Chinese).
34. Wang, J, Z Chu, Q Zhang. Study on austenite grain growth behavior of non-quenched and tempered steel. Hot Work Process 2012;41:14–16. (Chinese).
35. Palmiere, E, Garcia, C, Ardo, A. Compositional and microstructural changes which attend reheating and grain coarsening in steels containing niobium. Metall Mater Trans 1994;25:277–86.10.1007/BF02647973 ↗
36. Voronova, NA. Desulfurization of hot metal by magnesium. Minneapolis, MN: International Magnesium Association; 1983.
37. Barannik, I. Granulated magnesium and practice of using it for molten metal treatment. Int Magnesium Assoc 1994;51:82–90.