journal article·2010-03

Enhanced blue-green emission and ethanol sensing of Co-doped ZnO nanocrystals prepared by a solvothermal route

Jin Li, Huiqing Fan, Xiaohua Jia, Weiwei Yang, Pinyang Fang

Applied Physics A· Volume 98· Issue 3
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Abstract

In this paper, we report the structure, optical, and gas-sensing properties of Co-doped ZnO nanocrystals prepared by a simple solvothermal route. The red-shift of the band-gap edge is attributed to a merging of donor and conduction bands due to Co doping. Photoluminescence (PL) spectra were used to study the dependence of doping on the deep-level emission, which show obvious enhanced blue-green emission after Co doping. Gas sensors were prepared and tested for the detection of C2H5OH in air. It is found that the Co-doped nanocrystals have a significantly better sensing performance than pure ZnO, which is comparable to the Au-functionalized ZnO sensors. We provide a possible explanation in terms of the sensing mechanism of the surface reaction process.
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Research context

OpenAlex topics: ZnO doping and properties · Gas Sensing Nanomaterials and Sensors · Mercury impact and mitigation studies

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