journal article·2012-02Open access

Laser cleaning in conservation of stone, metal, and painted artifacts: state of the art and new insights on the use of the Nd:YAG lasers

S. Siano, J. Agresti, I. Cacciari, D. Ciofini, M. Mascalchi, I. Osticioli, A. A. Mencaglia

Applied Physics A· Volume 106· Issue 2

Abstract

In the present work the application of laser cleaning in the conservation of cultural assets is reviewed and some further developments on the interpretation of the associated laser-material interaction regimes are reported. Both the state of the art and new insights mainly focus on systematic approaches addressed to the solution of representative cleaning problems, including stone and metal artifacts along with wall and easel paintings. The innovative part is entirely dedicated to the extension of the application perspective of the Nd:YAG lasers by exploiting the significant versatility provided by their different pulse durations. Besides extensively discussing the specific conservation and physical problems involved in stone and metal cleaning, a significant effort was also made to explore the application potential for wall and easel paintings. The study of the latter was confined to preliminary irradiation tests carried out on prepared samples. We characterized the ablation phenomenology, optical properties, and photomechanical generation associated with the irradiation of optically absorbing varnishes using pulse durations of 10 and 120 ns. Further results concern the nature of the well-known problem of the yellowish appearance in stone cleaning, removal of biological growths and graffiti from stones, cleaning of bronze and iron artifacts and related aspects of laser conversion of unstable minerals, removal of calcareous stratification from wall paintings, and other features
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Cultural Heritage Materials Analysis · Laser-induced spectroscopy and plasma · Conservation Techniques and Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. L. Lazzarini, J.F. Asmus, M. Marchesini, in Proceedings of the 1st Int. Symp. on the Deterioration of Building Stones, La Rochelle (1972), pp. 89–94
2. J.F. Asmus, C.G. Murphy, W.H. Munk, in Developments in Laser Technology II, ed. by R.F. Wuerker. Proc. SPIE, vol. 41 (1973), pp. 19–30
3. J.F. Asmus, Technol. Conserv. 3, 14 (1978)
4. J.F. Asmus, IEEE Circuits Devices Mag. 2, 6 (1986)10.1109/MCD.1986.6311800 ↗
5. R. Salimbeni, R. Pini, S. Siano, G. Calcagno, J. Cult. Heritage 1, 385 (2000)10.1016/S1296-2074(00)01094-3 ↗
6. A. Giusti, C. Biliotti, C. Samarelli, OPD, Restauro 8, 120 (1996)
7. G. Orial, J.P. Gaufillet, in Technologie Industrielle Conservation Restauration du Patrimoine Culturel, Colloque AFTPV/SFIIC, Nice (1989), pp. 118–125
8. G. Orial, in Preservation and Restoration of Cultural Heritage. Proc. of the LCP Cong. (Ecole Polytechnique Fédérale de Lausanne, Lausanne, 1995), pp. 469–479
9. V. Vergès-Belmin, C. Pichot, G. Orial, in Conservation of Stone and Other Materials, ed. by M.J. Thiel. Proc. Int. of the RILEM/UNESCO Congress, Paris (1993), pp. 534–541
10. V. Vergès-Belmin, C. Pichot, G. Orial, in EUROCARE-EUROMARBLE EU 496: Proceedings of the 4th Workshop, ed. by R. Snethlage, V. Vergès-Belmin, Arles, 1993. Forschungsbericht, vol. 13 (Bayerisches Landesamt für Denkmalpflege, Munich, 1993)
11. V. Vergès-Belmin, in Preservation and Restoration of Cultural Heritage. Proc. of the LCP Congress (Ecole Polytechnique Fédérale de Lausanne, Lausanne, 1995), pp. 481–490
12. C. Weeks, Stud. Conserv. 43, 101 (1998)10.2307/1506646 ↗
13. P. Bromblet, M. Labouré, G. Orial, J. Cult. Heritage 4, 17S (2003)10.1016/S1296-2074(02)01222-0 ↗
14. M.I. Cooper, D.C. Emmony, J.H. Larson, in Proceedings of the 7th International Congress on Deterioration and Cleaning of Stone, Lisbon (1992), pp. 1305–1307
15. M.I. Cooper, D.C. Emmony, J.H. Larson, in Proceedings of Conference on Conservation Science in the UK, Glasgow, UK, May (1993), pp. 29–32
16. M.I. Cooper, D.C. Emmony, J. Larson, Opt. Laser Technol. 27, 69 (1995)10.1016/0030-3992(95)93962-Q ↗
17. J. Delgado Rodrigues, A.E. Charola, in Jerónimos Monastery, the Conservation Intervention (Cadernos IPPAR, Lisboa, 2006), pp. 199–206
18. G. Calcagno, M. Koller, Nimmrichter, Restauratoren Blätter (Special Issue: LACONA I), 39 (1997)
19. G. Calcagno, E. Pummer, M. Koller, J. Cult. Heritage 1, S111 (2000)10.1016/S1296-2074(00)00138-2 ↗
20. J. Delgado Rodrigues, A. Bouineau, A. Pasetti, A.F. Belém, D. Garnier, P. Wazen, in Atti del Convegno La pulitura delle superfici dell’architettura, Padova (1995)
21. A. Bouineau, J. Delgado Rodrigues, A. Pasetti, in Conservation et restauration des biens culturels: pierre, pollution atmosphérique, peinture murale, études scientifiques et cas pratiques: actes du Congrès LCP 1995, Montreux 1995, ed. by R. Pancella (Ecole Polytechnique Fédérale de Lausanne, Lausanne, 1996), pp. 707–709
22. S. Siano, F. Margheri, P. Mazzinghi, R. Pini, R. Salimbeni, G. Toci, M. Vannini, in Proc. Int. Conf. on LASERS 95, Charleston, USA (1995), pp. 441–444
23. S. Siano, F. Margheri, P. Mazzinghi, R. Pini, R. Salimbeni, Appl. Opt. 36, 7073 (1997)10.1364/AO.36.007073 ↗
24. S. Siano, F. Fabiani, R. Pini, R. Salimbeni, M. Giamello, G. Sabatini, J. Cult. Heritage 1, S47 (2000)10.1016/S1296-2074(00)00194-1 ↗
25. I. Gobernado-Mitre, A.C. Prieto, V. Zafiropulos, Y. Spetsidou, C. Fotakis, Appl. Spectrosc. 51, 1125 (1997)10.1366/0003702971941944 ↗
26. P.V. Maravelaki, V. Zafiropulos, V. Kylikoglou, M.P. Kalaitzaki, C. Fotakis, Spectrochim. Acta B 52, 41 (1997)10.1016/S0584-8547(96)01573-X ↗
27. P.V. Maravelaki-Kalaitzaki, V. Zafiropulos, C. Fotakis, Appl. Surf. Sci. 148, 92 (1999)10.1016/S0169-4332(99)00125-7 ↗
28. P. Maravelaki-Kalaitzaki, V. Zafiropulos, P. Pouli, D. Anglos, C. Balas, R. Salimbeni, S. Siano, R. Pini, J. Cult. Heritage 4, 77s (2003)10.1016/S1296-2074(02)01151-2 ↗
29. S. Klein, T. Stratoudaki, V. Zafiropulos, J. Hildenhagen, K. Dickmann, T. Lehmkuhl, Appl. Phys. A 69, 441 (1999)10.1007/s003390051029 ↗
30. G. Marakis, P. Maravelaki, V. Zafiropulos, S. Klein, J. Hildenhagen, K. Dickmann, J. Cult. Heritage 1, S61 (2000)10.1016/S1296-2074(00)00193-X ↗
31. G. Sabatini, M. Giamello, R. Pini, S. Siano, R. Salimbeni, J. Cult. Heritage 1, S1 (2000)10.1016/S1296-2074(00)00144-8 ↗
32. M. Labouré, P. Bromblet, G. Orial, G. Wiedemann, C. Simon Boisson, J. Cult. Heritage 1, S21 (2000)10.1016/S1296-2074(00)00195-3 ↗
33. R. Salimbeni, R. Pini, S. Siano, Spectrochim. Acta B 56, 877 (2001)10.1016/S0584-8547(01)00197-5 ↗
34. L. Bartoli, P. Pouli, C. Fotakis, S. Siano, R. Salimbeni, Laser Chem. 2006, 81750 (2006)10.1155/2006/81750 ↗
35. W. Kautek, E. Konig, C. Fotakis, V. Vergès-Belmin, K. Watkins, G. Bonsanti (eds.), Lasers in the Conservation of Artworks: Proc. of the Int. Conf. LACONA I, Heraklion, Crete, Greece, 4–6 October 1995 (Restauratoren Blätter, Wien, 1997) (Special Issue: LACONA I)
36. R. Salimbeni, G. Bonsanti (eds.), Lasers in the Conservation of Artworks: Proc. of the Int. Conf. LACONA III, Florence, Italy, 26–29 April 1999, J. Cult. Heritage 1(1) (2000)
37. V. Verges-Belmin (ed.), Lasers in the Conservation of Artworks: Proc. Int. Conf. LACONA IV, Paris, France, 11–14 September 2001, J. Cult. Heritage 4(1) (2003)
38. K. Dickmann, C. Fotakis, J.F. Asmus (eds.), Lasers in the Conservation of Artworks: Proc. Int. Conf. LACONA V, Osnabrück, Germany, 15–18 September 2003 (Springer, Heidelberg, 2005)
39. J. Nimmrichter, W. Kautek, M. Schreiner (eds.), Lasers in the Conservation of Artworks: Proc. Int. Conf. LACONA VI, Vienna, Austria, 21–25 September 2005 (Springer, Heidelberg, 2007)
40. M. Castillejo, P. Moreno, M. Oujja, R. Radvan, J. Ruiz (eds.), Lasers in the Conservation of Artworks: Proc. Int. Conf. LACONA VII, Madrid, Spain, 17–21 September 2007 (CRC Press, Taylor & Francis Group, London, 2008)10.1201/9780203882085 ↗
41. R. Radvan, J.F. Asmus, M. Castillejo, P. Pouli, A. Nevin, Lasers in the Conservation of Artworks: Proc. Int. Conf. LACONA VIII, Sibiu, Romania, 21–25 September 2009 (CRC Press, Taylor & Francis Group, Boca Raton, 2011)10.1201/b10567 ↗
42. M. Cooper, Laser Cleaning in Conservation (Butterworth Heinemann, Oxford, 1998)
43. C. Fotakis, D. Anglos, V. Zafiropulos, S. Georgiou, V. Tornari, Lasers in the Preservation of Cultural Heritage: Principles and Applications. Series in Optics and Optoelectronics (CRC Press, Taylor & Francis Group, Boca Raton, 2007)
44. S. Siano, in Handbook on the Use of Lasers in Conservation and Conservation Science, ed. by M. Schreiner, M. Strlič. http://alpha1.infim.ro/cost/pagini/handbook/chapters/prin_cle.htm
45. S. Siano, R. Salimbeni, Acc. Chem. Res. 43, 739 (2010)10.1021/ar900190f ↗
46. S. Georgiou, D. Anglos, C. Fotakis, Contemp. Phys. 49, 1 (2008)10.1080/00107510802038398 ↗
47. R. Pini, S. Siano, R. Salimbeni, V. Piazza, A.M. Iannucci, M. Giamello, G. Sabatini, F. Bevilacqua, J. Cult. Heritage 1, S93 (2000)
48. M. Cooper, S. Sportun, in LACONA VI Proc., ed. by J. Nimmrichter, W. Kautek, M. Schreiner (Springer, Heidelberg, 2007), pp. 55–64
49. P. Pouli, K. Frantzikinaki, E. Papakonstantinou, V. Zafiropulos, C. Fotakis, in LACONA V Proc., ed. by K. Dickmann, C. Fotakis, J.F. Asmus (Springer, Heidelberg, 2005), pp. 333–340
50. A. Giusti (ed.), Donatello restaurato. I marmi del pulpito di Prato. (Maschietto&Musolino, Siena, 2000)
51. R. Salimbeni, R. Pini, S. Siano, in 4th EC Conf. on Research for Protection, Conservation and Enhancement of Cultural Heritage: Opportunities for European Enterprises, Strasbourg (2000), pp. 65–73
52. S. Siano, R. Salimbeni, R. Pini, M. Matteini, S. Porcinai, A.M. Giusti, A. Casciani, J. Cult. Heritage 4, 123s (2003)
53. M. Giamello, D. Pinna, S. Porcinai, G. Sabatini, S. Siano, in Proc. 10th Inter. Cong. on Deterioration and Conservation of Stone, Stockholm (2004), pp. 841–848
54. S. Siano, A. Giusti, D. Pinna, S. Porcinai, M. Giamello, G. Sabatini, R. Salimbeni, in LACONA V Proc., ed. by K. Dickmann, C. Fotakis, J.F. Asmus (Springer, Berlin, 2005), pp. 171–178
55. A. Sansonetti, A. Pasetti, in Proc. of 4th Int. Symp. on the Conservation of Monuments in the Mediterranean, vol. 3 (1997), pp. 345–354
56. V. Vergès-Belmin, C. Dignard, J. Cul. Heritage, 4, 238 (2003)10.1016/S1296-2074(02)01203-7 ↗
57. S. Klein, F. Fekrsanati, J. Hildenhagen, K. Dickmann, H. Uphoff, Y. Marakis, V. Zafiropulos, Appl. Surf. Sci. 171, 243 (2001)10.1016/S0169-4332(00)00706-6 ↗
58. K. Dickmann, S. Klein, V. Zafiropulos, in Laser Techniques and Systems in Art Conservation, ed. by R. Salimbeni. Proc. SPIE, vol. 4402 (SPIE, Bellingham, 2001), pp. 54–6710.1117/12.445675 ↗
59. P. Pouli, G. Totou, V. Zafiropulos, C. Fotakis, M. Oujja, E. Rebollar, M. Castillejo, C. Domingo, A. Laborde, in LACONA VI Proc., ed. by J. Nimmrichter, W. Kautek, M. Schreiner (Springer, Heidelberg, 2007), pp. 105–114
60. S. Siano, M. Giamello, L. Bartoli, A. Mencaglia, V. Parfenov, R. Salimbeni, Laser Phys. 18, 27 (2008)10.1134/S1054660X08010064 ↗
61. F. Margheri, S. Modi, L. Masotti, P. Mazzinghi, R. Pini, S. Siano, R. Salimbeni, J. Cult. Heritage 1, S119 (2000)10.1016/S1296-2074(00)00187-4 ↗
62. G. Marakis, P. Pouli, V. Zafiropoulos, P. Maravelaki-Kalaitzaki, J. Cult. Heritage 4, S83 (2003)10.1016/S1296-2074(02)01208-6 ↗
63. S. Batishche, A. Englezis, T. Gorovets, A. Kouzmouk, U. Pilipenka, P. Pouli, H. Tatur, Appl. Surf. Sci. 248, 264 (2005)10.1016/j.apsusc.2005.03.046 ↗
64. P. Pouli, C. Fotakis, B. Hermosin, C. Saiz-Jimenez, C. Domingo, M. Oujja, M. Castillejo, Spectrochim. Acta A 71, 932 (2008)10.1016/j.saa.2008.02.031 ↗
65. V. Zafiropulos, P. Pouli, V. Kylikoglou, P. Maravelaki-Kalaitzaki, B.S. Lukyanchuk, A. Dogarion, in LACONA V Proc. (Springer, Heidelberg, 2005), pp. 311–318
66. E. Tanguy, N. Huet, Vinçotte, in LACONA V Proc., ed. by K. Dickmann, C. Fotakis, J.F. Asmus (Springer, Heidelberg, 2005), pp. 125–132
67. K. Liu, E. Garmire, Appl. Opt. 34, 4409 (1995)10.1364/AO.34.004409 ↗
68. C. Gómez, A. Costela, I. García-Moreno, R. Sastre, Appl. Surf. Sci. 252, 2782 (2006)10.1016/j.apsusc.2005.04.051 ↗
69. S. Klein, T. Stratoudaki, Y. Marakis, V. Zafiropulos, K. Dickmann, Appl. Surf. Sci. 157, 1 (2000)10.1016/S0169-4332(99)00561-9 ↗
70. R.M. Esbert, C.M. Grossi, A. Rojo, F.J. Alonso, M. Montoto, J. Ordaz, M.C.P. de Andres, C. Escudero, E. Barrera, Sebastian, C. Rodriguez-Navarro, K. Elert, J. Cult. Heritage 4, s50 (2003)10.1016/S1296-2074(02)01227-X ↗
71. C.M. Grossi, F.J. Alonso, R.M. Esbert, A. Rojo, Color Res. Appl. 32, 152 (2007)10.1002/col.20299 ↗
72. P. Leavengood, J. Twilley, J.F. Asmus, J. Cult. Heritage 1, S71 (2000)10.1016/S1296-2074(00)00191-6 ↗
73. E. Sarantopoulou, A.C. Cefalas, in Ultraviolet Spectroscopy and UV Lasers (Dekker, New York, 2002), pp. 191–227
74. A. de Cruz, M.L. Wolbarsht, A. Andreotti, M.P. Colombini, D. Pinna, C.F. Culberson, Stud. Conserv. 54, 268 (2009)10.1179/sic.2009.54.4.268 ↗
75. I. Gomoiu, R. Radvan, E. Sarantopoulou, A.C. Cefalas, in Handbook on the Use of Lasers in Conservation and Conservation Science, ed. by M. Schreiner, M. Strlič. http://alpha1.infim.ro/cost/pagini/handbook/index.htm
76. R. Salimbeni, R. Pini, S. Siano, J. Cult. Heritage 4, 72s (2003)10.1016/S1296-2074(02)01149-4 ↗
77. K. Dörschel, G. Müller, in Future Trend in Biomedical Applications of Lasers. Proc. SPIE, vol. 1525 (SPIE, Bellingham, 1991), pp. 253–27810.1117/12.48200 ↗
78. J. Agresti, A.A. Mencaglia, S. Siano, Anal. Bioanal. Chem. 395, 2255 (2009)10.1007/s00216-009-3053-9 ↗
79. S. Siano, R. Salimbeni, Stud. Conserv. 46, 269 (2001)10.2307/1506776 ↗
80. J. Debin, L. Yi, G. Min, in Proc. of the EEC China Workshop on Preservation of Cultural Heritages, Xian, Shaanxi, China (1991), pp. 102–109
81. R. Pini, S. Siano, R. Salimbeni, M. Pasquinucci, M. Miccio, J. Cult. Heritage 1, S129 (2000)
82. J. Larson, in From Marble to Chocolate: The Conservation of Modern Sculpture, ed. by J. Heuman. Tate Gallery Conference (Archetype Publications, London, 1995), pp. 53–58
83. C.A. Cottam, D.C. Emmony, J. Larson, S. Newman, Restauratorenblätter (Special Issue), 95 (1997)
84. S. Siano, R. Pini, S. Salimbeni, A. Giusti, M. Matteini, J. Cult. Heritage 4, 140s (2003)
85. S. Siano, F. Grazzi, V.A. Parfenov, J. Opt. Technol. 75, 419 (2008)10.1364/JOT.75.000419 ↗
86. M. Matteini, C. Lalli, I. Tosini, A. Giusti, S. Siano, J. Cult. Heritage 4, 147s (2003)10.1016/S1296-2074(02)01190-1 ↗
87. S. Siano, M. Miccio, P. Palleschi, in Un tesoro dal mare, ed. by A. Camilli (Bandecchi & Vivaldi, Pontedera, 2004), pp. 87–92
88. S. Siano, R. Pini, S. Salimbeni, M. Vannini, Appl. Phys. B 62, 503 (1996)10.1007/BF01081051 ↗
89. P. Belluzzo, S. Siano, G. Pieri, G. Lanterna, C. Innocenti, Kermes 67/68, 59 (2007)
90. S. Siano, A. Casciani, A. Giusti, M. Matteini, R. Pini, S. Porcinai, R. Salimbeni, J. Cult. Heritage 4, 123s (2003)
91. S. Siano, M.L. Nicolai, S. Porcinai, in Verrocchio’s David Restored, ed. by B. Paolozzi Strozzi et al. (Giunti, Firenze, 2003), pp. 97–108
92. S. Siano, F. Grazzi, Nuovo Cimento C 30, 123 (2007)
93. S. Agnoletti, A. Brini, E. Formigli, S. Francolini, M. Miccio, S. Siano, OPD, Restauro 15, 84 (2003)
94. F. Burrini, S. Gennai, in Il ritorno d’amore: l’Attis di Donatello restaurato, ed. by B. Paolozzi Strozzi (Museo Nazionale del Bargello, Firenze, 2005), pp. 100–116
95. M.L. Nicolai, in Donatello, il David restaurato, ed. by B. Paolozzi Strozzi (Giunti editore, Firenze, 2008), pp. 160–167
96. S. Agnoletti, A. Brini, E. Della Schiava, S. Gennai, A. Mignemi, N. Salvioli, D. Scapati, C. Valcepina, in I grandi bronzi del Battistero: l’arte di Vincenzo Danti discepolo di Michelangelo, ed. by C. Davis, B. Paolozzi Strozzi (Giunti editore, Firenze, 2008), pp. 370–381
97. M. Froidevaux, M. Cooper, P. Platt, K. Watkins, in LACONA VII Proc., ed. by M. Castillejo, P. Moreno, M. Oujja, R. Radvan, J. Ruiz (CRC Press, Taylor & Francis Group, London, 2008), pp. 191–198
98. K. Dickmann, J. Hildenhagen, J. Studer, E. Müsch, in LACONA V Proc., ed. by K. Dickmann, C. Fotakis, J.F. Asmus (Springer, Heidelberg, 2005), pp. 71–77
99. Y.S. Koh, I. Sarady, J. Cult. Heritage 4, 129s (2003)
100. Y.S. Koh, Sárady, in LACONA V Proc., ed. by K. Dickmann, C. Fotakis, J.F. Asmus (Springer, Heidelberg, 2005), pp. 95–100