journal article·2018-09

Comparing the effect of different surfactants on the aggregation and electrical contact properties of graphene nanoplatelets

Atiweena Krittayavathananon, Xiuting Li, Christopher Batchelor-McAuley, Montree Sawangphruk, Richard G. Compton

Publisher page

Abstract

Abstract We report the influence of different surfactants, Triton X-100, sodium dodecyl sulfate (SDS) and cetrimonium bromide (CTAB), on the suspended graphene nanoplatelets (GNPs) in aqueous solution studied via a single entity electrochemical technique. This method simply requires recording the current responses resulting from the impacts of individual and aggregated GNPs with an interdigitated gold electrode array. Upon impact the nanomaterial can bridge across two interdigitated gold microbands creating an electrical contact. The current magnitude reflects both the agglomeration state of the material and the contact resistance between the gold array and the carbon nanomaterial. The sensitivity of the magnitude of the current steps to the identity of the used surfactant was further evidenced, indicating the influence of these surfactants upon the electrical connectivity of the nanomaterial to the electrode substrate.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Conducting polymers and applications · Electrochemical Analysis and Applications · Molecular Junctions and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. Graphene-based nanomaterials and their electrochemistry10.1039/c002690p ↗
2. Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction10.1126/science.1168049 ↗
3. Functionalized carbon nanotubes for molecular hydrogen sensors10.1002/1521-4095(200109)13:18<1384::AID-ADMA1384>3.0.CO;2-8 ↗
4. Carbon nanotubule membranes for electrochemical energy storage and production10.1038/30694 ↗
5. Palladium nanoparticles decorated on reduced graphene oxide rotating disk electrodes toward ultrasensitive hydrazine detection: effects of particle size and hydrodynamic diffusion10.1021/ac503446q ↗
6. Enhancing the charge-storage performance of N-doped reduced graphene oxide aerogel supercapacitors by adsorption of the cationic electrolytes with single-stand deoxyribonucleic acid10.1016/j.carbon.2016.08.018 ↗
7. Nitrogen and oxygen dual-doped carbon hydrogel film as a substrate-free electrode for highly efficient oxygen evolution reaction10.1002/adma.201305608 ↗
8. Morphology and properties of polyester/exfoliated graphite nanocomposites10.1021/ma702385h ↗
9. Processable aqueous dispersions of graphene nanosheets10.1038/nnano.2007.451 ↗
10. Graphene-based composite thin films for electronics10.1021/nl8035367 ↗
11. Cationic surfactant mediated exfoliation of graphite into graphene flakes10.1016/j.carbon.2009.07.049 ↗
12. Flexible, transparent, conducting films of randomly stacked graphene from surfactant-stabilized, oxide-free graphene dispersions10.1002/smll.200901162 ↗
13. High-concentration, surfactant-stabilized graphene dispersions10.1021/nn1005304 ↗
14. Solution phase production of graphene with controlled thickness via density differentiation10.1021/nl902200b ↗
15. Dispersions of non-covalently functionalized graphene with minimal stabilizer10.1021/nn302784m ↗
16. Improving single-carbon-nanotube–electrode contacts using molecular electronics10.1021/acs.jpclett.7b01771 ↗
17. Quantifying single-carbon nanotube–electrode contact via the nanoimpact method10.1021/acs.jpclett.6b02899 ↗
18. The solution phase aggregation of graphene nanoplates10.1016/j.apmt.2018.01.001 ↗
19. Photoinduced charge and energy transfer in molecular wires10.1039/C4CS00221K ↗
20. The magnitude of current steps in the nano-impact experiment shows a decreasing order: SDS>CTAB>Triton X-100, while their molecular sizes have opposite order, indicating that the effect is likely dominated by the molecular size of the surfactants. The effects of the charge of surfactant might be secondary.
21. The size, shape, and hydration of nonionic surfactant micelles. Triton X-10010.1021/j100526a010 ↗
22. Structural behaviour of mixed cationic surfactant micelles: a small-angle neutron scattering study10.1016/j.jcis.2012.05.015 ↗
23. Size of sodium dodecyl sulfate micelles in aqueous solutions as studied by positron annihilation lifetime spectroscopy10.1021/jp960644m ↗
24. Ionic surfactant aggregates in saline solutions: sodium dodecyl sulfate (SDS) in the presence of excess sodium chloride (NaCl) or calcium chloride (CaCl2)10.1021/jp901228v ↗
25. Single graphene nanoplatelets: capacitance, potential of zero charge and diffusion coefficient10.1039/C5SC00623F ↗
26. Stochastic detection and characterisation of individual ferrocene derivative tagged graphene nanoplatelets10.1039/C5AN02550H ↗