journal article·2019-03

Surface enhanced Raman scattering on molecule junction

M. Kiguchi, A. Aiba, S. Fujii, S. Kobayashi

Publisher page

Abstract

Abstract Surface enhanced Raman scattering (SERS) is a powerful tool to study a small number of molecules adsorbed on metal surface. Recently, SERS is utilized to investigate the atomic structure of the molecule junction, which is a key component of molecular electronic devices. It is because the molecule is trapped between nano gap electrodes, and strong enhanced field is formed in the gap. The Raman signal from the molecule in the molecular junction is selectively observed. The SERS was first studied for the molecule junction, where small number of molecules bridge metal electrodes. Currently, the SERS of the single molecule junction is also reported. In this review, we discuss the history of the SERS of the molecule junction, and application of SERS to the molecule junction. Structural change induced by the application of the voltage across the junction and the chemical reaction on the single molecule junction have been reported with SERS.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Molecular Junctions and Nanostructures · Gold and Silver Nanoparticles Synthesis and Applications · Advanced biosensing and bioanalysis techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. Electronics using hybrid-molecular and mono-molecular devices10.1038/35046000 ↗
2. Single-molecule junctions for molecular electronics10.1039/C6TC03268K ↗
3. Rectification and stability of a single molecular diode with controlled orientation10.1038/nchem.392 ↗
4. Rectifying electron-transport properties through stacks of aromatic molecules inserted into a self-assembled cage10.1021/jacs.5b00086 ↗
5. Stereoelectronic switching in single-molecule junctions10.1038/nchem.2180 ↗
6. Single molecular resistive switch obtained via sliding multiple anchoring points and varying effective wire length10.1021/ja413104g ↗
7. Highly-conducting molecular circuits based on antiaromaticity10.1038/ncomms15984 ↗
8. Bowl inversion and electronic switching of buckybowls on gold10.1021/jacs.6b04741 ↗
9. Observation of molecular orbital gating10.1038/nature08639 ↗
10. Comprehensive suppression of single-molecule conductance using destructive sigma-interference10.1038/s41586-018-0197-9 ↗
11. Highly conductive molecular junctions based on direct binding of benzene to platinum electrodes10.1103/PhysRevLett.101.046801 ↗
12. A stellar relic from the early Milky Way10.1038/nature01142 ↗
13. Effects of hydration on molecular junction transport10.1038/nmat1754 ↗
14. Benzenedithiol: a broad-range single-channel molecular conductor10.1021/nl201777m ↗
15. Evidence for a single hydrogen molecule connected by an atomic chain10.1103/PhysRevLett.98.146802 ↗
16. Raman-spectra of pyridine adsorbed at a silver electrode10.1016/0009-2614(74)85388-1 ↗
17. Surface Raman spectroelectrochemistry. 1. Heterocyclic, aromatic, and aliphatic-amines adsorbed on anodized silver electrode10.1016/S0022-0728(77)80224-6 ↗
18. Surface-enhanced spectroscopy10.1103/RevModPhys.57.783 ↗
19. Field enhancement in subnanometer metallic gaps10.1103/PhysRevB.83.193404 ↗
20. Electromagnetic contributions to single-molecule sensitivity in surface-enhanced Raman scattering10.1103/PhysRevE.62.4318 ↗
21. Revealing the quantum regime in tunnelling plasmonics10.1038/nature11653 ↗
22. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering10.1126/science.275.5303.1102 ↗
23. Single molecule detection using surface-enhanced Raman scattering (SERS)10.1103/PhysRevLett.78.1667 ↗
24. Study of molecular junctions with a combined surface-enhanced Raman and mechanically controllable break junction method10.1021/ja0648615 ↗
25. Conductance and SERS measurement of benzenedithiol molecules bridging between Au electrodes10.1021/jp3112638 ↗
26. Charge-transfer resonance Raman process in surface-enhanced Raman-scattering from P-aminothiophenol adsorbed on silver – Herzberg–Teller contribution10.1021/j100099a038 ↗
27. Charge-transfer theory of surface enhanced Raman spectroscopy: Herzberg–Teller contributions10.1063/1.450037 ↗
28. Thermoelectricity in molecular junctions10.1126/science.1137149 ↗
29. Electromigrated nanoscale gaps for surface-enhanced Raman spectroscopy10.1021/nl070625w ↗
30. Simultaneous measurements of electronic conduction and Raman response in molecular junctions10.1021/nl073346h ↗
31. Detection of heating in current-carrying molecular junctions by Raman scattering10.1038/nnano.2008.304 ↗
32. Vibrational and electronic heating in nanoscale junctions10.1038/nnano.2010.240 ↗
33. Revealing the molecular structure of single-molecule junctions in different conductance states by fishing-mode tip-enhanced Raman spectroscopy10.1038/ncomms1310 ↗
34. Single molecule dynamics at a mechanically controllable break junction in solution at room temperature10.1021/ja307821u ↗
35. Site-selection in single-molecule junction for highly reproducible molecular electronics10.1021/jacs.5b11559 ↗
36. Fluctuation in interface and electronic structure of single-molecule junctions investigated by current versus bias voltage characteristics10.1021/jacs.7b13694 ↗
37. Enhancement of SERS background through charge transfer resonances on single crystal gold surfaces of various orientations10.1021/ja407459t ↗
38. Resolving metal–molecule interfaces at single-molecule junctions10.1038/srep26606 ↗
39. Voltage tuning of vibrational mode energies in single-molecule junctions10.1073/pnas.1320210111 ↗
40. Plasmon-induced conductance enhancement in single-molecule junctions10.1021/jz4014008 ↗
41. Plasmon-mediated electron transport in tip-enhanced Raman spectroscopic junctions10.1021/acs.jpclett.5b01902 ↗
42. Voltage-driven conformational switching with distinct Raman signature in a single-molecule junction10.1021/jacs.7b12818 ↗
43. Electrical and SERS detection of disulfide-mediated dimerization in single-molecule benzene-1,4-dithiol junctions10.1039/C8SC00727F ↗
44. Dynamic characterization of the postbreaking behavior of a nanowire10.1021/jp8055448 ↗