Liquid elementary metals and alloys: Synthesis, characterization, properties, and applications
Source abstract
Abstract
Liquid elementary metals and alloys at room or low temperatures have recently been attracting great attention due to their combined feature of metallic as well as the liquid state in nature, which can be particularly important in future electronics, catalysts, and sensors. In addition, their surface skin is highly sensitive to the ambient environment, providing highly flexible platforms for accommodating surface modification and chemical reactions to extend their implementation. In this review, the synthesis routes and characterization techniques of liquid elementary metals and alloys in both forms of bulk and micro/nano-scale droplets are critically discussed. The corresponding electrical, chemical, electrochemical, mechanical, and thermal properties of either the bulk or surface states are summarized. Furthermore, their implementations in electronics, catalysis, energy storage, cooling, radio frequency (RF) and biomedical devices are categorized and reviewed. Finally, the current challenges and prospects of liquid metal research are provided.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Nanomaterials and Printing Technologies · Advanced Memory and Neural Computing · Transition Metal Oxide Nanomaterials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Viscosity effect on GaInSn studied by XPS10.1002/sia.1817 ↗
2. Solar energy: potential and future prospects10.1016/j.rser.2017.09.094 ↗
3. Recent advances and emerging trends in photo-electrochemical solar energy conversion10.1002/aenm.201802877 ↗
4. Thermal energy storage materials and systems for solar energy applications10.1016/j.rser.2016.10.021 ↗
5. A short history of fusible metals and alloys–towards room temperature liquid metals10.1002/ejic.202200313 ↗
6. A gallium-based magnetocaloric liquid metal ferrofluid10.1021/acs.nanolett.7b04050 ↗
7. The metal flux: a preparative tool for the exploration of intermetallic compounds10.1002/anie.200462170 ↗
8. A liquid metal reaction environment for the room-temperature synthesis of atomically thin metal oxides10.1126/science.aao4249 ↗
9. Wafer-Scale synthesis of semiconducting SnO monolayers from interfacial oxide layers of metallic liquid tin10.1021/acsnano.7b04856 ↗
10. Liquid metal batteries: past, present, and future10.1021/cr300205k ↗
11. A review of solar collectors and thermal energy storage in solar thermal applications10.1016/j.apenergy.2012.11.051 ↗
12. Historical and recent development of concentrating photovoltaic cooling technologies10.1016/j.rser.2016.01.083 ↗
13. Uniform cooling of photovoltaic panels: a review10.1016/j.rser.2015.12.064 ↗
14. Opportunities and challenges in micro-and nano-technologies for concentrating photovoltaic cooling: a review10.1016/j.rser.2012.11.051 ↗
15. Utilizing p-type native oxide on liquid metal microdroplets for low temperature gas sensing10.1016/j.matdes.2017.03.017 ↗
16. Ordered-vacancy-enabled indium sulphide printed in wafer-scale with enhanced electron mobility10.1039/C9MH01365B ↗
17. Printable single-unit-cell-thick transparent zinc-doped indium oxides with efficient electron transport properties10.1021/acsnano.0c06791 ↗
18. Gallium-rich Pd–Ga phases as supported liquid metal catalysts10.1038/nchem.2822 ↗
19. State-of-the-art of solar thermal power plants—a review10.1016/j.rser.2013.06.037 ↗
20. 3D visible-light-driven plasmonic oxide frameworks deviated from liquid metal nanodroplets10.1002/adfm.202106397 ↗
21. Light-driven liquid metal nanotransformers for biomedical theranostics10.1038/ncomms15432 ↗
22. Transformable liquid-metal nanomedicine10.1038/ncomms10066 ↗
23. Thermal energy storage systems for concentrated solar power plants10.1016/j.rser.2017.03.139 ↗
24. Solar energy for future world:-A review10.1016/j.rser.2016.05.022 ↗
25. An active cooling system for photovoltaic modules10.1016/j.apenergy.2011.01.017 ↗
26. Liquid metal technology in solar power generation-Basics and applications10.1016/j.solmat.2020.110925 ↗
27. Liquid metal–based soft microfluidics10.1002/smll.201903841 ↗
28. Growth and in situ characterization of 2D materials by chemical vapour deposition on liquid metal catalysts: a review10.1039/D0NR07330J ↗
29. Liquid metal droplets enabled soft robots
30. Perspective on gallium-based room temperature liquid metal batteries
31. Liquid metal batteries for future energy storage10.1039/D1EE00531F ↗
32. Recent advances in the modeling of fundamental processes in liquid metal batteries10.1016/j.rser.2022.112167 ↗
33. Liquid metal architectures for soft and wearable energy harvesting devices10.1088/2399-7532/abd4f0 ↗
34. Liquid metal-based devices: material properties, fabrication and functionalities10.3390/nano11123400 ↗
35. Liquid metals as soft electromechanical actuators10.1039/D1MA00885D ↗
36. Current status of liquid metal printing
37. Liquid metal direct write and 3D printing: a review10.1002/admt.202000070 ↗
38. Advances in liquid metal-enabled flexible and wearable sensors10.3390/mi11020200 ↗
39. Liquid metal based flexible and implantable biosensors10.3390/bios10110170 ↗
40. Liquid metal–enabled cybernetic electronics
41. Liquid metal enabled injectable biomedical technologies and applications
42. Liquid metal biomaterials for biomedical imaging
43. Liquid metal based theranostic nanoplatforms: Application in cancer therapy, imaging and biosensing10.1016/j.nano.2020.102175 ↗
44. Biomedical applications of liquid metal nanoparticles: a critical review10.3390/bios10120196 ↗
45. Nano-biomedicine based on liquid metal particles and allied materials10.1002/anbr.202170041 ↗
46. Gallium-based liquid metal particles for therapeutics10.1016/j.tibtech.2020.10.005 ↗
47. Responsive liquid metal droplets: from bulk to nano10.3390/nano12081289 ↗
48. Liquid metal polymer composites: from printed stretchable circuits to soft actuators10.1088/2058-8585/ac515a ↗
49. Multifunctional liquid metal polymer composites10.1002/pol.20210867 ↗
50. Recent development in liquid metal materials10.1002/open.202000330 ↗
51. Liquid metal based nano-composites for printable stretchable electronics10.3390/s22072516 ↗
52. Surface modification of liquid metal as an effective approach for deformable electronics and energy devices10.1039/D0SC05310D ↗
53. Synthesis and application of core–shell liquid metal particles: a perspective of surface engineering10.1039/D0MH01117G ↗
54. Ga based particles, alloys and composites: fabrication and applications10.3390/nano11092246 ↗
55. Ga-Based liquid metal micro/nanoparticles: recent advances and applications10.1002/smll.201903391 ↗
56. Functional liquid metal nanoparticles: synthesis and applications10.1039/D1MA00789K ↗
57. Liquid metal phagocytosis: Intermetallic wetting induced particle internalization10.1002/advs.201700024 ↗
58. Metal-based magnetic fluids with core–shell structure FeB@ SiO 2 amorphous particles10.1039/C7SM01238A ↗
59. Formation of particles of bismuth-based binary alloys and intermetallic compounds by ultrasonic cavitation10.1039/C5NJ00781J ↗
60. Gallium-based liquid metal amalgams: transitional-state metallic mixtures (TransM2ixes) with enhanced and tunable electrical, thermal, and mechanical properties10.1021/acsami.7b10256 ↗
61. Liquid metal/metal oxide frameworks10.1002/adfm.201304064 ↗
62. Liquid metal/metal oxide frameworks with incorporated Ga2O3 for photocatalysis10.1021/am5077364 ↗
63. Directing substrate morphology via self-assembly: ligand-mediated scission of gallium–indium microspheres to the nanoscale10.1021/nl202728j ↗
64. Nanodroplets for stretchable superconducting circuits10.1002/adfm.201603427 ↗
65. Synthesis of liquid core–shell particles and solid patchy multicomponent particles by shearing liquids into complex particles (SLICE)10.1021/la5035118 ↗
66. Sonication-enabled rapid production of stable liquid metal nanoparticles grafted with poly (1-octadecene-alt-maleic anhydride) in aqueous solutions10.1039/C8NR05600E ↗
67. Zhang · Adv. Funct. Mater · 2014 · 24 · 379910.1002/adfm.201304064 ↗
68. Self-fueled biomimetic liquid metal mollusk10.1002/adma.201405438 ↗
69. A study of the production and reversible stability of EGaIn liquid metal microspheres using flow focusing10.1039/c2lc40492c ↗
70. Continuous transfer of liquid metal droplets across a fluid–fluid interface within an integrated microfluidic chip10.1039/C5LC00415B ↗
71. Formation of spherical and non-spherical eutectic gallium-indium liquid-metal microdroplets in microfluidic channels at room temperature10.1002/adfm.201200324 ↗
72. Liquid-metal microdroplets formed dynamically with electrical control of size and rate10.1002/adma.201503875 ↗
73. Fabrication of nanoscale Ga balls via a Coulomb explosion of microscale silica-covered Ga balls by TEM electron-beam irradiation10.1038/srep11313 ↗
74. Williams · 1996
75. Controllable preparation of an ice cream-shaped hollow sphere array10.1039/D2RA00236A ↗
76. Observation of five-fold local symmetry in liquid lead10.1038/35048537 ↗
77. Shape-transformable liquid metal nanoparticles in aqueous solution10.1039/C7SC00057J ↗
78. High ultraviolet absorption in colloidal gallium nanoparticles prepared from thermal evaporation10.3390/nano7070172 ↗
79. UV plasmonic properties of colloidal liquid-metal eutectic gallium-indium alloy nanoparticles10.1038/s41598-019-41789-8 ↗
80. Ultrasonic cavitation of molten gallium: formation of micro-and nano-spheres10.1016/j.ultsonch.2013.11.004 ↗
81. Reversible size control of liquid-metal nanoparticles under ultrasonication10.1002/anie.201506469 ↗
82. Synthesis of hollow metallic particles via ultrasonic treatment of a metal emulsion10.1016/j.scriptamat.2010.01.028 ↗
83. High-temperature abnormal behavior of resistivities for Bi–In melts10.1016/j.physleta.2004.06.089 ↗
84. Are there phase transitions in liquid metallic alloys?10.1080/14786431003745310 ↗
85. Electronic transport properties of liquid Ga–Zn alloys10.1016/j.intermet.2003.09.007 ↗
86. Electrical resistivity of liquid iron with different content of impurities
87. Some properties of liquid alloys
88. Electric resistivity of molten Fe-Ni and Fe-Co alloys10.2355/isijinternational1966.12.314 ↗
89. Electrical conductivity measurements in liquid metals by rotational technique10.1023/A:1004523407095 ↗
90. Electrical, thermal, and species transport properties of liquid eutectic Ga-In and Ga-In-Sn from first principles10.1063/1.4865105 ↗
91. The electrical resistance of liquid gallium in the neighbourhood of its melting point10.1088/0370-1301/63/9/303 ↗
92. The resistance of liquid metals10.1098/rspa.1934.0166 ↗
93. Lide · 2004
94. Directly writing resistor, inductor and capacitor to composite functional circuits: a super-simple way for alternative electronics10.1371/journal.pone.0069761 ↗
95. Research advancement of liquid metal printed electronics ink
96. Liquid metal enabled microfluidics10.1039/C7LC00046D ↗
97. Microfluidic electronics10.1039/c2lc21176a ↗
98. Bismuthene on a SiC substrate: a candidate for a high-temperature quantum spin Hall material10.1126/science.aai8142 ↗
99. Quantum spin Hall effect in silicene and two-dimensional germanium10.1103/PhysRevLett.107.076802 ↗
100. Large-gap quantum spin Hall insulators in Tin films10.1103/PhysRevLett.111.136804 ↗