journal article·2022-03Open access

Boosting CO2 reforming of methane via the metal-support interaction in mesostructured SBA-16-derived Ni nanoparticles

Chao Sun, Paulina Summa, Ye Wang, Katarzyna Świrk Da Costa, Albert Miró i Rovira, Sandra Casale, Konrad Świerczek, Changwei Hu, Magnus Rønning, Patrick Da Costa

Abstract

High surface area and porosity SBA-16 was synthesized and used as support for Ni nanoparticles using three methods including wet impregnation, citric acid-assisted impregnation, and ammonia evaporation. All the studied samples showed high activity in the CO2 reforming of methane reaction, however, the best catalytic behavior was found for the catalyst derived from ammonia evaporation. Based on characterization techniques, it was assumed that the improvement in Ni/SBA-16-AE performance was due to the strong metal-support interaction resulting from the formation of Ni-phyllosilicate. Additionally, a high Ni dispersion was observed which may be related to the confinement of cage-like pores of the SBA-16 matrix. The ammonia evaporation technique can well contribute to the limited sintering of Ni nanoparticles and reduced amount of deposited carbon.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Catalysts for Methane Reforming · Catalytic Processes in Materials Science · Catalysis and Oxidation Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (56)

Show source-provided references
1. An overview of global climate changing in current scenario and mitigation action10.1016/j.rser.2012.01.044 ↗
2. Reduction of CO2 to chemicals and fuels: a solution to global warming and energy crisis10.1021/acsenergylett.8b00878 ↗
3. Phyllosilicate nanoclay-based aqueous nanoparticle sorbent for CO2 capture at ambient conditions10.1016/j.apmt.2017.09.009 ↗
4. Carbon capture and storage update10.1039/C3EE42350F ↗
5. Sustainable conversion of carbon dioxide: an integrated review of catalysis and life cycle assessment10.1021/acs.chemrev.7b00435 ↗
6. Integrative CO2 Capture and hydrogenation to methanol with reusable catalyst and amine: toward a carbon neutral methanol economy10.1021/jacs.7b12183 ↗
7. Ni/CeO2 nanoparticles promoted by yttrium doping as catalysts for CO2 methanation10.1021/acsanm.0c02841 ↗
8. Low-temperature catalytic CO2 dry reforming of methane on Ni-Si/ZrO2 catalyst10.1021/acscatal.8b00584 ↗
9. Ceria-doped Ni/SBA-16 catalysts for dry reforming of methane10.1021/cs400159w ↗
10. CO and CO2 hydrogenation study on supported cobalt Fischer-Tropsch synthesis catalysts10.1016/S0920-5861(01)00468-0 ↗
11. Fischer-Tropsch synthesis of hydrocarbons over mesoporous Co/SBA-15 catalysts: the influence of metal loading, cobalt precursor, and promoters10.1016/S0021-9517(03)00289-6 ↗
12. Atomically dispersed nickel as coke-resistant active sites for methane dry reforming10.1038/s41467-019-12843-w ↗
13. Narrowing band gap energy of CeO2 in (Ni/CeO2)@SiO2 catalyst for photothermal methane dry reforming10.1016/j.cej.2021.129989 ↗
14. Optimizing the Ni/Cu ratio in Ni-Cu nanoparticle catalysts for methane dry reforming10.1021/acsanm.1c00673 ↗
15. Low temperature CO2 reforming with methane reaction over CeO2-modified Ni@SiO2Catalysts10.1021/acsami.0c09371 ↗
16. Effect of calcination temperature on the performance of the Ni@SiO2Catalyst in methane dry reforming10.1021/acs.iecr.0c01213 ↗
17. Reducing carbon deposition and enhancing reaction stability by ceria for methane dry reforming over Ni@SiO2@CeO2 catalyst10.1016/j.fuel.2021.120182 ↗
18. Ni/SiO2 catalyst prepared by strong electrostatic adsorption for a low-temperature methane dry reforming reaction10.1021/acs.iecr.0c06020 ↗
19. Confining Ni and ceria in silica shell as synergistic multifunctional catalyst for methane dry reforming reaction10.1016/j.jpowsour.2021.230232 ↗
20. Effect of metal particle size on coking during CO2 reforming of CH4 over Ni-alumina aerogel catalysts10.1016/S0926-860X(99)00487-1 ↗
21. Steam reforming and graphite formation on Ni catalysts10.1006/jcat.2002.3579 ↗
22. Synthesis, characterization and catalytic performance of Ce-SBA-15 supported nickel catalysts for methane dry reforming to hdrogen and syngas10.1016/j.ijhydene.2011.03.138 ↗
23. Synthesis strategies of ceria-zirconia doped Ni/SBA-15 catalysts for methane dry reforming10.1016/j.catcom.2014.09.050 ↗
24. Comparative study of modified Ni catalysts over mesoporous CaO-Al2O3 support for CO2/methane reforming10.1016/j.catcom.2020.106100 ↗
25. Interfacial synergistic catalysis over Ni nanoparticles encapsulated in mesoporous ceria for CO2 methanation10.1016/j.apcatb.2021.120454 ↗
26. High-temperature stable Ni nanoparticles for the dry reforming of methane10.1021/acscatal.6b01683 ↗
27. Syngas production via CO 2 reforming of CH 4 over Ni-based SBA-15: promotional effect of promoters (Ce, Mg, and Zr)10.1016/j.mtener.2019.04.001 ↗
28. Synthesis of Ni-based catalysts supported on nitrogen-incorporated SBA-16 and their catalytic performance in the reforming of methane with carbon dioxide10.1016/S1872-5813(17)30012-9 ↗
29. Nickel-based nanocatalysts promoted over MgO-modified SBA-16 for dry reforming of methane for syngas production: impact of support and promoters10.1016/j.joei.2021.04.005 ↗
30. Organic acid-assisted preparation of highly dispersed Co/ZrO2 catalysts with superior activity for CO2 methanation10.1016/j.apcatb.2019.05.028 ↗
31. Enhanced performance and selectivity of CO2 methanation over phyllosilicate structure derived Ni-Mg/SBA-15 catalysts10.1016/j.apcatb.2020.119564 ↗
32. Effect of ceria promotion on the catalytic performance of Ni/SBA-16 catalysts for CO2 methanation10.1039/D0CY00922A ↗
33. Tailoring the yttrium content in Ni-Ce-Y/SBA-15 mesoporous silicas for CO2 methanation10.1016/j.cattod.2021.07.031 ↗
34. On the effect of yttrium promotion on Ni-layered double hydroxides-derived catalysts for hydrogenation of CO2 to methane
35. Mesostructured silica SBA-16 with tailored intrawall porosity part 1: synthesis and characterization10.1021/jp0635765 ↗
36. Microwave-hydrothermal synthesis and characterization of zirconium substituted SBA-15 mesoporous silica10.1021/jp010889l ↗
37. Nanosized transition metals in controlled environments of phyllosilicate–mesoporous silica composites as highly thermostable and active catalysts10.1039/c3cc43197e ↗
38. Nickel Particles Selectively Confined in the Mesoporous Channels of SBA-15 Yielding a Very Stable Catalyst for DRM Reaction10.1021/acs.jpcb.7b03835 ↗
39. Ni/YMnO3 perovskite catalyst for CO2 methanation
40. The effect of Ni precursor salts on diatomite supported Ni-Mg catalysts in methanation of CO210.4028/www.scientific.net/MSF.1016.1417 ↗
41. Simultaneous tuning porosity and basicity of nickel@nickel-magnesium phyllosilicate core-shell catalysts for CO2 reforming of CH410.1021/la503340s ↗
42. Combined XRD and XANES studies of a Re-promoted Co/γ-Al 2O3 catalyst at Fischer-Tropsch synthesis conditions10.1016/j.cattod.2009.10.010 ↗
43. Preparation of hcp and fcc Ni and Ni/NiO nanoparticles using a citric acid assisted Pechini-type method10.1155/2011/162495 ↗
44. Persson · 2014
45. Particle size and dispersion measurements
46. Comparative study of Ni-Ce loading method: beneficial effect of ultrasonic-assisted impregnation method in CO2 reforming of CH4 over Ni-Ce/SBA-1510.1016/j.jece.2018.01.001 ↗
47. Metal-support interaction: titania-supported and silica-supported nickel catalysts10.1006/jcat.1997.1741 ↗
48. CO2 methanation over Ca doped ordered mesoporous Ni-Al composite oxide catalysts: the promoting effect of basic modifier10.1016/j.jcou.2017.07.014 ↗
49. Bi-functional hydrotalcite-derived NiO-CaO-Al2O3 catalysts for steam reforming of biomass and/or tar model compound at low steam-to-carbon conditions10.1016/j.apcatb.2015.02.017 ↗
50. CO2 methanation over nickel-ZrO2 catalyst supported on carbon nanotubes: a comparison between two impregnation strategies10.1016/j.apcatb.2018.06.045 ↗
51. One-step synthesis of highly active and stable Ni-ZrOx for dry reforming of methane10.1021/acs.iecr.0c01416 ↗
52. Yttrium promoted Ni-based double-layered hydroxides for dry methane reforming
53. Ce- and Y-modified double-layered hydroxides as catalysts for dry reforming of methane : on the effect of yttrium promotion10.3390/catal9010056 ↗
54. Dry reforming of methane over catalysts derived from nickel-containing Mg-Al layered double hydroxides10.1016/S0021-9517(02)00047-7 ↗
55. Synthesis strategies of Zr- and Y-promoted mixed oxides derived from double-layered hydroxides for syngas production via dry reforming of methane
56. Understanding of tri-reforming of methane over Ni /Mg / Al hydrotalcite-derived catalyst for CO2 utilization from flue gases from natural gas-fired power plants10.1016/j.jcou.2020.101317 ↗