A scalable crosslinked fiberglass-aerogel thermal insulation composite

Abstract Ceramic aerogels are attractive for thermal insulation due to its lightweight and low thermal conductivity, while it is indispensable to address the obstacle of its brittleness nature and large-scale manufacturing for building efficiency applications. The economical manufacturing of large-scale elastic thermal insulation aerogels has remained challenging. Herein, we report a universal manufacturing of the fiberglass reinforced aerogel composites where the architectured three-dimensional fiber networks with the cross-linked silica aerogel exhibit superinsulation and mechanical elasticity. These remarkable performances are obtained through in-situ cross-linking reaction between molecular assembly induced aerogel and fiberglass under ambient pressure drying environment, in which the interfacial interactions are verified from its infrared spectra. The resulting ultralight aerogel composite sheet exhibits a density of 0.1 g cm−3, large strain recovery (>50%), and low thermal conductivity (0.0253 W m−1 K−1). The thermal insulation aerogel composites shed light on the super-elastic aerogel manufacturing with scalability for energy saving building applications.