journal article·2021-12

Colorless polyimides with excellent optical transparency and self-healing properties based on multi-exchange dynamic network

Young Nam Kim, Juheon Lee, Young-O Kim, Jaewoo Kim, Haksoo Han, Yong Chae Jung

Publisher page

Abstract

Abstract Colorless polyimides (CPIs) with outstanding mechanical properties are used as essential materials in the production of future flexible display panels, foldable windows, and spacecraft cockpit materials. However, under repetitive stress and deformation, fatigue fractures caused by cracks and radio waves may act as critical determinants of the properties and duration of the material. To solve this problem, the present study developed a CPI capable of self-healing, wherein the transparency and any damage caused by external stress are rapidly and easily restored. Our synthesized CPI films showed ultra-transmittance (> 95%) and excellent self-healing efficiency (> 98%) with a simultaneously induced multi exchange network. Notably, the films exhibited excellent mechanical properties even after a bending fatigue test involving more than 10,000 cycles. This study therefore suggests a new type of CPI with a self-healing function and shows that the trade-off between the durability and functionality can be completely resolved.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Synthesis and properties of polymers · Polymer composites and self-healing · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. A new negative-type photosensitive polyimide based on poly (hydroxyimide), a cross-linker, and a photoacid generator10.1021/ma9605560 ↗
2. Highly robust bendable oxide thin-film transistors on polyimide substrates via mesh and strip patterning of device layers10.1002/adfm.201700437 ↗
3. Advanced polyimide materials: syntheses, physical properties and applications10.1016/j.progpolymsci.2012.02.005 ↗
4. Flexible full color organic light-emitting diode display on polyimide plastic substrate driven by amorphous indium gallium zinc oxide thin-film transistors
5. High-performance, highly bendable MoS2 transistors with high-k dielectrics for flexible low-power systems10.1021/nn401429w ↗
6. Photophysics, photochemistry, and optical properties of polyimides10.1016/S0079-6700(00)00042-3 ↗
7. Towards solution-processable, thermally robust, transparent polyimide-chain-end tethered organosilicate nanohybrids10.1016/j.compositesb.2018.11.029 ↗
8. Synthesis, characterization, and properties of fully aliphatic polyimides and their derivatives for microelectronics and optoelectronics applications10.1007/BF03218762 ↗
9. Synthesis and characterization of organosoluble aliphatic–aromatic copolyimides based on cycloaliphatic dianhydride10.1016/S0014-3057(01)00206-3 ↗
10. Synthesis and characterization of transparent polyimides derived from ester-containing dianhydrides with different electron affinities10.1039/C5RA16574A ↗
11. Colorless poly (ether-imide) s deriving from 2, 2-bis [4-(3, 4-dicarboxyphenoxy) phenyl] propane dianhydride (BPADA) and aromatic bis (ether amine) s bearing pendent trifluoromethyl groups10.1016/j.eurpolymj.2005.10.001 ↗
12. Space environmentally stable polyimides and copolyimides derived from [2, 4-bis (3-aminophenoxy) phenyl] diphenylphosphine oxide10.1021/ma0201779 ↗
13. An ultra-lightweight design for imperceptible plastic electronics10.1038/nature12314 ↗
14. Efficient light-emitting diodes based on nanocrystalline perovskite in a dielectric polymer matrix10.1021/acs.nanolett.5b00235 ↗
15. Nanocasting technique to prepare lotus-leaf-like superhydrophobic electroactive polyimide as advanced anticorrosive coatings10.1021/am3029377 ↗
16. Advanced anticorrosive coatings prepared from electroactive polyimide–TiO2 hybrid nanocomposite materials10.1016/j.electacta.2010.07.063 ↗
17. In situ poly (urea-formaldehyde) microencapsulation of dicyclopentadiene10.3109/02652040309178083 ↗
18. Self-healing polymers based on thermally reversible diels–alder chemistry10.1039/c2py20957h ↗
19. Robust and stretchable self-healing polyurethane based on polycarbonate diol with different soft-segment molecular weight for flexible devices10.1016/j.eurpolymj.2019.05.031 ↗
20. Colorless, transparent, robust, and fast scratch-self-healing elastomers via a phase-locked dynamic bonds design10.1002/adma.201802556 ↗
21. Understanding and controlling the self-healing behavior of 2-ureido-4 [1H]-pyrimidinone-functionalized clustery and dendritic dual dynamic supramolecular network10.1016/j.polymer.2019.03.027 ↗
22. A transparent, self-healing, highly stretchable ionic conductor10.1002/adma.201605099 ↗
23. Dynamic covalent polymer networks: from old chemistry to modern day innovations10.1002/adma.201606100 ↗
24. Healable polymeric materials: a tutorial review10.1039/b904502n ↗
25. Superior toughness and fast self-healing at room temperature engineered by transparent elastomers
26. A highly efficient self-healing elastomer with unprecedented mechanical properties
27. Effect of the dianhydride/branched diamine ratio on the architecture and room temperature healing behavior of polyetherimides10.1021/acsami.6b10433 ↗
28. Understanding the effect of the dianhydride structure on the properties of semiaromatic polyimides containing a biobased fatty diamine10.1021/acssuschemeng.7b03026 ↗
29. Semiaromatic polyimides based on bis (aminomethyl) bicyclo [2. 2. 1] heptane10.1088/0954-0083/11/4/302 ↗
30. Nonaromatic polyimides derived from cycloaliphatic monomers10.1021/ma9903862 ↗
31. Development of solution-processable, optically transparent polyimides with ultra-low linear coefficients of thermal expansion10.3390/polym9100520 ↗
32. Transient mechanochromism in epoxy vitrimer composites containing aromatic disulfide crosslinks10.1039/C6TC02383E ↗
33. Thermally healable and reprocessable bis (hindered amino) disulfide-cross-linked polymethacrylate networks10.1021/acsmacrolett.7b00762 ↗
34. Catalyst-free room-temperature self-healing elastomers based on aromatic disulfide metathesis10.1039/C3MH00061C ↗
35. Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water10.1039/C1SC00117E ↗
36. Amorphous MoS3 as the sulfur-equivalent cathode material for room-temperature Li–S and Na–S batteries10.1073/pnas.1711917114 ↗
37. Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo 3 S 13] 2− clusters10.1038/nchem.1853 ↗
38. Interchain helically π-stacked assembly of cationic chiral poly (para-phenylene) derivatives enforced by anionic π-conjugated molecules through both electrostatic and π–π interactions10.1021/acs.chemmater.5b00121 ↗
39. Aliphatic–aromatic polyimide blends for H2 separation10.1016/j.ijhydene.2010.06.038 ↗
40. Restoration of large damage volumes in polymers10.1126/science.1251135 ↗