journal article·2024-02Open access

An overview of advanced oxidation processes using copper-based catalytic degradation of organic pollutants in water

Enyioma C. Okpara, Olanrewaju B. Wojuola, Taiwo W. Quadri, Craig E. Banks

Abstract

Organic pollutants are harmful to the environment due to their bio-accumulative and long-persistent nature, causing adverse effects on plants, animals, and humans. Their rapid spread beyond target applications in the ecosystem could be responsible for various fatal diseases and eco imbalances. Conventional techniques for removing these pollutants are ineffective because of their high solubility in water and nonbiodegradability. In contemporary times, we have witnessed a notable surge in interest in advanced oxidation processes (AOPs) for water treatment processes. This heightened attention is attributed to their exceptional degradation efficiency for recalcitrant organic pollutants. This review, therefore, focuses on copper-based homogeneous and heterogeneous catalysts for AOPs that offer both cost-effectiveness and high performance. Emphasis is placed on the use of copper-based catalysts in photocatalysis, Fenton-like process (including photo-Fenton (Fe2+/UV/H2O2)), persulfates activation, and ultrasonic irradiation. The catalytic performance, mechanism, and pathway for the abatement of the target pollutants by the copper-based catalysts in each AOP are described in detail. The reusability, stability, and factors affecting the AOPs are briefly highlighted. We further provide perspectives on the key opportunities and challenges associated with copper-based catalysts in AOPs, recommending further exploration for enhanced applications in future studies.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced oxidation water treatment · Advanced Photocatalysis Techniques · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. In-situ growing of metal-organic frameworks on three-dimensional iron network as an efficient adsorbent for antibiotics removal10.1016/j.cej.2020.124844 ↗
2. In situ grown single-atom cobalt on polymeric carbon nitride with bidentate ligand for efficient photocatalytic degradation of refractory antibiotics10.1002/smll.202001634 ↗
3. Construction of iodine vacancy-rich BiOI/Ag@ AgI Z-scheme heterojunction photocatalysts for visible-light-driven tetracycline degradation: transformation pathways and mechanism insight10.1016/j.cej.2018.05.093 ↗
4. Peroxymonosulfate and peroxydisulfate activation by fish scales biochar for antibiotics removal: synergism of N, P-codoped biochar10.1016/j.chemosphere.2023.138326 ↗
5. In-situ synthesis of facet-dependent BiVO4/Ag3PO4/PANI photocatalyst with enhanced visible-light-induced photocatalytic degradation performance: synergism of interfacial coupling and hole-transfer10.1016/j.cej.2019.122840 ↗
6. Treatment of organic pollution in industrial saline wastewater: a literature review10.1016/j.watres.2006.08.027 ↗
7. Pharmaceuticals and personal care products (PPCPs): a review on environmental contamination in China10.1016/j.envint.2013.06.012 ↗
8. Recent progress in sustainable technologies for adsorptive and reactive removal of sulfonamides10.1016/j.cej.2019.123423 ↗
9. Dual redox cycles of Mn(Ⅱ)/Mn(III) and Mn(III)/Mn(IV) on porous Mn/N co-doped biochar surfaces for promoting peroxymonosulfate activation and ciprofloxacin degradation10.1016/j.jcis.2022.12.008 ↗
10. Disinfection byproducts formation from emerging organic micropollutants during chlorine-based disinfection processes10.1016/j.cej.2022.140476 ↗
11. Antibacterial drug discovery in the resistance era10.1038/nature17042 ↗
12. Are there other persistent organic pollutants? A challenge for environmental chemists10.1021/es061677a ↗
13. Modeling the transport of sodium dodecyl benzene sulfonate in riverine sediment in the presence of multi-walled carbon nanotubes10.1016/j.watres.2017.11.003 ↗
14. The effects of biochar on antibiotic resistance genes (ARGs) removal during different environmental governance processes: a review10.1016/j.jhazmat.2022.129067 ↗
15. Activation of peroxydisulfate by bimetal modified peanut hull-derived porous biochar for the degradation of tetracycline in aqueous solution10.1016/j.jece.2022.107366 ↗
16. Tube wall delamination engineering induces photogenerated carrier separation to achieve photocatalytic performance improvement of tubular g-C3N410.1016/j.jhazmat.2021.127177 ↗
17. Recent advances of Zr based metal organic frameworks photocatalysis: energy production and environmental remediation10.1016/j.ccr.2021.214177 ↗
18. Persulfate activation by swine bone char-derived hierarchical porous carbon: multiple mechanism system for organic pollutant degradation in aqueous media10.1016/j.cej.2019.123091 ↗
19. Metal-organic frameworks derived magnetic carbon-αFe/Fe3C composites as a highly effective adsorbent for tetracycline removal from aqueous solution10.1016/j.cej.2019.05.164 ↗
20. Efficacy of carbonaceous nanocomposites for sorbing ionizable antibiotic sulfamethazine from aqueous solution10.1016/j.watres.2016.03.014 ↗
21. Hydrogen peroxide-impregnated supramolecular precursors synthesize mesoporous-rich ant nest-like filled tubular g-C3N4 for effective photocatalytic removal of pollutants10.1016/j.cej.2022.137332 ↗
22. Construction of a novel S-scheme heterojunction piezoelectric photocatalyst V-BiOIO3/FTCN and immobilization with floatability for tetracycline degradation10.1016/j.jhazmat.2022.130251 ↗
23. Application of carbon aerogel-based materials in persulfate activation for water treatment: a review10.1016/j.jclepro.2022.135518 ↗
24. Integrating N and F co-doped TiO2 nanotubes with ZIF-8 as photoelectrode for enhanced photo-electrocatalytic degradation of sulfamethazine10.1016/j.cej.2020.124388 ↗
25. Removal of residual pharmaceuticals from aqueous systems by advanced oxidation processes10.1016/j.envint.2008.07.009 ↗
26. Electrochemically enhanced simultaneous degradation of sulfamethoxazole, ciprofloxacin and amoxicillin from aqueous solution by multi-walled carbon nanotube filter10.1016/j.seppur.2019.116167 ↗
27. Design and engineering of layered double hydroxide based catalysts for water depollution by advanced oxidation processes: a review10.1039/C9TA13522G ↗
28. Covalent–organic framework (COF)-core–shell composites: classification, synthesis, properties, and applications10.1002/adfm.202304990 ↗
29. Advanced oxidation processes in water/wastewater treatment: principles and applications. A review10.1080/10643389.2013.829765 ↗
30. Facile assembled biochar-based nanocomposite with improved graphitization for efficient photocatalytic activity driven by visible light10.1016/j.apcatb.2019.03.004 ↗
31. Synergistic effect of artificial enzyme and 2D nano-structured Bi2WO6 for eco-friendly and efficient biomimetic photocatalysis10.1016/j.apcatb.2019.03.008 ↗
32. Recent advances in application of graphitic carbon nitride-based catalysts for degrading organic contaminants in water through advanced oxidation processes beyond photocatalysis: a critical review10.1016/j.watres.2020.116200 ↗
33. A “bottle-around-ship” like method synthesized yolk-shell Ag3PO4@ MIL-53 (Fe) Z-scheme photocatalysts for enhanced tetracycline removal10.1016/j.jcis.2019.11.025 ↗
34. Advanced oxidation processes for wastewater treatment: formation of hydroxyl radical and application10.1080/10643389.2010.507698 ↗
35. BiOX (X = Cl, Br, I) photocatalytic nanomaterials: applications for fuels and environmental management10.1016/j.cis.2018.03.004 ↗
36. A detailed review on advanced oxidation process in treatment of wastewater: mechanism, challenges and future outlook10.1016/j.chemosphere.2022.136524 ↗
37. Gama-graphyne as photogenerated electrons transfer layer enhances photocatalytic performance of silver phosphate10.1016/j.apcatb.2019.118479 ↗
38. Heterogeneous Fenton-like catalyst for treatment of rhamnolipid-solubilized hexadecane wastewater10.1016/j.chemosphere.2019.124387 ↗
39. High-performance porous carbon catalysts doped by iron and nitrogen for degradation of bisphenol F via peroxymonosulfate activation10.1016/j.cej.2019.123683 ↗
40. Emergent methods to synthesize and characterize semiconductor CuO nanoparticles with various morphologies—an overview10.1080/17458080601094421 ↗
41. One-dimensional metal oxide nanotubes, nanowires, nanoribbons, and nanorods: synthesis, characterizations, properties and applications10.1080/10408436.2011.606512 ↗
42. Narayanan · 2005 · 12663
43. Facile synthesis of diverse transition metal oxide nanoparticles and electrochemical properties10.1039/C6QI00096G ↗
44. The absolute energy positions of conduction and valence bands of selected semiconducting minerals10.2138/am-2000-0416 ↗
45. Tuning interfacial Cu-O atomic structures for enhanced catalytic applications
46. Hydrothermal synthesis of hierarchical copper oxide nanoparticles and its potential application as adsorbent for Pb (II) with high removal capacity10.1080/01496395.2014.922101 ↗
47. Structural, optical and electronic properties of CuO and Zn doped CuO: DFT based First-principles calculations10.1016/j.chemphys.2019.110536 ↗
48. Engineering nanostructures of CuO-based photocatalysts for water treatment: current progress and future challenges10.1016/j.arabjc.2020.06.031 ↗
49. Recent advances in metal sulfides: from controlled fabrication to electrocatalytic, photocatalytic and photoelectrochemical water splitting and beyond10.1039/C8CS00664D ↗
50. Ultrathin single crystal ZnS nanowires10.1039/C0CC02549F ↗
51. Spinels: controlled preparation, oxygen reduction/evolution reaction application, and beyond10.1021/acs.chemrev.7b00051 ↗
52. Applications of transition metal oxides and chalcogenides and their composites in water treatment: a review10.1016/j.envadv.2023.100341 ↗
53. Recent advances in waste water treatment through transition metal sulfides-based advanced oxidation processes10.1016/j.watres.2021.116850 ↗
54. Promising visible-light driven hydrogen production from water on a highly efficient CuCo2S4 nanosheet photocatalyst10.1039/C9TA00391F ↗
55. Preparing copper doped carbon nitride from melamine templated crystalline copper chloride for Fenton-like catalysis10.1016/j.apcatb.2019.117830 ↗
56. Artificial photosynthesis with polymeric carbon nitride: when meeting metal nanoparticles, single atoms, and molecular complexes10.1002/smll.201900772 ↗
57. Identification of Fenton-like active Cu sites by heteroatom modulation of electronic density10.1073/pnas.2119492119 ↗
58. In-situ Cu-loaded sludge biochar catalysts for oxidative degradation of bisphenol A from high-salinity wastewater10.1016/j.jclepro.2023.139334 ↗
59. Strategies for enhancing the heterogeneous Fenton catalytic reactivity: a review10.1016/j.apcatb.2019.05.041 ↗
60. CuO nanosheet as a recyclable Fenton-like catalyst prepared from simulated Cu(II) waste effluents by alkaline H2O2 reaction
61. A high-efficiency CuO/CeO2 catalyst for diclofenac degradation in Fenton-like system10.3389/fchem.2019.00796 ↗
62. Heterogeneous photo-Fenton-like degradation of emerging pharmaceutical contaminants in wastewater using Cu-doped MgO nanoparticles10.1016/j.apcata.2021.118468 ↗
63. Design and synthesis of an exceptionally stable and highly porous metal-organic framework10.1038/46248 ↗
64. Symmetry-guided synthesis of highly porous metal–organic frameworks with fluorite topology10.1002/ange.201307340 ↗
65. Luminescent functional metal–organic frameworks10.1021/cr200101d ↗
66. A resistance-switchable and ferroelectric metal–organic framework10.1021/ja508592f ↗
67. Cu-MOF for effectively organic pollutants degradation and E. coli inactivation via catalytic activation of peroxymonosulfate10.1016/j.jtice.2021.11.021 ↗
68. Ultrasound-enhanced zero-valent copper activation of persulfate for the degradation of bisphenol AF10.1016/j.cej.2019.122143 ↗
69. Ultrasound-enhanced nanosized zero-valent copper activation of hydrogen peroxide for the degradation of norfloxacin10.1016/j.ultsonch.2017.08.025 ↗
70. Rapid oxidation of acetaminophen with zero-valent copper induced hydrogen peroxide process in presence of ferric ion and chloride ion10.1016/j.cej.2023.144202 ↗
71. Multiple reinforcement of chloride ion on oxidizing acetaminophen with zero-valent copper particles: in-site formation and catalysis of hydrogen peroxide
72. Sonocatalytic degradation of p-chlorophenol by nanoscale zero-valent copper activated persulfate under ultrasonic irradiation in aqueous solutions
73. Efficient degradation of nitrobenzene by Cu-Co-Fe-LDH catalyzed peroxymonosulfate to produce hydroxyl radicals10.1016/j.cej.2018.09.111 ↗
74. Persulfate coupled with Cu2+/LDH-MoS4: a novel process for the efficient atrazine abatement, mechanism and degradation pathway10.1016/j.cej.2022.134933 ↗
75. A review on advanced treatment of pharmaceutical wastewater
76. Photocatalytic decouloration of malachite green dye by application of TiO2 nanotubes10.1016/j.jhazmat.2009.03.076 ↗
77. UV light induced photodegradation of malachite green on TiO2 nanoparticles10.1016/j.jhazmat.2006.07.011 ↗
78. Photocatalytic performance of ZnO nanomaterials for self sensitized degradation of malachite green dye under solar light10.1016/j.apcata.2014.10.053 ↗
79. Ameta · 2018
80. Facile synthesis of S-doped reduced TiO2-x with enhanced visible-light photocatalytic performance10.1016/S1872-2067(17)62825-0 ↗
81. Antireflection and passivation property of titanium oxide thin film on silicon nanowire by liquid phase deposition10.1016/j.surfcoat.2017.01.027 ↗
82. Assembled composite of hematite iron oxide on sponge-like BiOCl with enhanced photocatalytic activity
83. Mechanistic insights into photodegradation of organic dyes using heterostructure photocatalysts10.3390/catal9050430 ↗
84. TiO2 nanoparticles assembled on kaolinites with different morphologies for efficient photocatalytic performance10.1038/s41598-018-29563-8 ↗
85. The effects of metal doped TiO2 and dithizone-metal complexes on DSSCs performance10.1016/j.solener.2018.03.064 ↗
86. Toward designing semiconductor-semiconductor heterojunctions for photocatalytic applications10.1016/j.apsusc.2017.07.192 ↗
87. A critical review on efficient photocatalytic degradation of organic compounds using copper-based nanoparticles
88. Highly dispersible and uniform size Cu2ZnSnS4 nanoparticles for photocatalytic application10.1016/j.apt.2017.06.023 ↗
89. Solar-light induced photodegradation of organic pollutants over CdS-pillared zirconium–titanium phosphate (ZTP)10.1016/j.molcata.2011.08.012 ↗
90. Microwave fabrication of Cu2ZnSnS4 nanoparticle and its visible light photocatalytic properties10.1186/1556-276X-9-477 ↗
91. Photocatalytic degradation of methylene blue by hydrothermally synthesized CZTS nanoparticles
92. Structural, optical and photocatalytic properties of spray deposited Cu2ZnSnS4 thin films with various S/(Cu+Zn+Sn) ratio10.1016/j.mssp.2018.07.001 ↗
93. Synthesis of hierarchical Cu2CdSnS4 by microwave-assisted transformation from precursor for photodegradation to malachite green10.1016/j.jallcom.2022.163966 ↗
94. The role of magnetite/graphene oxide nano-composite as a high-efficiency adsorbent for removal of phenazopyridine residues from water samples, an experimental/theoretical investigation10.1016/j.molliq.2019.112040 ↗
95. Recent advances in nanomaterial development for lithium ion-sieving technologies10.1016/j.desal.2022.115624 ↗
96. Proteasome inhibitory, antioxidant, and synergistic antibacterial and anticandidal activity of green biosynthesized magnetic Fe3O4 nanoparticles using the aqueous extract of corn (Zea mays L.) ear leaves10.3109/21691401.2016.1153484 ↗
97. Facile green synthesis of Fe3O4 nanoparticles using aqueous leaf extract of Zanthoxylum armatum DC. for efficient adsorption of methylene blue10.1080/21870764.2018.1459335 ↗
98. Bio inspired green synthesis of Ni/Fe3O4 magnetic nanoparticles using Moringa oleifera leaves extract: a magnetically recoverable catalyst for organic dye degradation in aqueous solution10.1016/j.jallcom.2016.12.363 ↗
99. Hydrogen production by electrochemical reaction using waste zeolite boosted with titania and Au nanoparticles
100. Green synthesis of formamides using the Natrolite zeolite as a natural, efficient and recyclable catalyst10.1016/j.molcata.2013.04.001 ↗