MXenes—A new class of 2D layered materials: Synthesis, properties, applications as supercapacitor electrode and beyond
Source abstract
Abstract
Abstract Since the discovery of Ti3C2 MXene in 2011, continuous research has been progressed in developing new MAX phases and extracting MXenes from them. The surface terminations such as -O, -OH, -F groups present on the MXene influence their properties to a wide extent. By controlling the inter-layer spacing between the MXene sheets and the number of MXene layers, their properties can be tuned greatly. Their 2D structure with unique compositions has helped them obtain properties that are useful in various fields of applications such as batteries, supercapacitors, photo and electrocatalysts, bio-sensors, gas-sensors, water purification, water splitting, lubricants, electronics, electromagnetic interference shielding and so on. This review focuses on the synthesis, properties and applications of MXenes outlining the current challenges and scope for future research.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: MXene and MAX Phase Materials · Graphene and Nanomaterials Applications · Advanced Memory and Neural Computing
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. A brief review on electrode materials for supercapacitor10.20964/2016.12.50 ↗
2. A review of electrode materials for electrochemical supercapacitors10.1039/C1CS15060J ↗
3. Chapter 5 - interface applications in nanomaterials10.1016/B978-0-12-375049-5.00005-0 ↗
4. Graphene-based materials for supercapacitor electrodes – a review
5. Chapter 10 - graphene-based nanolayers toward energy storage device
6. Conducting-polymer-based supercapacitor devices and electrodes10.1016/j.jpowsour.2010.06.084 ↗
7. Electric field effect in atomically thin carbon films10.1126/science.1102896 ↗
8. Synthesis of graphene and its applications: a review10.1080/10408430903505036 ↗
9. Honeycomb carbon: a review of graphene10.1021/cr900070d ↗
10. Two-dimensional atomic crystals10.1073/pnas.0502848102 ↗
11. Two-dimensional transition metal dichalcogenide (TMD) nanosheets10.1039/C5CS90037A ↗
12. Enantioselective catalysis with homochiral metal–organic frameworks10.1039/b807083k ↗
13. Covalently-controlled properties by design in group IV graphane analogues10.1021/ar500296e ↗
14. Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility10.1021/nn501226z ↗
15. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC210.1002/adma.201102306 ↗
16. Stability trends of MAX phases from first principles10.1103/PhysRevB.81.220102 ↗
17. The MN+1AXN phases: a new class of solids: thermodynamically stable nanolaminates10.1016/S0079-6786(00)00006-6 ↗
18. 25th anniversary article: MXenes: a new family of two-dimensional materials10.1002/adma.201304138 ↗
19. Elastic and mechanical properties of the MAX phases10.1146/annurev-matsci-062910-100448 ↗
20. Chemical bonding and electronic-structure in MAX phases as viewed by X-ray spectroscopy and density functional theory10.1016/j.tsf.2016.11.005 ↗
21. An extraordinarily stable catalyst: Pt NPs supported on two-dimensional Ti3C2X2 (X = OH, F) nanosheets for oxygen reduction reaction10.1039/c3cc44428g ↗
22. Ti3C2MXenes with Modified Surface for High-Performance Electromagnetic Absorption and Shielding in the X-Band10.1021/acsami.6b06455 ↗
23. Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway10.1126/science.aaa3145 ↗
24. Interacting carbon nitride and titanium carbide nanosheets for high-performance oxygen evolution10.1002/anie.201509758 ↗
25. High and anisotropic carrier mobility in experimentally possible Ti2CO2 (MXene) monolayers and nanoribbons10.1039/C5NR04717J ↗
26. Remarkably improved hydrogen storage properties of NaAlH4 doped with 2D titanium carbide10.1016/j.jpowsour.2016.07.095 ↗
27. Synthesis of nanoflower-shaped MXene derivative with unexpected catalytic activity for dehydrogenation of sodium alanates10.1021/acsami.6b13973 ↗
28. Ti3C2 MXene co-catalyst on metal sulfide photo-absorbers for enhanced visible-light photocatalytic hydrogen production10.1038/ncomms13907 ↗
29. MXene: a promising photocatalyst for water splitting10.1039/C6TA04414J ↗
30. A novel nitrite biosensor based on the direct electrochemistry of hemoglobin immobilized on MXene-Ti3C210.1016/j.snb.2015.04.090 ↗
31. Monolayer Ti2CO2: a promising candidate for NH3 sensor or capturer with high sensitivity and selectivity10.1021/acsami.5b03737 ↗
32. Photoluminescent Ti3C2 MXene quantum dots for multicolor cellular imaging10.1002/adma.201604847 ↗
33. Highly loaded MXene/carbon nanotube yarn electrodes for improved asymmetric supercapacitor performance10.1557/mrc.2019.7 ↗
34. MXene: a promising transition metal carbide anode for lithium-ion batteries10.1016/j.elecom.2012.01.002 ↗
35. Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors10.1038/ncomms7544 ↗
36. Porous heterostructured MXene/carbon nanotube composite paper with high volumetric capacity for sodium-based energy storage devices10.1016/j.nanoen.2016.06.005 ↗
37. MXene-coated silk-derived carbon cloth toward flexible electrode for supercapacitor application10.1016/j.jechem.2017.10.030 ↗
38. Synthesis and thermal stability of two-dimensional carbide MXene Ti3C210.1016/j.mseb.2014.10.009 ↗
39. Two-dimensional vanadium carbide (MXene) as a high-capacity cathode material for rechargeable aluminum batteries10.1021/acsnano.7b05350 ↗
40. Intercalation and exfoliation routes to graphite nanoplatelets10.1039/b413029d ↗
41. Two-dimensional transition metal carbides10.1021/nn204153h ↗
42. MXene: an emerging two-dimensional material for future energy conversion and storage applications10.1039/C7TA09094C ↗
43. Synthesis of a new graphene-like transition metal carbide by de-intercalating Ti3AlC210.1016/j.matlet.2013.07.102 ↗
44. Calculated elastic properties of M2AlC (M=Ti, V, Cr, Nb and Ta)10.1016/j.ssc.2003.12.008 ↗
45. Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)10.1021/acs.chemmater.7b02847 ↗
46. Transparent conductive two-dimensional titanium carbide epitaxial thin films10.1021/cm500641a ↗
47. Synthesis and electrochemical properties of two-dimensional RGO/Ti₃C₂T(x) nanocomposites10.3390/nano8020080 ↗
48. Preparation of Ti3C2 and Ti2C MXenes by fluoride salts etching and methane adsorptive properties10.1016/j.apsusc.2017.04.239 ↗
49. Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide10.1126/science.1241488 ↗
50. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance10.1038/nature13970 ↗
51. Graphene-like titanium carbides and nitrides Tin+1Cn, Tin+1Nn (n=1, 2, and 3) from de-intercalated MAX phases: first-principles probing of their structural, electronic properties and relative stability10.1016/j.commatsci.2012.07.011 ↗
52. Synthesis of two-dimensional titanium nitride Ti4N3 (MXene)10.1039/C6NR02253G ↗
53. Two-dimensional titanium nitride (Ti2N) MXene: synthesis, characterization, and potential application as surface-enhanced raman scattering substrate10.1021/acsnano.7b03129 ↗
54. Pseudocapacitive Storage in Nanolayered Ti2NTx MXene Using Mg-Ion Electrolyte10.1021/acsanm.9b00289 ↗
55. Electrocatalytic and optoelectronic characteristics of the two-dimensional titanium nitride Ti4N3Tx MXene10.1021/acsami.9b01150 ↗
56. Intercalation and delamination of layered carbides and carbonitrides10.1038/ncomms2664 ↗
57. Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”10.1039/C5DT01247C ↗
58. Antibacterial activity of Ti3C2Tx MXene10.1021/acsnano.6b00181 ↗
59. Ultrathin MXene-Micropattern-Based field-effect transistor for probing neural activity10.1002/adma.201504657 ↗
60. Effects of applied potential and water intercalation on the surface chemistry of Ti2C and Mo2C MXenes10.1021/acs.jpcc.6b09109 ↗
61. MXene/graphene hybrid fibers for high performance flexible supercapacitors10.1039/C7TA07999K ↗
62. Preparation of high-purity V2C MXene and electrochemical properties as Li-Ion batteries10.1149/2.0641704jes ↗
63. Synthesis and electrochemical properties of two-dimensional hafnium carbide10.1021/acsnano.7b00030 ↗
64. Amine-assisted delamination of Nb2C MXene for Li-Ion energy storage devices10.1002/adma.201500604 ↗
65. Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)10.1021/acsnano.5b03591 ↗
66. Synthesis and electrochemical performance of Ti3C2Tx with hydrothermal process10.1007/s13391-016-6088-z ↗
67. Effect of hydrazine intercalation on structure and capacitance of 2D titanium carbide (MXene)10.1039/C6NR01462C ↗
68. Low temperature solution synthesis of reduced two dimensional Ti3C2 MXenes with paramagnetic behaviour10.1039/C8NR06854B ↗
69. Three-dimensional porous MXene/layered double hydroxide composite for high performance supercapacitors10.1016/j.jpowsour.2016.07.062 ↗
70. Binder-free Ti3C2Tx MXene electrode film for supercapacitor produced by electrophoretic deposition method10.1016/j.cej.2017.02.144 ↗
71. Electrospun MXene/carbon nanofibers as supercapacitor electrodes10.1039/C8TA09810G ↗
72. Two-dimensional V4C3 MXene as high performance electrode materials for supercapacitors10.1016/j.electacta.2019.03.205 ↗
73. Dispersions of two-dimensional titanium carbide MXene in organic solvents10.1021/acs.chemmater.6b04830 ↗
74. Organic-Base-Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance10.1002/anie.201606643 ↗
75. Few-layer MXenes delaminated via high-energy mechanical milling for enhanced sodium-ion batteries performance10.1021/acsami.7b12155 ↗
76. Electronic properties and applications of MXenes: a theoretical review10.1039/C7TC00140A ↗
77. Predicted surface composition and thermodynamic stability of MXenes in solution10.1021/acs.jpcc.5b11887 ↗
78. Persson · 2019 · 125
79. NMR reveals the surface functionalisation of Ti3C2 MXene10.1039/C6CP00330C ↗
80. Schottky-barrier-Free contacts with two-dimensional semiconductors by surface-engineered MXenes10.1021/jacs.6b10834 ↗
81. Transition metal carbides and nitrides in energy storage and conversion10.1002/advs.201500286 ↗
82. Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media10.1039/C4TA02638A ↗
83. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes)10.1021/acs.chemmater.7b00745 ↗
84. Flexible and conductive MXene films and nanocomposites with high capacitance10.1073/pnas.1414215111 ↗
85. Fabrication of Ti3C2Tx MXene transparent thin films with tunable optoelectronic properties10.1002/aelm.201600050 ↗
86. Highly conductive optical quality solution-processed films of 2D titanium carbide10.1002/adfm.201600357 ↗
87. Novel electronic and magnetic properties of two-dimensional transition metal carbides and nitrides10.1002/adfm.201202502 ↗
88. Two-dimensional Nb-Based M4C3 solid solutions (MXenes)10.1111/jace.13922 ↗
89. New two-dimensional niobium and vanadium carbides as promising materials for Li-Ion batteries10.1021/ja405735d ↗
90. Theoretical stability and materials synthesis of a chemically ordered MAX phase, Mo2ScAlC2, and its two-dimensional derivate Mo2ScC2 MXene10.1016/j.actamat.2016.12.008 ↗
91. Two-dimensional molybdenum carbide (MXene) as an efficient electrocatalyst for hydrogen evolution10.1021/acsenergylett.6b00247 ↗
92. A two-dimensional zirconium carbide by selective etching of Al3C3 from nanolaminated Zr3Al3C510.1002/anie.201510432 ↗
93. 2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)10.1039/C7NR06721F ↗
94. Two-dimensional Ti3C2 as anode material for Li-ion batteries10.1016/j.elecom.2014.07.026 ↗
95. High mass loading, binder-free MXene anodes for high areal capacity Li-ion batteries10.1016/j.electacta.2015.02.132 ↗
96. MoS2-on-MXene heterostructures as highly reversible anode materials for lithium-ion batteries10.1002/anie.201710616 ↗
97. 3D porous MXene (Ti3C2)/Reduced graphene oxide hybrid films for advanced Lithium storage10.1021/acsami.7b17386 ↗
98. Fe3O4@Ti3C2 MXene hybrids with ultrahigh volumetric capacity as an anode material for lithium-ion batteries10.1039/C8TA00122G ↗
99. S-functionalized MXenes as electrode materials for Li-ion batteries10.1016/j.apmt.2016.07.005 ↗
100. Theoretical investigation of zirconium carbide MXenes as prospective high capacity anode materials for Na-ion batteries10.1039/C8TA04417A ↗