journal article·2026-08Open access

Aging in Mechanics and Electromagnetic Properties of Polymer Composites for Signal Frequencies Beyond the Gigahertz Limit

Lahti A, Asp A, George L, Jutila L, Hentilä T, Järveläinen J, Hakala P, Karunarathna A, Di Vito D, Kanerva M

Applied Composite Materials· Volume 33· Issue 4

Abstract

Abstract Polymeric materials with various reinforcements are frequently used in radomes and enclosures to protect sensitive electronics from weather and mechanical damage. This work focuses on attenuation of radio frequency (RF) signals beyond 1 GHz when composites have experienced long-term aging effects due to ultraviolet (UV) exposure. Glass fibre (GF) reinforced epoxy, GF-reinforced polyester and natural flax fibre-reinforced epoxy are studied. The methods are attenuation measurements using the free space method for RF attenuation, split-post dielectric resonator, and mechanical testing via flexural tests. The results indicate decreases in strength for polyester-based GF-reinforced composite and pure matrix specimens, 8.9–23%, respectively, after UV aging of 72 and 180 days, respectively. The aging increased brittleness of the composite with a decrease in the strain at peak stress by 12%. Also the epoxy-matrix composites with flax reinforcement experienced degradation, shown by 43% decrease in flexural stiffness. 18 days of UV aging led to an increase of loss tangent in pure UPE (0.0078±0.00007 versus 0.00872±0.00012).
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Research context

OpenAlex topics: Smart Materials for Construction · Electromagnetic wave absorption materials · Natural Fiber Reinforced Composites

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References (38)

Show source-provided references
1. Järveläinen, J., Karttunen, A., Aurinsalo, J., Huhtinen, I., Hujanen, A.: Characterization of mmWave radomes for base stations and automotive radars. In: 2019 $$13th$$ European Conference on Antennas and Propagation (EuCAP), pp 1–5 (2019)
2. Connor, D., Barnard, D., Jones, R., McClelland, F., Bowler, N.: Dielectric and infrared inference of thermo-oxidative aging of a bismaleimide composite material. Compos. B Eng. 101, 167–175 (2016)10.1016/j.compositesb.2016.06.004 ↗
3. Gahleitner, R., Bonek, E.: Radio wave penetration into urban buildings in small cells and microcells. In: Proceedings of Vehicular Technology Conference (VTC). Stockholm, Sweden, June 8-10, IEEE (1994)
4. Dhere, P., Chilveri, P., Vatti, R., Iyer, V., Jagdale, K.: Analysis of the impact of building materials on ISM 2.4 GHz band. In: Proceedings of the IEEE International Conference on Current Trends toward Converging Technologies. Coimbatore, India (2018)10.1109/ICCTCT.2018.8550827 ↗
5. Bouvard, O., Lanini, M., Burnier, L., Witte, R., Cuttat, B., Salvade, A., et al.: Mobile communication through insulating windows: A new type of low emissivity coating. In: Proceedings of the CISBAT International Conference—Future Buildings and Districts—Energy Efficiency from Nano to Urban Scale. Lausanne, Switzerland, September 6-8, Energy Procedia, p. 122 (2017)10.1016/j.egypro.2017.07.396 ↗
6. Riddle, B., Baker-Jarvis, J., Krupka, J.: Complex permittivity measurements of common plastics over variable temperatures. IEEE Trans. Microw. Theory Tech. 51(3), 727–733 (2003)10.1109/TMTT.2003.808730 ↗
7. Riddle, B., Baker-Jarvis, J., Krupka, J.: Erratum: Complex permittivity measurements of common plastics over variable temperatures. IEEE Trans. Microwave Theory Tech. 51(2148), (2003). IEEE Transactions on Microwave Theory and Techniques 2003;51(10):214810.1109/TMTT.2003.817470 ↗
8. Ramo, S., Whinnery, J., Duzer, T.: Fields and Waves in Communication Electronics. Wiley, NY (1994)
9. Frank, G., Massman, J., Barnett, P., Butcher, D.: Thermal and structural analysis or a vascular cooled composite radome. SAMPE J. 60(3), 20–27 (2024)10.33599/SJ.v60no3.02 ↗
10. Di Vito, D., Kanerva, M., Järvelä, J., Laitinen, A., Pärnänen, T., Saari, K., et al.: Safe and sustainable design of composite smart poles for wireless technologies. Appl. Sci. 10(1), 7594 (2020)10.3390/app10217594 ↗
11. Pavan, C.M., Abdul, A.M., Nikhilesh, G.P., Sateesh, N.: Modelling and analysis of aircraft radome using different materials. Mater. Today Proc. 62(6), 4492–4497 (2022)
12. Audone, B., Delogu, A., Moriondo, P.: Radome design and measurements. IEEE Trans. Instrum. Meas. 37(2), 292–295 (1988)10.1109/19.6069 ↗
13. Sampers, J., Hutten, E., Gijsman, P.: Accelerated weathering of unsaturated polyester resins. aspects of appearance change. Polym. Testing 44, 208–223 (2015)10.1016/j.polymertesting.2015.04.012 ↗
14. Costa, F., Borgese, M., Degiorgi, M., Monorchio, A.: Electromagnetic characterisation of materials by using transmission/reflection (T$$/$$R) devices. Electronics (Basel) 6(4), 95 (2017)
15. Hakala, P., Javanshour, F., Jordan, J., Laaksonen, P., Jutila, L., Järveläinen, J., et al.: The performance of flax reinforced composites for wireless and sport applications: natural additives and sandwich concepts. In: Vassilopoulos, A. P., Michaud, V. (eds.), Proceedings of the 20$$th$$ European Conference on Composite Materials: Composites meet sustainability. Lausanne, Switzerland, June 26-30, (2022)
16. Barani, Z., Kargar, F., Ghafouri, Y., Baraghani, S., Sudhindra, S., Mohammadzadeh, A., et al.: Electromagnetic-polarization-selective composites with quasi-1D Van der Waals fillers: Nanoscale material functionality that mimics macroscopic systems. ACS Appl. Mater. Interf. 13(18), 21527–21533 (2021)10.1021/acsami.1c03204 ↗
17. Shokrieh, M., Bayat, A.: Effects of ultraviolet radiation on mechanical properties of glass/polyester composites. J. Compos. Mater. 41(20), 2443–2455 (2007)10.1177/0021998307075441 ↗
18. Reyes, N., Casado, F., Tapia, V.: Complex dielectric permittivity of engineering and 3D printing polymers at Q band. J. Infrared Millimeter Terahertz Waves 39, 1140–1147 (2018)10.1007/s10762-018-0528-9 ↗
19. Awaja, F., Pigram, P.: Surface molecular characterisation of different epoxy resin composites subjected to UV accelerated degradation using XPS and ToF-SIMS. Polym. Degrad. Stab. 94(4), 651–658 (2009)10.1016/j.polymdegradstab.2009.01.001 ↗
20. Tanaka, T.: Aging of polymeric and composite insulating materials. Aspects of interfacial performance in aging. IEEE Trans. Dielectr. Electr. Insul. 9(5), 704–716 (2002)10.1109/TDEI.2002.1038658 ↗
21. Jiang, X., Sima, W., Peng, Q., Yang, M., Sun, P.: Effect of thermal ageing on space charge characteristics in double-layered polyester film. IEEE Trans. Dielectr. Electr. Insul. 23(5), 3156–3164 (2016)10.1109/TDEI.2016.7736881 ↗
22. Spectral power distribution for QUV with UVA-340 fluorescent lamps. Technical data sheet, Q-Lab Corp (2011)
23. Myllari, V., Ruoko, T., Järvelä, P.: The effects of UV irradiation to polyetheretherketone fibres. Polym. Degrad. Stab. 109(1), 278–284 (2014)10.1016/j.polymdegradstab.2014.08.003 ↗
24. Jacques, L.: Accelerated and outdoor/natural exposure testing of coatings. Prog. Polym. Sci. 25(9), 1337–1362 (2000)10.1016/S0079-6700(00)00030-7 ↗
25. Altan, N.: Indoor wireless metering networks, Institute for Computer Science and Business Information Systems, University of Duisburg-Essen (2009). (Ph.D. thesis)
26. Norton, K.: Transmission loss in radio propagation. Proc. IRE 41(1), 146–152 (1953)10.1109/JRPROC.1953.274172 ↗
27. Schwartz, R.: Measurement of dielectric material properties. Procedure, (2012). Cited: August, 2024 https://www.rohde-schwarz.com/in/applications/measurement-of-dielectric-material-properties-application-note 56280-15697.html
28. Goncalves, F., Pinto, A., Mesquita, R., Silva, E., Brancaccio, A.: Free-space materials characterization by reflection and transmission measurements using frequency-by-frequency and multi-frequency algorithms. Electronics 7, 260 (2018)10.3390/electronics7100260 ↗
29. Nicolson, A., Ross, G.: Measurement of the intrinsic properties of materials by time-domain techniques. IEEE Trans. Instrum. Meas. 19(4), 377–382 (1970)10.1109/TIM.1970.4313932 ↗
30. Rothwell, E., Frasch, J., Ellison, S., Chahal, P., Ouedraogo, R.: Analysis of the Nicolson-Ross-Weir method for characterizing the electromagnetic properties of engineered materials. Electromagnet. Waves (Cambridge) 157, 31–47 (2016)10.2528/PIER16071706 ↗
31. Gu, X., Raghavan, D., Nguyen, T., VanLandingham, M., Yebassa, D.: Characterization of polyester degradation using tapping mode atomic force microscopy: Exposure to alkaline solution at room temperature. Polym. Degrad. Stab. 74(1), 139–149 (2001)10.1016/S0141-3910(01)00138-0 ↗
32. Bélan, F., Bellenger, V., Mortaigne, B.: Hydrolytic stability of unsaturated polyester networks with controlled chain ends. Polym. Degrad. Stab. 56(1), 93–102 (1997)10.1016/S0141-3910(96)00185-1 ↗
33. Javanshour, F., Prapavesis, A., Pärnänen, T., Orell, O., Lessa, B.M., Layek, R., et al.: Modulating impact resistance of flax epoxy composites with thermoplastic interfacial toughening. Compos. A Appl. Sci. Manuf. 150, 106628 (2021)10.1016/j.compositesa.2021.106628 ↗
34. Zhao, Q., Jia, Z., Li, X., Ye, Z.: Surface degradation of unsaturated polyester resin in Xe artificial weathering environment. Mater. Des. 31(9), 4457–4460 (2010)10.1016/j.matdes.2010.04.004 ↗
35. Loss, C., Goncalves, R., Pinho, P., Salvado, R.: Influence of some structural parameters on the dielectric behavior of materials for textile antennas. Text. Res. J. 89(7), 1131–1143 (2019)10.1177/0040517518764000 ↗
36. Wang, W., He, D., Gu, J., Lu, J., Du, J.: Electrical–thermal aging characteristic research of polymer materials by infrared spectroscopy. Polym. Adv. Technol. 25(12), 1396–1405 (2014)10.1002/pat.3375 ↗
37. Kanerva, M., Sarlin, E., Hoikkanen, M., Rämö, K., Saarela, O., Vuorinen, J.: Interface modification of glass fibre–polyester composite–composite joints using peel plies. Int. J. Adhes. Adhes. 59, 40–52 (2015)10.1016/j.ijadhadh.2015.01.016 ↗
38. Mustafa, E.: Investigation of aging process of insulating materials in multi-stress environment, Department of Electric Power Engineering, Budapest University of Technology and Economics (2021). (Ph.D. thesis)