journal article·2021-04Open access

Predicting Delaminations and Residual Strength of Carbon Fibre Reinforced Polymers (CFRP) After One-Sided Thermal Loading by Means of Infrared Spectroscopy

Tanja Marina Vetter, Sebastian Eibl, Hans-Joachim Gudladt

Applied Composite Materials· Volume 28· Issue 2

Abstract

Abstract This study investigates the change of chemical, structural, and mechanical properties of carbon fibre reinforced polymers (CFRP) after one-sided thermal loading. Therefore, CFRP samples (HexPly® 8552/IM7) with varying thickness (4 and 8 mm) are irradiated at different heat fluxes (15, 30, and 50 kW/m2). For a depth-resolved view on matrix degradation inside the CFRP, infrared spectroscopy (ATR-FTIR) is applied along a ground incline plane. A change of structural properties in the form of developing delaminations is investigated with microfocused computed X-ray tomography (µCT). The loss of residual strength is determined by means of interlaminar shear strength testing (ILSS). The evaluation of the data shows that delaminations occur predominantly dependent on temperature and only beyond a certain level of matrix degradation traceable by IR spectroscopy. It is also shown that delaminations are mainly responsible for the loss of strength. Furthermore, linear discriminant analysis (LDA) is performed to predict the presence of delaminations. This information provides a basis for a reliable prediction of the residual strength by IR spectroscopy after one-sided thermal loading.
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Research context

OpenAlex topics: Thermography and Photoacoustic Techniques · Ultrasonics and Acoustic Wave Propagation · Fire effects on concrete materials

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References (46)

Show source-provided references
1. Schürmann, H.: Konstruieren mit Faser-Kunststoff-Verbunden. 2nd edition, Springer (2007)10.1007/978-3-540-72190-1 ↗
2. Tant, M.R., Connel, J.W., McManus, H.L.N.: High-Temperature Properties and Applications of Polymeric Materials. ACS Symposium Series (1995)10.1021/bk-1995-0603 ↗
3. Mouritz, A.P., Gibson, A.G.: Fire Properties of Polymer Composite Materials, Springer (2006)
4. Henderson, J.B., Wiebelt, J.A., Tant, M.R.: A Model for the Thermal Response of Polymer Composite Materials with Experimental Verification. J. Compos. Mater. 19, 579–595 (1985)10.1177/002199838501900608 ↗
5. Milke, J.A., Vizzini, A.J.: Thermal Response of Fire-Exposed Composites. J. Compos. Tech. Res. 13, 145–151 (1991)10.1520/CTR10219J ↗
6. La Delfa, G., Urso-Miano, V., Gibson, AG.: Thermal damage in composite wing boxes. 17th International Conference on Composites, Proceedings, Edinburgh, United Kingdom (2009)
7. Ng, SJ., Cramer, R.J., Mehrkam, P.: Characterization of IM7/8552 polymer composites subjected to heat damage. 29th International SAMPE Technical Conference, Proceedings, Orlando, Florida (1997)
8. Pering, G.A., Farrell, P.V., Springer, G.S.: Degradation of tensile and shear properties of composites exposed to fire or high temperature. J. Compos. Mater. 14, 54–68 (1980)
9. Vieille, B., Coppalle, A., Keller, C., Garde, M.R., Viel, Q., Dargent, E.: Correlation between post fire behavior and microstructure degradation of aeronautical polymer composites. Mater. Des. 74, 74–85 (2015)
10. Gardiner, C.P., Mathis, Z., Mouritz, A.P.: Tensile and Compressive Properties of FRP Composites with Localised Fire Damage. Appl. Compos. Mater. 9, 353–367 (2002)10.1023/A:1020204913612 ↗
11. Wolfrum, J., Whitney, E., Eibl, S.: Approaches to understand and predict the influence of rapid heat-up on degradation and strength of carbon fibre polymer matrix composites. J. Compos. Mater. 51, 1–13 (2016)
12. Ankara, A., Gökçe Dara, B., Weisgerber, D.: The Thermal Response of CFRP Structures. J. Thermoplast. Compos. Mater. 16, 317–331 (2003)10.1177/0892705703016004003 ↗
13. Vetter, T.M., Bibinger, J., Zimmer, F., Eibl, S., Gudladt, H.J.: Characterization of one-sided thermal damage of carbon fiber reinforced polymers by means of depth profiles. J. Compos. Mater. 54, 3699–3713 (2020)10.1177/0021998320917190 ↗
14. Awaja, F., Nguyen, M.T., Zhang, S., Arhatari, B.: The investigation of inner structural damage of UV and heat degraded polymer composites using X-ray micro CT. Compos. Part A. 42, 408–418 (2011)10.1016/j.compositesa.2010.12.015 ↗
15. Amenabar, I., Mendikute, A., López-Arraiza, A., Lizaranzu, M., Aurrekoetxea, J.: Comparison and analysis of non-destructive testing techniques suitable for delamination inspection in wind turbin blades. Compos. Part B. 42, 1298–1305 (2011)10.1016/j.compositesb.2011.01.025 ↗
16. Towsyfyan, H., Biguri, A., Boardman, R., Blumensatz, T.: Successes and challenges in non-destructive testing of aircraft composite structures. Chin. J. Aeronaut. 33, 771–791 (2019)10.1016/j.cja.2019.09.017 ↗
17. Bondzic, S., Hodgkin, J., Krstina, J., Mardel, J.: Chemistry of Thermal Ageing in Aerospace Epoxy Composites. J. Appl. Polym. Sci. 100, 2210–2219 (2006)10.1002/app.23692 ↗
18. Dao, B., Hodgkin, J., Krstina, J., Mardel, J., Tian, W.: Accelerated Aging Versus Realistic Aging in Aerospace Composite Materials. II. Chemistry of Thermal Aging in a Structural Composite. J. Appl. Polym. Sci. 102, 3221–3232 (2006)10.1002/app.24573 ↗
19. Wolfrum, J., Eibl, S., Lietch, L.: Rapid evaluation of long-term thermal degradation of carbon fibre epoxy composites. Compos. Sci. Technol. 69, 523–530 (2009)10.1016/j.compscitech.2008.11.018 ↗
20. Dara, I.H., Ankara, A., Akovali, G., Suzer, S.: Heat-damage assessment of carbon-fiber-reinforced polymer composites by diffuse reflectance infrared spectroscopy. J. Appl. Polym. Sci. 96, 1222–1230 (2005)10.1002/app.21500 ↗
21. Heckner, S., Geistbeck, M., Grosse, C.U., Eibl, S., Helwig, A.: FTIR spectroscopy as a non-destructive testing method for CFRP surfaces in aerospace. 7th International Symposium on NDT in Aerospace, conference paper, Bremen, Germany (2015)
22. Shelley, P., Vahey, P., Werner, G., Seelenbinder, J.: Handheld Infrared Spectroscopy for Composite Non-Destructive Testing. SAMPE 2011, Long Beach, CA (2011)
23. Eibl, S.: Observing Inhomogeneity of Plastic Components in Carbon Fiber Reinforced Polymer Materials by ATR-FTIR Spectroscopy in the Micrometer Scale. J. Compos. Mater. 42, 1231–1246 (2008)10.1177/0021998308091734 ↗
24. Doblies, A., Boll, B., Fiedler, B.: Prediction of Thermal Exposure and Mechanical Behavior of Epoxy Resin using Artificial Neural Networks and Fourier Transform Infrared Spectroscopy. Polymers 11(2), 363 (2019)10.3390/polym11020363 ↗
25. Toivola, R., Afkhami, F., Baker, S., McClure, J., Flinn, B.D.: Detection of incipient thermal damage in carbon fiber-bismaleimide composites using hand-held FTIR. Polym. Testing 69, 490–498 (2018)10.1016/j.polymertesting.2018.05.036 ↗
26. Eibl, S., Wolfrum, J.: Prospects to separately estimate temperature and duration of a thermal pre-load on a polymer matrix composite. J. Compos. Mater. 47, 3011–3025 (2012)10.1177/0021998312460714 ↗
27. Eibl, S.: Reliable and universally applicable chemometric techniques based on infrared spectroscopy to non-destructively quantify thermal damage of carbon fibre reinforced epoxy matrix composites. Polym. Testing 76, 396–410 (2019)10.1016/j.polymertesting.2019.03.027 ↗
28. Shelley, PH., Werner, G.J., Vahey, P.G.: Thermal effect measurement with mid-infrared spectroscopy. Applied for The Boeing Company, Patent no. US8552382B2 (2013)
29. Werner, G.J., Shelley, P.H., George, P.E.: Method for classifiying resins types in carbon fiber reinvorced plastic materials using IR spectroscopy. Applied for The Boeing Company, Patent no. US8044354B2 (2010)
30. Product Data Sheet HexPly® 8552, Hexcel Inc. www.hexcel.com
31. Cui, W.C., Wisnom, M.R., Jones, M.: Failure mechanisms in three and four point short beam bending tests of unidirectional glass/epoxy. J. Strain Anal. 27, 235–243 (1992)10.1243/03093247V274235 ↗
32. Aslan, Z.: Apparent interlaminar shear strength measurement by four point short beam test. Adv. Compos. Lett. 24(2), 27–32 (2015)10.1177/096369351502400203 ↗
33. DIN EN 2563.: Carbon fibre reinforced plastics – Unidirectional laminates – Determination of the apparent interlaminar shear strength. German Version, (1997–03)
34. Lee, L.C., Liong, C.Y., Jemain, A.A.: A Contemporary Review on Data Preprocessing (DP) Practice Strategy in ATR-FTIR Spectrum. Chemom. Intell. Lab. Syst. 163, 64–75 (2017)10.1016/j.chemolab.2017.02.008 ↗
35. Musto, P.: Two-Dimensional FTIR Spectroscopy Studies on the Thermal-Oxidative Degradation of Epoxy and Epoxy-Bis(maleimide) Networks
36. Eibl, S.: Influence of carbon fibre orientation on reaction-to-fire properties of polymer matrix composites. Fire Mater. 36, 309–324 (2011)10.1002/fam.1112 ↗
37. Wolfrum, J., Quan, E., Maier, G., Eibl, S.: Damage initiation of thermally degraded carbon composites in tension. J. Compos. Mater. 52(24), 3399–3409 (2018)10.1177/0021998318765928 ↗
38. Olivier, L., Baudet, C., Bertheau, D., Grandidier, J.C., Lafarie-Frenot, M.C.: Development of experimental, theoretical and numerical tools for studying thermo-oxidation of CFRP composites. Compos. Part A. 40, 1008–1016 (2009)10.1016/j.compositesa.2008.04.005 ↗
39. Musto, P., Ragosta, G., Russo, P., Mascia, L.: Thermal-Oxidative Degradation of Epoxy and Epoxy-Bismaleimide Networks: Kinetics and Mechanism. Macromol. Chem. Phys. 202(18), 234–243 (2001)10.1002/1521-3935(20011201)202:18<3445::AID-MACP3445>3.0.CO;2-N ↗
40. Eibl, S.: Thermal and Reaction to Fire Properties of CFRP under Various Heat Impact Scenarios – Specific Hazards. 17th European Conference on Composite Materials Munich, Proceedings, Munich, Germany (2016)
41. Schneider, B.: Einfluss des Oberflächenvorbehandlungsverfahrens auf die Alterungsbeständigkeit von strukturellen CFK-Klebungen. PhD-Thesis, Universität der Bundeswehr München (2018)
42. Seggewiß, P.: Experimentelle und numerische Untersuchung des Verhaltens kohlenstofffaserverstärkter Epoxidmatrix-Systeme unter einseitiger thermischer und gleichzeitiger mechanischer Belastung. PhD Thesis, Universität der Bundeswehr München (2011)
43. Schuster, T.: Einfluss von Carbon Nanotubes auf die funktionellen und strukturellen Eigenschaften von kohlenstofffaserverstärkten Kunststoffen. PhD Thesis, Universität der Bundeswehr München (2016)
44. Miller, J.N., Miller, J.C.: Statistics and Chemometrics for Analytical Chemistry. 6th edition, Pearson Education Limited (2010)
45. Naes, T., Isaksson, T., Fearn, T., Davies, T.: A user-friendly guide to Multivariate Calibration and Classification. NIR Publications Chichester (2002)
46. Backhaus, K., Erichson, B., Plinke, W., Weiber, R.: Multivariate Analysemethoden – eine anwendungsorientierte Einführung. 15th edition, Springer Gabler (2018)10.1007/978-3-662-56655-8 ↗