journal article·2021-08

On the Influence of the Functionalization of Graphene Nanoplatelets and Glass Fiber on the Mechanical Properties of GFRP Composites

Vigneshwaran Gnanakkan Samuel Veerakumar, Balasivanandha Prabu Shanmugavel, Sivasankaran Harish

Applied Composite Materials· Volume 28· Issue 4
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Abstract

This work presents the influence of functionalised graphene nanoplatelets (f-GnPs) and functionalised glass fibers (f-fiber) on the tensile strength and the fracture toughness of the GFRP composites. The functionalization on the glass fabric and GnPs was performed by using 3-Aminopropyltriethoxysilane (APTS) as a coupling agent and confirmed by Fourier Transform Infrared (FTIR) Spectroscopy. The GnPs (non-functionalised and functionalised) with 0.1 wt% was introduced in the composites in two different ways, (1) dispersing GnPs/f-GnPs in epoxy; (2) depositing GnPs/f-GnPs on the functionalized fiber (f-fiber) surface. The mechanical properties, such as tensile strength and Mode I fracture toughness of the multi-phase composites were investigated. The longitudinal intra-laminar Mode I fracture toughness test was performed on the compact tension (CT) specimens by using the digital image correlation (DIC) technique to perform the fracture control study. The tensile fracture surface morphology of the composites was examined by Scanning Electron Microscope (SEM). The tensile strength of the composites with f-GnPs deposited on the f-Fiber outperformed the unmodified composites with 16% enhancement owing to the strong fiber/matrix interface bonding developed by f-GnPs. The composites with f-GnPs dispersed in the matrix showed an increase in the fracture toughness (KIC) of 76% over the unmodified composites. The effects of the f-GnPs dispersed in the matrix showed good interfacial adhesion, while the composites with f-GnPs deposited on the f-Fibers showed poor fiber/matrix adhesion, as observed in the tensile fractography of the composites.
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Research context

OpenAlex topics: Graphene research and applications · Fiber-reinforced polymer composites · Mechanical Behavior of Composites

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References (51)

Show source-provided references
1. Karger-Kocsis, J., Mahmood, H., Pegoretti, A.: Recent advances in fiber/matrix interphase engineering for polymer composites. Prog. Mater Sci. 73, 1–43 (2015). https://doi.org/10.1016/j.pmatsci.2015.02.00310.1016/j.pmatsci.2015.02.003 ↗
2. Nagasankar, P., Balasivanandha Prabu, S., Velmurugan, R.: Role of different fiber orientations and thicknesses of the skins and the core on the transverse shear damping of polypropylene honeycomb sandwich structures, Mechanics of Materials. 91, 252–261 (2015). https://doi.org/10.1016/j.mechmat.2015.08.00210.1016/j.mechmat.2015.08.002 ↗
3. Hoffmann, J., Sabban, J., Scharr, G.: Pullout performance of circumferentially notched z-pins in carbon fiber reinforced laminates. Compos. A Appl. Sci. Manuf. 110, 197–202 (2018). https://doi.org/10.1016/j.compositesa.2018.05.00210.1016/j.compositesa.2018.05.002 ↗
4. Yekani Fard, M., Raji, B., Woodward, J., Padilla, M.: Experimental characterization of damage mechanisms of seamless net-shaped circular pre-form and overlapped stitched composite pipes, Polymer Testing. 78, 105934 (2019).https://doi.org/10.1016/j.polymertesting.2019.10593410.1016/j.polymertesting.2019.105934 ↗
5. Dell’Anno, G., Treiber, J.W.G., Partridge, I.K.: Manufacturing of composite parts reinforced through-thickness by tufting. Robotics and Computer-Integrated Manufacturing. 37, 262–272 (2016). https://doi.org/10.1016/j.rcim.2015.04.00410.1016/j.rcim.2015.04.004 ↗
6. Zhang, P., Zhou, W., Yin, H., Shang, Y.: Progressive damage analysis of three-dimensional braided composites under flexural load by micro-CT and acoustic emission. Compos. Struct. 226, 111196 (2019). https://doi.org/10.1016/j.compstruct.2019.11119610.1016/j.compstruct.2019.111196 ↗
7. Keszei, S., Matkó, S., Bertalan, G., Anna, P., Marosi, G., Tóth, A.: Progress in interface modifications: from compatibilization to adaptive and smart interphases. Eur. Polymer J. 41, 697–705 (2005). https://doi.org/10.1016/j.eurpolymj.2004.10.03910.1016/j.eurpolymj.2004.10.039 ↗
8. Miller, S.G., Bauer, J.L., Maryanski, M.J., Heimann, P.J., Barlow, J.P., Gosau, J.M., Allred, R.E.: Characterization of epoxy functionalized graphite nanoparticles and the physical properties of epoxy matrix nanocomposites. Compos. Sci. Technol. 70, 1120–1125 (2010). https://doi.org/10.1016/j.compscitech.2010.02.02310.1016/j.compscitech.2010.02.023 ↗
9. Barakat, N.A.M., Khalil, K.A., Kim, H.Y.: Toward facile synthesizing of diamond nanostructures via nanotechnological approach: Lonsdaleite carbon nanofibers by electrospinning. Mater. Res. Bull. 47, 2140–2147 (2012). https://doi.org/10.1016/j.materresbull.2012.06.01210.1016/j.materresbull.2012.06.012 ↗
10. Biswas, M., Sinha Ray, S.: A conducting nanocomposite of poly(N-vinylcarbazole) with buckminsterfullerene, Synthetic Metals. 123, 135–139 (2001). https://doi.org/10.1016/S0379-6779(00)01382-510.1016/S0379-6779(00)01382-5 ↗
11. Ma, P.C., Siddiqui, N.A., Marom, G., Kim, J.K.: Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review. Compos. A Appl. Sci. Manuf. 41, 1345–1367 (2010). https://doi.org/10.1016/j.compositesa.2010.07.00310.1016/j.compositesa.2010.07.003 ↗
12. Potts, J.R., Dreyer, D.R., Bielawski, C.W., Ruoff, R.S.: Graphene-based polymer nanocomposites. Polymer 52, 5–25 (2011). https://doi.org/10.1016/j.polymer.2010.11.04210.1016/j.polymer.2010.11.042 ↗
13. Singh, V., Joung, D., Zhai, L., Das, S., Khondaker, S.I., Seal, S.: Graphene based materials: Past, present and future. Prog. Mater Sci. 56, 1178–1271 (2011). https://doi.org/10.1016/j.pmatsci.2011.03.00310.1016/j.pmatsci.2011.03.003 ↗
14. Geim, A.K., Novoselov, K.S.: The rise of graphene. Nat. Mater. 6, 183–191 (2007). https://doi.org/10.1038/nmat184910.1038/nmat1849 ↗
15. Valorosi, F., De Meo, E., Blanco-Varela, T., Martorana, B., Veca, A., Pugno, N., Kinloch, I.A., Anagnostopoulos, G., Galiotis, C., Bertocchi, F., Gomez, J., Treossi, E., Young, R.J., Palermo, V.: Graphene and related materials in hierarchical fiber composites: Production techniques and key industrial benefits. Compos. Sci. Technol. 185, 107848 (2020). https://doi.org/10.1016/j.compscitech.2019.10784810.1016/j.compscitech.2019.107848 ↗
16. Rafiee, M.A., Rafiee, J., Wang, Z., Song, H., Yu, Z., Koratkar, N.: Enhanced Mechanical Properties of Nanocomposites at Low Graphene Content. ACS Nano 3, 3884–3890 (2009). https://doi.org/10.1021/nn901047210.1021/nn9010472 ↗
17. Mahmood, H., Tripathi, M., Pugno, N., Pegoretti, A.: Enhancement of interfacial adhesion in glass fiber/epoxy composites by electrophoretic deposition of graphene oxide on glass fibers. Compos. Sci. Technol. 126, 149–157 (2016). https://doi.org/10.1016/j.compscitech.2016.02.01610.1016/j.compscitech.2016.02.016 ↗
18. Thomason, J.L.: Glass fibre sizing: A review. Compos. A Appl. Sci. Manuf. 127, 105619 (2019). https://doi.org/10.1016/j.compositesa.2019.10561910.1016/j.compositesa.2019.105619 ↗
19. Thomason, J.: A review of the analysis and characterisation of polymeric glass fibre sizings. Polym. Testing 85, 106421 (2020). https://doi.org/10.1016/j.polymertesting.2020.10642110.1016/j.polymertesting.2020.106421 ↗
20. Wong, R.: Recent Aspects of Glass Fiber-Resin Interfaces. J. Adhes. 4, 171–179 (1972). https://doi.org/10.1080/0021846720807222110.1080/00218467208072221 ↗
21. Kuila, T., Bose, S., Mishra, A.K., Khanra, P., Kim, N.H., Lee, J.H.: Chemical functionalization of graphene and its applications. Prog. Mater Sci. 57, 1061–1105 (2012). https://doi.org/10.1016/j.pmatsci.2012.03.00210.1016/j.pmatsci.2012.03.002 ↗
22. Saravanan, N., Rajasekar, R., Mahalakshmi, S., Sathishkumar, T., Sasikumar, K., Sahoo, S.: Graphene and modified graphene-based polymer nanocomposites – A review. J. Reinf. Plast. Compos. 33, 1158–1170 (2014). https://doi.org/10.1177/073168441452484710.1177/0731684414524847 ↗
23. Ma, J., Meng, Q., Michelmore, A., Kawashima, N., Zaman, I., Bengtsson, C., Kuan, H.C.: Covalently bonded interfaces for polymer/graphene composites. Journal of Materials Chemistry A. 1, 4255–4264 (2013). https://doi.org/10.1039/c3ta01277h10.1039/c3ta01277h ↗
24. Georgakilas, V., Otyepka, M., Bourlinos, A.B., Chandra, V., Kim, N., Kemp, K.C., Hobza, P., Zboril, R., Kim, K.S.: Functionalization of Graphene: Covalent and Non-Covalent Approaches. Derivatives and Applications, Chemical Reviews. 112, 6156–6214 (2012). https://doi.org/10.1021/cr300041210.1021/cr3000412 ↗
25. Chen, J., Zhao, D., Jin, X., Wang, C., Wang, D., Ge, H.: Modifying glass fibers with graphene oxide: Towards high-performance polymer composites. Compos. Sci. Technol. 97, 41–45 (2014). https://doi.org/10.1016/j.compscitech.2014.03.02310.1016/j.compscitech.2014.03.023 ↗
26. Domun, N., Hadavinia, H., Zhang, T., Liaghat, G., Vahid, S., Spacie, C., Paton, K.R., Sainsbury, T.: Improving the fracture toughness properties of epoxy using graphene nanoplatelets at low filler content. Nanocomposites. 3, 85–96 (2017). https://doi.org/10.1080/20550324.2017.136541410.1080/20550324.2017.1365414 ↗
27. Yang, H., Li, F., Shan, C., Han, D., Zhang, Q., Niu, L., Ivaska, A.: Covalent functionalization of chemically converted graphene sheets via silane and its reinforcement. J. Mater. Chem. 19, 4632–4638 (2009). https://doi.org/10.1039/b901421g10.1039/b901421g ↗
28. Kuilla, T., Bhadra, S., Yao, D., Kim, N.H., Bose, S., Lee, J.H.: Recent advances in graphene based polymer composites. Progress in Polymer Science (Oxford). 35, 1350–1375 (2010). https://doi.org/10.1016/j.progpolymsci.2010.07.00510.1016/j.progpolymsci.2010.07.005 ↗
29. Seretis, G.V., Theodorakopoulos, I.D., Manolakos, D.E., Provatidis, C.G.: Effect of sonication on the mechanical response of graphene nanoplatelets/glass fabric/epoxy laminated nanocomposites. Compos. B Eng. 147, 33–41 (2018). https://doi.org/10.1016/j.compositesb.2018.04.03410.1016/j.compositesb.2018.04.034 ↗
30. ASTM.: Standard Test Method for Plane-Strain Fracture Toughness of Metallic Materials 1, ASTM Standard E399–90. 90, 1–31 (1997). https://doi.org/10.1520/E0399-90R9710.1520/E0399-90R97 ↗
31. Vigneshwaran, G.V., Prabu, S.B., Paskaramoorthy, R.: Effect of Graphene Addition on Crack Propagation Resistance in Glass Fibre Reinforced Polymer Matrix Composite, in: MSEC2018–6563 (Ed.), Volume 2: Materials; Joint MSEC-NAMRC-Manufacturing USA, American Society of Mechanical Engineers, College Station, Texas, USA, 2018: pp. 1–7. https://doi.org/10.1115/MSEC2018-656310.1115/MSEC2018-6563 ↗
32. Gao, Y., Sun, W., Yang, W., Li, Q.: Palladium nanoparticles supported on amine-functionalized glass fiber mat for fixed-bed reactors on the effective removal of hexavalent chromium by catalytic reduction. J. Mater. Sci. Technol. 34, 961–968 (2018). https://doi.org/10.1016/j.jmst.2017.05.01310.1016/j.jmst.2017.05.013 ↗
33. Yadav, S.K., Cho, J.W.: Functionalized graphene nanoplatelets for enhanced mechanical and thermal properties of polyurethane nanocomposites. Appl. Surf. Sci. 266, 360–367 (2013). https://doi.org/10.1016/j.apsusc.2012.12.02810.1016/j.apsusc.2012.12.028 ↗
34. Ojha, M., Penumakala, P.K., Marrivada, G.V., Chaganti, P.K., Gupta, A.K.: Processing of glass fiber pultruded composites using graphene nanoplatelets modified epoxy matrix. Materials Today: Proceedings. 18, 3298–3304 (2019). https://doi.org/10.1016/j.matpr.2019.07.23710.1016/j.matpr.2019.07.237 ↗
35. Priya, I.I.M., Vinayagam, B.K.: Enhancement of bi-axial glass fibre reinforced polymer composite with graphene platelet nanopowder modifies epoxy resin. Adv. Mech. Eng. 10, 1–10 (2018). https://doi.org/10.1177/168781401879326110.1177/1687814018793261 ↗
36. Rafiee, M., Nitzsche, F., Laliberte, J., Thibault, J., Labrosse, M.R.: Simultaneous reinforcement of matrix and fibers for enhancement of mechanical properties of graphene-modified laminated composites. Polym. Compos. 40, E1732–E1745 (2019). https://doi.org/10.1002/pc.2513710.1002/pc.25137 ↗
37. Ahmadi-Moghadam, B., Sharafimasooleh, M., Shadlou, S., Taheri, F.: Effect of functionalization of graphene nanoplatelets on the mechanical response of graphene/epoxy composites, Materials & Design (1980–2015). 66, 142–149 (2015). https://doi.org/10.1016/j.matdes.2014.10.04710.1016/j.matdes.2014.10.047 ↗
38. Drzal, L.T., Madhukar, M.: Fibre-matrix adhesion and its relationship to composite mechanical properties. J. Mater. Sci. 28, 569–610 (1993). https://doi.org/10.1007/BF0115123410.1007/BF01151234 ↗
39. Borrego, L.P., Costa, J.D.M., Ferreira, J.A.M., Silva, H.: Fatigue behaviour of glass fibre reinforced epoxy composites enhanced with nanoparticles. Compos. B Eng. 62, 65–72 (2014). https://doi.org/10.1016/j.compositesb.2014.02.01610.1016/j.compositesb.2014.02.016 ↗
40. Ahmadi-Moghadam, B., Taheri, F.: Influence of graphene nanoplatelets on modes I, II and III interlaminar fracture toughness of fiber-reinforced polymer composites. Eng. Fract. Mech. 143, 97–107 (2015). https://doi.org/10.1016/j.engfracmech.2015.06.02610.1016/j.engfracmech.2015.06.026 ↗
41. Rokbi, M., Osmani, H., Benseddiq, N., Imad, A.: On experimental investigation of failure process of woven-fabric composites. Compos. Sci. Technol. 71, 1375–1384 (2011). https://doi.org/10.1016/j.compscitech.2011.05.00310.1016/j.compscitech.2011.05.003 ↗
42. Kim, J.-K., Mai, Y.: High strength, high fracture toughness fibre composites with interface control—A review. Compos. Sci. Technol. 41, 333–378 (1991). https://doi.org/10.1016/0266-3538(91)90072-W10.1016/0266-3538(91)90072-W ↗
43. Khanna, S.K., Shukla, A.: Energy absorption mechanisms during dynamic fracturing of fibre-reinforced composites. J. Mater. Sci. 28, 3722–3730 (1993). https://doi.org/10.1007/BF0035317010.1007/BF00353170 ↗
44. Alexopoulos, N.D., Paragkamian, Z., Poulin, P., Kourkoulis, S.K.: Fracture related mechanical properties of low and high graphene reinforcement of epoxy nanocomposites. Compos. Sci. Technol. 150, 194–204 (2017). https://doi.org/10.1016/j.compscitech.2017.07.03010.1016/j.compscitech.2017.07.030 ↗
45. Domun, N., Paton, K.R., Blackman, B.R.K., Kaboglu, C., Vahid, S., Zhang, T., Dear, J.P., Kinloch, A.J., Hadavinia, H.: On the extent of fracture toughness transfer from 1D/2D nanomodified epoxy matrices to glass fibre composites. J. Mater. Sci. 55, 4717–4733 (2020). https://doi.org/10.1007/s10853-019-04340-810.1007/s10853-019-04340-8 ↗
46. Menbari, S., Ashori, A., Rahmani, H., Bahrami, R.: Viscoelastic response and interlaminar delamination resistance of epoxy/glass fiber/functionalized graphene oxide multi-scale composites. Polym. Testing 54, 186–195 (2016). https://doi.org/10.1016/j.polymertesting.2016.07.01610.1016/j.polymertesting.2016.07.016 ↗
47. Zaheer, U., Khurram, A.A., Subhani, T.: A treatise on multiscale glass fiber epoxy matrix composites containing graphene nanoplatelets. Advanced Composites and Hybrid Materials. 1, 705–721 (2018). https://doi.org/10.1007/s42114-018-0057-y10.1007/s42114-018-0057-y ↗
48. Li, Z., Wang, R., Young, R.J., Deng, L., Yang, F., Hao, L., Jiao, W., Liu, W.: Control of the functionality of graphene oxide for its application in epoxy nanocomposites. Polymer 54, 6437–6446 (2013). https://doi.org/10.1016/j.polymer.2013.09.05410.1016/j.polymer.2013.09.054 ↗
49. Jiang, T., Kuila, T., Kim, N.H., Ku, B.-C., Lee, J.H.: Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites. Compos. Sci. Technol. 79, 115–125 (2013). https://doi.org/10.1016/j.compscitech.2013.02.01810.1016/j.compscitech.2013.02.018 ↗
50. Chatterjee, S., Wang, J.W.W., Kuo, W.S.S., Tai, N.H.H., Salzmann, C., Li, W.L.L., Hollertz, R., Nüesch, F.A.A., Chu, B.T.T.T.T.: Mechanical reinforcement and thermal conductivity in expanded graphene nanoplatelets reinforced epoxy composites, Chemical Physics Letters. 531, 6–10 (2012) . https://doi.org/10.1016/j.cplett.2012.02.00610.1016/j.cplett.2012.02.006 ↗
51. Wang, X., Xing, W., Zhang, P., Song, L., Yang, H., Hu, Y.: Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites. Compos. Sci. Technol. 72, 737–743 (2012). https://doi.org/10.1016/j.compscitech.2012.01.02710.1016/j.compscitech.2012.01.027 ↗