journal article·2000-11

Oil Palm Fibre Reinforced Phenol Formaldehyde Composites: Influence of Fibre Surface Modifications on the Mechanical Performance

M. S. Sreekala, M. G. Kumaran, Seena Joseph, Maya Jacob, Sabu Thomas

Applied Composite Materials· Volume 7· Issue 5-6
Publisher page

Abstract

Oil palm fibres have been used as reinforcement in phenol formaldehyde resin. In order to improve the interfacial properties, the fibres were subjected to different chemical modifications such as mercerisation, acrylonitrile grafting, acrylation, latex coating, permanganate treatment, acetylation, and peroxide treatment. The effect of fibre coating on the interface properties has also been investigated. Morphological and structural changes of the fibres were investigated using scanning electron microscopy and IR spectroscopy. Mechanical properties of untreated and treated fibres were studied. Changes in stress–strain characteristics, tensile strength, tensile modulus and elongation at break of the fibres upon various modifications were studied and compared. The incorporation of the modified fibres resulted in composites having excellent impact resistance. Fibre coating enhanced the impact strength of untreated composite by a factor of four. Tensile and flexural performance of the composites were also investigated. Finally, inorder to have an insight into the failure behaviour, the tensile and impact fracture surfaces of the composites were analysed using scanning electron microscope.
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Research context

OpenAlex topics: Natural Fiber Reinforced Composites · Fiber-reinforced polymer composites · Advanced Cellulose Research Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. Hill, S., New Scientist, 1 Feb. 1997, p. 36.
2. Wright, J. R. and Mathias, L. J., 'New Lightweight Materials. BalsaWood-Polymer Composites Based on Ethyl _-(hydroxymethyl) Acrylate', J.Appl.Polym.Sci. 48, 1993, 2241.10.1002/app.1993.070481217 ↗
3. Hedenberg, P. and Gatenholm, P., 'Conversion of Plastic/Cellulose Waste into Composites. 1. Model of the Interphase', J.Appl.Polym.Sci. 56, 1995, 641.10.1002/app.1995.070560601 ↗
4. Maldas, D. and Kokta, B. V., 'Effect of Fibre Treatment on Mechanical Properties of Hybrid Fibre Reinforced Polystyrene Composites', J.Comp.Mater. 25, 1991, 375.10.1177/002199839102500402 ↗
5. Maldas, D. and Kokta, B. V., 'Effect of Recycling on the Mechanical Properties of Wood Fibre/Polystyrene Composites. II. Saw Dust as a Reinforcing Filler', Polym.Plast.Technol.Eng. 29, 1990, 419.10.1080/03602559008049856 ↗
6. Maldas, D., Kokta, B. V., Raj, R. G., and Daneault, C., 'Improvement of the Mechanical Properties of Sawdust Wood Fibre Polysterene Composites by Chemical Treatment', Polymer 29, 1988, 1255.10.1016/0032-3861(88)90053-5 ↗
7. Warner, R. R. and Rezai, E., 'Polymer-grafted Cellulose Fibres. III Interaction of Grafted and Ungrafted Fibres in Handsheets', J.Appl.Polym.Sci. 65, 1997, 1487.10.1002/(SICI)1097-4628(19970822)65:8<1487::AID-APP5>3.0.CO;2-C ↗
8. Bledzki, A. K., Reihmane, S., and Gassan, J., 'Properties and Modification Methods for Vegetable Fibres for Natural Fibre Composites', J.Appl.Polym.Sci. 59, 1996, 1329.10.1002/(SICI)1097-4628(19960222)59:8<1329::AID-APP17>3.0.CO;2-0 ↗
9. Gatenholm, P., Bertilsson, H., and Mathiasson, A., 'The Effect of Chemical Composition of Interphase on Dispersion of Cellulose Fibres in Polymers. 1. PVC Coated Cellulose in Polystyrene', J.Appl.Polym.Sci. 49, 1993, 197.10.1002/app.1993.070490202 ↗
10. Hon, D. N. S. and Ou, N. H., 'Thermoplasticization of Wood. 1. Benzylation of Wood', J.Polym.Sci.Part A: Polym.Chem. 27, 1989, 2457.10.1002/pola.1989.080270725 ↗
11. Blackketter, D. M., Upadhyaya, D., King, T. R., and King, J. A., Polym.Comps. 14, 1993, 430.10.1002/pc.750140510 ↗
12. Joly, C., Kofman, M., and Gauthier, R., J.M.S-Pure Appl.Chem.A 33(12), 1996, 1981.
13. Ghosh, P., Das, D., and Samanta, A. K., J.Polym.Mater. 12, 1995, 297.
14. David, C., Fornasier, R., Lejong, W., and Vanlautem, N., 'Pre-treatment of Eucalyptus Wood with Sodium Hypochlorite and Enzymatic Hydrolysis by Cellulases of Trichoderma Viride', J.Appl.Polym.Sci. 36, 1988, 29.10.1002/app.1988.070360103 ↗
15. Brewis, D. M., Comyn, J., Fowler, J. R., Briggs, D., and Gibson, V. A., Fib.Sci.Technol. 12, 1979, 41.10.1016/0015-0568(79)90011-3 ↗
16. King, J. A., Buttry, D. A., and Adams, D. F., Polym.Comps. 14, 1993, 292.10.1002/pc.750140404 ↗
17. Rowell, R. M. and Gutzmer, D. I., Wood Sci. 7, 1975, 240.
18. Hebeish, A., El-Rafie, M. H., Khalil, M. I., and Bendak, A., J.Appl.Polym.Sci. 21, 1977, 1901.10.1002/app.1977.070210716 ↗
19. Belgacem, M. N., Bataille, P., and Sapieha, S., 'Effect of Corona Modification on the Mechanical Properties of Polypropylene Cellulose Composites', J.Appl.Polym.Sci. 53, 1994, 379.10.1002/app.1994.070530401 ↗
20. King, J. A., Buttry, D. A., and Adams, D. F., Polym.Comps. 14, 1993, 301.10.1002/pc.750140405 ↗
21. Nitschke, M. and Meichsner, J., 'Low Pressure Plasma Polymer Modification from the FTIR Point of View', J.Appl.Polym.Sci. 65, 1997, 391.10.1002/(SICI)1097-4628(19970711)65:2<381::AID-APP19>3.0.CO;2-2 ↗
22. Wu, S. R., Sheu, G. S., and Shyu, S. S., 'Kevlar Fibre-Epoxy Adhesion and its Effect on Composite Mechanical and Fracture Properties by Plasma and Chemical Treatment', J.Appl.Polym.Sci. 62, 1996, 1347.10.1002/(SICI)1097-4628(19961128)62:9<1347::AID-APP5>3.0.CO;2-H ↗
23. George, J., Bhagawan, S. S., and Thomas, S., 'Improved Interactions in Chemically Modified Pineapple Leaf Fibre Reinforced Polyethylene Composites', Composite Interfaces 5, 1998, 201.10.1163/156855498X00153 ↗
24. Nair, K. C. M., Diwan, S. M., and Thomas, S., 'Tensile Properties of Short Sisal Fibre Reinforced Polystyrene Composites', J.Appl.Polym.Sci. 60, 1996, 1483.10.1002/(SICI)1097-4628(19960531)60:9<1483::AID-APP23>3.0.CO;2-1 ↗
25. Joseph, K., Thomas, S., and Pavithran, C., 'Effect of Chemical Treatment on Short Sisal Fibre Reinforced Polyethylene Composites', Polymer 37, 1996, 5139.10.1016/0032-3861(96)00144-9 ↗
26. Pothen, L. A., Neelakantan, N. R., and Thomas, S., 'Short Banana Fibre Reinforced Polyester Composites: Mechanical Failure & Ageing Characteristics', J.Reinf.Plast.Comp. 16, 1997, 744.10.1177/073168449701600806 ↗
27. Sreekala, M. S., Kumaran, M. G., and Thomas, S., 'Oil Palm Fibres: Morphology, Chemical Composition, Surface Modification & Mechanical Properties', J.Appl.Polym.Sci. 66, 1997, 821.10.1002/(SICI)1097-4628(19971031)66:5<821::AID-APP2>3.0.CO;2-X ↗
28. Demma, G., Acierno, D., Russo, P., and Kenny, J. M., J.Polym.Eng. 14, 1995, 283.10.1515/POLYENG.1995.14.4.283 ↗
29. Sreekala, M. S., Thomas, S., and Neelakantan, N. R., 'Utilization of Short Oil Palm Empty Fruit Bunch Fibre as Reinforcement in Phenol-Formaldehyde Resin: Studies on Mechanical Properties', J.Polym.Eng. 16, 1997, 265.
30. Thejappa, N. and Pandey, S. N., 'Characterisation of Cotton-Polysterene Graft Copolymers', J.Appl.Polym.Sci. 27, 1982, 2307.10.1002/app.1982.070270701 ↗
31. Kundu, S. K., Ray, P. K., Sen, S. K., and Bhaduri, S. K., 'Characterisation of Grafted Jute Fibre by Optical ans Scanning Electron Microscopy', J.Appl.Polym.Sci. 49, 1993, 25.10.1002/app.1993.070490104 ↗
32. Sikdar, B., Basak, R. K., and Mitra, B. C., 'Studies on Graft Copolymerisation of Acrylonitrile onto Jute Fibre with Permanganate Ion Initiation System in Presence of Air', J.Appl.Polym.Sci. 55, 1995, 1673.10.1002/app.1995.070551207 ↗
33. Hornof, V., Kokta, B. V., and Valade, J. L., J.Appl.Polym.Sci. 20, 1976, 1543.10.1002/app.1976.070200612 ↗
34. Kessira, L. and Ricard, A., 'Thermal Behaviour of Ungrafted and Grafted Bagasse and Wood Pulps', J.Appl.Polym.Sci. 49, 1993, 1603.10.1002/app.1993.070490911 ↗
35. Hon, D. N. S. (ed.), Graft Copolymerization of Lignocellulosic Fibres, ACS Symposium Series 187, Washington D.C., 1982.10.1021/bk-1982-0187 ↗
36. Mohanty, A. K., Parija, S., and Misra, M., 'Ce (IV)-N-Acetylglycine Initiated Graft Copolymerisation of Acrylonitrile onto Chemically Modified Pineapple Leaf Fibres', J.Appl.Polym.Sci. 60, 1996, 931.10.1002/(SICI)1097-4628(19960516)60:7<931::AID-APP2>3.0.CO;2-N ↗
37. Carvalho, D. L., 'Polypropylene-Wood Fibre Composites: Effect of Treatment and Mixing Conditions on Mechanical Properties', J.Appl.Polym.Sci. 65, 1997, 1227.10.1002/(SICI)1097-4628(19970808)65:6<1227::AID-APP18>3.0.CO;2-Q ↗
38. Ghosh, P. and Ganguly, P. K., 'Polyacrylonitrile (PAN)-Grafted Jute Fibres: Some Physical and Chemical Properties and Morphology', J.Appl.Polym.Sci. 52, 1994, 77.10.1002/app.1994.070520109 ↗
39. Raj, R. G., Kokta, B. V., Grouleau, G., and Daneault, C., Polym.Plast.Technol.Eng. 29, 1990, 339.10.1080/03602559008049849 ↗
40. Kau, H. T., Polymer Composites 11, 1990, 253.10.1002/pc.750110502 ↗
41. Jang, B. Z., Chen, L. C., Hwang, L. R., Hawkes, J. E., and Zee, R. H., Polym.Comp. 11, 1990, 144.10.1002/pc.750110303 ↗
42. Reed, P. E. and Bevan, L., Polym.Comp. 14, 1993, 286.10.1002/pc.750140403 ↗
43. Nielsen, L. E., Mechanical Properties of Polymers and Composites, Vol. 2, Marcel Dekker, New York, 1974.
44. Liu, Yu-Fu and Kagawa, Y., 'Analysis of Debonding and Frictional Sliding in Fibre-Reinforced Brittle Matrix Composite Basic Problems', Mater.Sci.Eng.A 212, 1996, 75.10.1016/0921-5093(96)10196-9 ↗