journal article·2026-09

Sustainable synthesis of ZSM-23 from halloysite nanotubes via etching and seed-assisted nucleation for enhanced crystallinity and hierarchical porosity

Yamen Aljajan, Maria Rubtsova, Lubov Zatsepina, Ekaterina Smirnova, Valentin Stytsenko, Aleksandr Glotov

Publisher page

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Clay minerals and soil interactions · Mesoporous Materials and Catalysis · Zeolite Catalysis and Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (97)

Show source-provided references
1. Enlargement of halloysite clay nanotube lumen by selective etching of aluminum oxide10.1021/nn302328x ↗
2. Assessing the effect of acid and alkali treatment on a halloysite-based catalyst for dry reforming of methane10.1039/D3RA07990B ↗
3. Characterization of the porous structure of two naturally occurring materials through n2-adsorption (77 k) and gas chromatographic methods10.1016/S0927-7757(00)00698-1 ↗
4. Tailored HZSM-5 catalyst modification via phosphorus impregnation and mesopore introduction for selective catalytic conversion of polypropylene into light olefins10.1016/j.jaap.2024.106592 ↗
5. Albdiry · 2014
6. Hydroisomerization catalysts for High-Quality diesel fuel production10.3390/catal13101363 ↗
7. ZSM-48 zeolite catalysts for hydroisomerization of linear paraffins, diesel and sustainable aviation fuels production: synthesis, characterization, and application10.1080/01614940.2025.2495547 ↗
8. Isodewaxing of diesel fuels using bifunctional catalysts supported on MTT zeolites10.1134/S0965544125601516 ↗
9. Unveiling the potential of halloysite nanotubes: Insights into their synthesis, properties, and applications in nanocomposites10.1002/star.202400080 ↗
10. Synthesis of hierarchically porous ZSM-5 zeolite by self-assembly induced by aging in the absence of seeding-assistance10.1016/j.micromeso.2020.110296 ↗
11. Mesoporosity and acidity manipulation in ZSM-23 and their n -Hexadecane hydroisomerization performance10.1002/slct.202200839 ↗
12. Manipulation of hydroisomerization performance on Pt/ZSM-23 by introducing Al2O310.1016/S1872-5813(22)60034-3 ↗
13. Experimental methods in chemical engineering: specific surface area and pore size distribution measurements—BET, BJH, and DFT10.1002/cjce.23632 ↗
14. Precision engineering of zeolite catalysts for light hydrocarbon cracking to light olefins: advances and challenges10.1002/cctc.202500952 ↗
15. Nanomaterials: a review about halloysite nanotubes, properties, and application in the biological field
16. Halloysite nanotubes: Interfacial properties and applications in cultural heritage10.1021/acs.langmuir.0c00573 ↗
17. Seed-assisted synthesis of ZSM-23 zeolites in the absence of alkali metal ions10.1016/j.micromeso.2017.06.013 ↗
18. Effect of Extra-Framework Fe species in Pt/Fe/ZSM-23 catalysts on hydroisomerization performance of n -Hexadecane10.1021/acs.iecr.1c04065 ↗
19. Molecular views on mechanisms of brønsted acid-catalyzed reactions in zeolites10.1021/acs.chemrev.2c00896 ↗
20. Adsorption characteristics of nanoporous carbon–silica composites synthesized from graphite oxide by a mechanochemical intercalation method10.1016/j.jcis.2007.04.016 ↗
21. Precise control of the size of zeolite B-ZSM-5 based on seed surface crystallization10.1039/C6RA28030G ↗
22. Recent advances in the seed-directed synthesis of zeolites without addition of organic templates10.3390/nano12162873 ↗
23. Micro-Mesoporous catalyst based on dealuminated halloysite nanotubes for isomerization of c-8 aromatic fraction10.1134/S0965544121100030 ↗
24. Micro-mesoporous catalysts based on ZSM-5 zeolite synthesized from natural clay nanotubes: Preparation and application in the isomerization of c-8 aromatic fraction10.1016/j.cej.2022.139581 ↗
25. Halloysite clay nanotubes: innovative applications by smart systems10.1016/j.clay.2024.107319 ↗
26. The Johnson-Mehl- Avrami-Kohnogorov model: a brief review10.1007/BF03185527 ↗
27. Microstructure and properties of halloysite nanotubes and modification methods: a comprehensive review10.1016/j.clay.2024.107348 ↗
28. Characterization of selectively etched halloysite nanotubes by acid treatment10.1016/j.apsusc.2017.06.104 ↗
29. Isomerization of xylenes in the presence of Pt-Containing catalysts based on halloysite aluminosilicate nanotubes10.1134/S1070427218080141 ↗
30. A study of platinum catalysts based on ordered Al–МСМ-41 aluminosilicate and natural halloysite nanotubes in xylene isomerization10.1134/S0965544119110033 ↗
31. Mesoporous metal catalysts templated on clay nanotubes10.1246/bcsj.20180207 ↗
32. Morphological features of halloysite nanotubes as revealed by various microscopies10.1180/clm.2023.37 ↗
33. Determination of microporous structure of zeolites by t-plot method—State-of-the-art
34. Kinetics of silica oligomerization and nanocolloid formation as a function of pH and ionic strength at 25°C10.1016/j.gca.2004.06.038 ↗
35. Synthesis and characterization of pure phase zeolite 4A from coal fly ash10.1016/j.jclepro.2019.02.066 ↗
36. Self-assembly of halloysite nanotubes in water modulated via heterogeneous surface charge and transparent exopolymer particles10.1016/j.clay.2025.107775 ↗
37. Influence of selective acid-etching on functionality of halloysite-chitosan nanocontainers for sustained drug release10.1016/j.msec.2021.112029 ↗
38. A highly efficient catalytic c4 alkane cracking over zeolite ZSM-2310.1016/j.catcom.2005.02.002 ↗
39. Recent advances of halloysite nanotubes in biomedical applications
40. Combining USY and ZSM-23 in Pt/zeolite hydrocracking catalyst to produce diesel and lube base oil with improved cold flow properties10.1016/j.fuel.2023.128085 ↗
41. Synthesis and application of Pt-containing catalysts based on mordenite zeolite and natural halloysite nanotubes in the gas-phase isomerization of c-8 aromatic fraction10.1016/j.cej.2023.146597 ↗
42. Synergistic catalytic performance of Pt–Au bimetallic catalysts on high-crystallinity ZSM-23 zeolite for hexadecane hydroisomerization: metal–acid balance and enhanced isomerization selectivity10.1021/acs.inorgchem.4c01212 ↗
43. Mechanisms of light alkene oligomerization on metal-modified zeolites10.1021/acscatal.4c00552 ↗
44. Effect of seed amounts on the synthesis of zeolite ZSM-5 using coal bottom ash and rice husk as sources of silica and alumina by using seeding method10.4028/www.scientific.net/MSF.948.9 ↗
45. Why zeolites have so few seven-membered rings10.1021/jp504143r ↗
46. Influence of synthesis parameters on the crystallinity and Si/Al ratio of NaY zeolite synthesized from kaolin10.1007/s12182-010-0085-x ↗
47. Regulation of the Si/Al ratios and al distributions of zeolites and their impact on properties10.1039/D2SC06010H ↗
48. Synthesis of ZSM-5 zeolite nanosheets with tunable silanol nest contents across an ultra-wide pH range and their catalytic validation
49. Metal–acid intimacy and pore structure in bifunctional catalysts: impact on n -C16 hydroisomerization performance and product distribution
50. Halloysite clay nanotubes for catalytic conversion of biomass: synergy between computational modeling and experimental studies10.1021/acscatal.4c05907 ↗
51. Modulating acid site distribution in MTT channels for controllable hydroisomerization of long-chain n-alkanes10.1016/j.fuproc.2022.107605 ↗
52. Zeolite-X synthesized from halloysite nanotubes and its application in CO2 capture10.1016/j.jtice.2022.104281 ↗
53. Classical nucleation theory from a dynamical approach to nucleation10.1063/1.4811490 ↗
54. Recent advances in organotemplate-free synthesis of zeolites
55. Structural analysis of hierarchically organized zeolites10.1038/ncomms9633 ↗
56. Synthesis of ZSM-23 (MTT) zeolites with different crystal morphology and intergrowths: Effects on the catalytic performance in the conversion of methanol to hydrocarbons10.1039/C9CY01068H ↗
57. Sustainable porous heterogeneous catalysts for the conversion of biomass into renewable energy products10.1021/acssusresmgt.4c00190 ↗
58. Effect of Si/Al ratio in the faujasite structure on adsorption of methane and nitrogen: a molecular dynamics study10.1002/ceat.202000356 ↗
59. Proton adsorption selectivity of zeolites in aqueous media: effect of Si/Al ratio of zeolites10.3390/molecules191220468 ↗
60. Energy analysis of aluminosilicate zeolites with comprehensive ranges of framework topologies, chemical compositions, and aluminum distributions10.1021/jacs.6b01341 ↗
61. Hierarchical zeolite synthesis by alkaline treatment: advantages and applications10.3390/catal13020316 ↗
62. Role of zeolite acidity and Ni content in hexadecane hydroisomerization over Ni/ZSM-23 catalyst10.1021/acs.iecr.3c03574 ↗
63. Toward sustainability in zeolite manufacturing: an industry perspective10.3389/fchem.2022.1050363 ↗
64. A geopolymer route to micro- and meso-porous carbon10.1039/C9RA09698A ↗
65. Nucleation of porous crystals from Ion-Paired prenucleation clusters10.1021/acs.chemmater.2c00418 ↗
66. Zeolite catalysts with tunable hierarchy factor by Pore-Growth moderators10.1002/adfm.200901394 ↗
67. Synthesis of MFI-type framework from Philippine natural zeolite: effects of alkaline treatment on zeolite morphology and structure and its impact on MFI-type framework formation10.1557/s43579-025-00775-0 ↗
68. Classical nucleation theory for the crystallization kinetics in sheared liquids10.1103/PhysRevE.99.062801 ↗
69. Synthesis and investigation of catalysts supported on micro–mesoporous MFI zeolites in hydroisodewaxing of diesel fuels10.1134/S0965544125600936 ↗
70. Future perspectives of zeolites
71. Recent advances in sustainable synthesis of zeolites
72. Sustainable synthesis of zeolites10.1016/j.micromeso.2025.114017 ↗
73. Enhanced mass transport of one-dimensional zeolite MTT by secondary growth10.1021/jacsau.5c00645 ↗
74. Low-pressure hysteresis in adsorption: an artifact?10.1021/jp305358y ↗
75. Micro-Mesoporous catalyst based on natural aluminosilicate nanotubes and ZSM-5 zeolite for methanol conversion to hydrocarbons10.1134/S0965544121070082 ↗
76. Architectural design of core–shell nanotube systems based on aluminosilicate clay10.1039/D2NA00163B ↗
77. The effects of growth modifiers on the catalytic performance of hierarchical Pd/ZSM-23 bifunctional catalysts for n-hexadecane hydroisomerization10.1016/j.fuel.2023.128406 ↗
78. Silica dissolution catalyzed by NaOH: reaction kinetics and energy barriers simulated by quantum mechanical strategies10.2465/jmps.110909 ↗
79. Catalytic cracking of crude oil: mini review of catalyst formulations for enhanced selectivity to light olefins10.1021/acs.energyfuels.2c00567 ↗
80. Shape selectivity in the conversion of methanol to hydrocarbons: the catalytic performance of one-dimensional 10-ring zeolites: ZSM-22, ZSM-23, ZSM-48, and EU-110.1021/cs200517u ↗
81. Surface modified halloysite nanotubes: a flexible interface for biological, environmental and catalytic applications10.1016/j.cis.2018.09.001 ↗
82. Nucleation, growth, and seeding in zeolite synthesis, 2001
83. The synthesis of granular ZSM-23 zeolite with a high degree of crystallinity and a micro-meso-macroporous structure, and its use in the hydroisomerization of n-Hexadecane10.3390/nano14231897 ↗
84. What drives porosity in aluminosilicate zeolites?10.1039/D5CE00034C ↗
85. Towards a sustainable manufacture of hierarchical zeolites10.1002/cssc.201301313 ↗
86. Gram-scale ruthenium catalysts templated on halloysite nanotubes and MCM-41/halloysite composite for removal of aromatics from gasoline fraction10.1039/D3NJ01709E ↗
87. Selective production of light olefins over zeolite catalysts: Impacts of topology, acidity, and particle size10.1016/j.micromeso.2022.112353 ↗
88. High-efficiency palladium/halloysite nanotubes catalyst for toluene catalytic oxidation: characterization, performance and reaction mechanism10.1016/j.clay.2023.106842 ↗
89. The stability of halloysite nanotubes in acidic and alkaline aqueous suspensions10.1088/0957-4484/23/6/065705 ↗
90. Modification of ZSM-23 zeolite via vapor-phase transport method: reducing the length along the unidimensional channels for enhanced catalytic performances in methanol-to-hydrocarbons10.1016/j.micromeso.2024.113184 ↗
91. Recent advances in halloysite nanotube derived composites for water treatment10.1039/C5EN00149H ↗
92. Changes in structure, morphology, porosity, and surface activity of mesoporous halloysite nanotubes under heating10.1346/CCMN.2012.0600602 ↗
93. Properties and applications of halloysite nanotubes: recent research advances and future prospects10.1016/j.clay.2015.05.001 ↗
94. Effects of acid treatment on the physico-chemical and pore characteristics of halloysite10.1016/j.colsurfa.2011.12.067 ↗
95. On understanding the sequential post-synthetic microwave-assisted dealumination and alkaline treatment of y zeolite10.1016/j.micromeso.2022.111736 ↗
96. Effects of concentration on the alkali-treatment of ZSM-5 zeolite: a study on dividing points10.1007/s10853-010-4593-2 ↗
97. Catalysts and shape selective catalysis in the methanol-to-olefin (MTO) reaction10.1016/j.jcat.2021.01.027 ↗