Using Agrawal integral equation to study the pyrolysis kinetics of exfoliated montmorillonite from a polyhedral oligomeric silsesquioxane surfactant and click chemistry
Source abstract
Abstract
Abstract In this study, the exfoliated montmorillonite was prepared through the click chemistry of a propargyl-containing intercalator with singly or multiply azido-functionalized polyhedral oligomeric silsesquioxane nanoparticles. Thermogravimetric analyses revealed that the pyrolysis kinetics had a close relationship to the layered structures, exfoliated structures, and cage-like molecules of polyhedral oligomeric silsesquioxane nanoparticles. The pyrolysis of exfoliated montmorillonite had a mechanism function of Avrami–Erofeev equation, and the kinetic compensation effect equation revealed the pyrolysis.
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Research context
OpenAlex topics: Polymer Nanocomposites and Properties · Fiber-reinforced polymer composites · Polymer crystallization and properties
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