journal article·2025-03Open access

Combined effect of 2D nature and structural glass behaviour and true magnetic contribution to the low-temperature heat capacity of layered double hydroxides

V. Tkáč, Yu.G. Pashkevich, E.L. Fertman, R. Tarasenko, E. Čižmár, A. Feher, A.V. Fedorchenko, C.S. Neves, D.E.L. Vieira, A.N. Salak

Abstract

Heat capacity of cobalt-aluminium and magnesium-aluminium layered double hydroxides (LDH) with the divalent-to-trivalent cations ratio ( n ) of 2 and 3, and intercalated with NO 3 − , CO 3 2− and OH − , was measured as a function of temperature between 2 and 100 K. Magnetic contribution to the heat capacity ( C mag ) of Co n Al LDH was extracted from comparison of the C ( T ) dependences with the respective reduced dependences of their non-magnetic counterparts, Mg n Al LDH. At the lowest measured temperatures, the magnetic contribution to the heat capacity ( C mag ) of Co-containing LDH was found to be almost two orders of magnitude bigger than their lattice contribution. In a zero magnetic field, the low-temperature C mag of Co 2 Al LDH was measured to be proportional to T 2.6 , while for Co 3 Al LDH, C mag ∼ T 2 was observed. An application of an external magnetic field was revealed to converge these dependences to C mag ∼ T 3 in compounds with both n = 2 and 3. However, the conversion in Co 2 Al LDH occurred at lower values of external magnetic field (50 kOe) than that in Co 3 Al LDH (90 kOe). It was revealed from the C ( T ) behaviour of the non-magnetic LDH at the lowest measured temperatures that they possess the features typical for both a 2D solid and a structural glass. The reduced C ( T )/ T 3 heat capacity of Mg n Al LDH intercalated with nitrate was found to demonstrate a so-called boson peak, which is a manifestation of a glassy state. The observed low-temperature structural glassy state in LDH was associated with the disorder of the intercalated species. • Magnetic contribution ( C mag ) is the dominant contribution to the heat capacity of Co Al LDH at low T . • Low- T heat capacity of LDH demonstrates the features typical for both a 2D solid and a structural glass. • Boson peak in the lattice heat capacity versus T is an indicator of the interlayer disorder in LDH. • Extracted magnetic contribution to C ( T ) reflects intrinsic differences in magnetic nature of LDH.
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Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Aerogels and thermal insulation · Thermal Expansion and Ionic Conductivity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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