Synthetic silico-metallic mineral particles SSMMP: A new option for CO2 capture and CO2/N2 separation from post-combustion technology
Source abstract
Abstract
A new class of solid adsorbents based on pristine and ionic liquid (IL) functionalized synthetic silico-metallic mineral particles (SSMMP) for CO 2 capture and CO 2/N 2 separation are presented. Pristine particles were submitted to hydrothermal treatment producing synthetic talc. Samples were characterized by thermal analyses (TGA), specific surface area measurements (BET), infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction(XRD), NMR spectroscopy, and scanning electron microscopy (SEM). Values for specific surface areas varied from 5 m 2/g for a sample with high IL content to 354 m 2 /g for pristine SSMMP. Samples presented distinct morphology as well as sorption capacities. IL and its increased concentration in the samples negatively influenced CO 2 sorption capacity but played an essential role in CO 2/N 2 selectivity. The best results were obtained from CO 2 sorption values for SSMMP-M1 without IL of 2.07 mmol CO 2/g at 1 bar and 4.93 mmol CO 2/g at 30 bar. In addition, a selectivity of 16.94 for the CO 2/N 2 mixture was achieved for SSMMP-5%-Im(nBu)-I sample. SSMMP particles are easy to obtain with low-cost starting materials used in the low energy and CO 2-free emission synthesis process. The sorption/desorption cycles proved the stability for both pristine and IL functionalized samples.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon Dioxide Capture Technologies · Membrane Separation and Gas Transport · Phase Equilibria and Thermodynamics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (88)
Show source-provided references
1. Rationalizing the role of the anion in CO2 capture and conversion using imidazolium-based ionic liquid modified mesoporous silica
2. Atilhan · 2016 · 61 · 2749
3. Experimental evaluation and thermodynamic modeling of hydrate selectivity in separation of CO2 and CH410.1016/j.cherd.2016.05.005 ↗
4. Hybrid Alkoxysilane-Functionalized Urethane-Imide-based Poly (ionic liquids) as a New Platform for Carbon Dioxide Capture10.1021/acs.energyfuels.7b02027 ↗
5. Cellulose based poly(ionic liquids): Tuning cation-anion interaction to improve carbon dioxide sorption10.1016/j.fuel.2017.09.057 ↗
6. Interfacial-chemistry mediated behavior of colloidal talc dispersions10.1016/j.jcis.2004.09.048 ↗
7. Adsorption of gases in Multimolecular Layers10.1021/ja01269a023 ↗
8. Functionalization of synthetic talc-like phyllosilicates by alkoxyorganosilane grafting10.1039/c0jm01276a ↗
9. Activated carbons and amine-modified materials for carbon dioxide capture -- A review10.1007/s11783-013-0510-7 ↗
10. Pressure-induced structural transitions of a room temperature ionic liquid — 1- ethyl-3-methylimidazolium chloride Pressure-induced structural transitions of a room temperature HPSTAR ionic liquid — 1-ethyl-3-methylimidazolium chloride10.1063/1.4977044 ↗
11. Physicochemical studies on precipitated magnesium silicates
12. Magnesium silicates – adsorbents of organic compounds
13. Adsorptive properties of synthetic magnesium silicates
14. Synthetic talc and talc-like structures: preparation, features and applications10.1002/chem.201702763 ↗
15. Multifunctional heterogeneous catalysts highly performing in the conversion of carbon dioxide: mechanistic insights10.1016/j.jcou.2019.12.008 ↗
16. Angewandte solvation of carbon dioxide in [ C 4 mim ][ BF 4 ] and [ C 4 mim ][ PF 6 ] ionic liquids revealed by high-pressure NMR spectroscopy **10.1002/anie.201305630 ↗
17. Synthetic silico-metallic mineral particles (SSMMP) as nanofillers: comparing the effect of different hydrothermal treatments on the PU/SSMMP nanocomposites properties10.1007/s00289-015-1449-6 ↗
18. Comparing different synthetic talc as fillers for polyurethane nanocomposites10.1002/masy.201500141 ↗
19. Dietemann · 2012
20. Development of solid adsorbent for carbon dioxide capture from flue gas10.1016/j.seppur.2013.02.027 ↗
21. Designing silica xerogels containing RTIL for CO2 capture and CO2/CH4 separation: Influence of ILs anion, cation and cation side alkyl chain length and ramification10.1016/j.jenvman.2020.110340 ↗
22. Preparation of zeolite NaA for CO2 capture from nickel laterite residue10.1007/s12613-014-0976-8 ↗
23. Waste derived MCMRH- supported IL for CO2/CH4 separation10.1016/j.jngse.2018.03.028 ↗
24. Dumas · 2013
25. Method for preparing a hydrogel comprising silico-metallic mineral particles and hydrogel
26. Synthetic talc advances: coming closer to nature, added value, and industrial requirements10.1016/j.clay.2013.09.006 ↗
27. Phyllosilicates synthesis: a way of accessing edges contributions in NMR and FTIR spectroscopies. Example of synthetic talc10.1007/s00269-013-0577-5 ↗
28. Method for preparing a composition comprising functionalised silico/germano-metal particles and composition obtained
29. Method for preparing a composition comprising functionalised mineral particles and corresponding composition
30. Dumas · 2015 · 15 · 5451
31. Measurement, standards, and data needs for CO2 capture materials: a critical review10.1021/es402622q ↗
32. Strategies for mitigation of climate change: a review10.1007/s10311-020-01059-w ↗
33. Hydrothermal syntheses and characterisation of alkylammonium phyllosilicates containing CSiO3 and SiO4 units10.1016/j.clay.2005.01.005 ↗
34. Enhanced adsorption of carbon dioxide on surface-modified mesoporous silica-supported tetraethylenepentamine: Role of surface chemical structure10.1016/j.micromeso.2015.05.037 ↗
35. Synthesis of new lamellar inorganic-organic talc-like hybrids10.1039/B713004J ↗
36. Thermal degradation of aqueous DEEA solution at stripper conditions for post-combustion CO2 capture10.1016/j.ces.2015.02.033 ↗
37. Revisited vibrational assignments of imidazolium-based ionic liquids10.1002/jrs.2754 ↗
38. Carbon dioxide adsorption by zinc-functionalized ionic liquid impregnated into bio-templated mesoporous silica beads10.1016/j.cej.2015.08.006 ↗
39. Hasib-ur-rahman · 2010 · 49 · 313
40. Heats of adsorption and adsorption heterogeneity for methane, ethane, and carbon dioxide in MCM-4110.1021/la052237k ↗
41. Anchoring a halogenated amine on the surface of a microporous activated carbon for carbon dioxide capture10.1016/j.jtice.2013.01.014 ↗
42. Adsorption performance of MCM-41 impregnated with amine for CO2 removal10.1016/j.fuproc.2012.08.017 ↗
43. [BMIM][PF6] incorporation doubles CO2 selectivity of ZIF-8: elucidation of interactions and their consequences on performance10.1021/acsami.6b11087 ↗
44. Kloprogge · 2017
45. Li-LSX-zeolite evaluation for post-combustion CO2 capture10.1016/j.cej.2018.10.063 ↗
46. A new aerogel based CO2 adsorbent developed using a simple sol-gel method along with supercritical drying10.1039/C4CC06424K ↗
47. Design considerations for measurement of gas sorption in polymers by pressure decay10.1002/pol.1976.180141014 ↗
48. H2O-prompted CO2capture on metal silicates: in situ generated from SBA-1510.1039/D0RA02736G ↗
49. CO 2 capture using particulate silica aerogel immobilized with tetraethylenepentamine10.1016/j.micromeso.2013.02.052 ↗
50. Structural properties and reactivities of amino-modi fi ed silica fume solid sorbents for low-temperature CO 2 capture10.1016/j.powtec.2013.03.022 ↗
51. Amine tethered pore-expanded MCM-41: a promising adsorbent for CO2 capture10.1016/j.cej.2016.09.103 ↗
52. Study of the interaction between silica surfaces and the carbon dioxide molecule10.1021/jp107754g ↗
53. New amino-inorganic hybrids from talc silylation and copper adsorption properties
54. Functionalization with amine-containing organosilane of mesoporous silica MCM-41 and MCM-48 obtained at room temperature10.1016/j.ceramint.2014.02.051 ↗
55. Incorporation of acetate-based ionic liquids into a zeolitic imidazolate framework (ZIF-8) as efficient sorbents for carbon dioxide capture10.1016/j.cej.2017.10.104 ↗
56. Imidazolium based ionic liquids confined into mesoporous silica MCM-41 and SBA-15 for carbon dioxide capture10.1016/j.micromeso.2019.109916 ↗
57. Nanosilica extraction from processed agricultural residue using green technology10.1016/j.jclepro.2016.11.142 ↗
58. Improving carbon dioxide solubility in ionic liquids10.1021/jp071897q ↗
59. Review: Common attributes of hydraulically fractured oil and gas production and CO2 geological sequestration10.1002/ghg.1300 ↗
60. A model-based approach for the evaluation of new zeolite 13X-based adsorbents for the efficient post-combustion CO2 capture using P/VSA processes10.1016/j.cherd.2017.06.016 ↗
61. High pressure adsorption of CO 2 on MCM-41 grafted with quaternary ammonium ionic liquids
62. Densities and low pressure solubilities of carbon dioxide in five promising ionic liquids10.1039/c3ra46339g ↗
63. Synthesis chemistry of metal-organic frameworks for CO2 capture and conversion for sustainable energy future10.1016/j.rser.2018.04.073 ↗
64. Textural properties determined CO2 capture of tetraethylenepentamine loaded SiO2 nanowires from Α-sepiolite10.1016/j.cej.2017.12.109 ↗
65. Vibrational spectroscopy of ionic liquids10.1021/acs.chemrev.6b00461 ↗
66. Imidazolium-based ionic liquids impregnated in silica and alumina supports for CO2 capture10.1590/1980-5373-mr-2018-0810 ↗
67. The influence of Ni/Mg content of synthetic Mg/Ni talc on mechanical and thermal properties of waterborne polyurethane nanocomposites10.1007/s42452-020-2852-7 ↗
68. State-of-the-art of CO 2 capture with ionic liquids10.1021/ie3003705 ↗
69. Modeling the adsorptive selectivity of carbon nanotubes for effective separation of CO2/N2 mixtures10.1007/s00894-010-0810-9 ↗
70. Silica surface features and their role in the adsorption of biomolecules: Computational modeling and experiments10.1021/cr3003054 ↗
71. Rojas · 2017
72. Carbon dioxide capturing technologies: a review focusing on metal organic framework materials (MOFs)
73. CO 2 adsorption on branched polyethyleneimine-impregnated mesoporous silica SBA-1510.1016/j.apsusc.2009.12.070 ↗
74. Infrared spectroscopy in clay science
75. Sexton · 2011 · 50 · 667
76. Nanoparticles as an efficient catalyst for the preparation of propargylamines
77. Cation À Anion À CO 2 Interactions in Imidazolium-based ionic liquid sorbents10.1002/cphc.201800751 ↗
78. Raman and infrared spectra and ab initio calculations of C 2–4 MIM imidazolium hexafluorophosphate ionic liquids10.1021/jp040199s ↗
79. Development of hybrid amine-functionalized MCM-41 sorbents for CO2capture10.1016/j.cej.2014.08.107 ↗
80. A review of post-combustion CO2 Capture technologies from coal-fired power plants10.1016/j.egypro.2017.03.1209 ↗
81. CO2 absorption with aqueous tertiary amine solutions: equilibrium solubility and thermodynamic modeling10.1016/j.jct.2018.03.020 ↗
82. Recent progress and remaining challenges in post-combustion CO2 capture using metal-organic frameworks (MOFs)10.1016/j.pecs.2020.100849 ↗
83. Water effects on postcombustion Co2 capture in Mg-MOF-7410.1021/jp311118x ↗
84. A review of CO2 capture by absorption and adsorption10.4209/aaqr.2012.05.0132 ↗
85. Improvement of CO2 adsorption on ZIF-8 crystals modified by enhancing basicity of surface10.1016/j.ces.2011.06.051 ↗
86. CO2 capture over molecular basket sorbents: Effects of SiO2 supports and PEG additive10.1016/j.jechem.2017.09.002 ↗
87. Results in Materials Exfoliated vermiculite nanosheets supporting tetraethylenepentamine for CO 2 capture10.1016/j.rinma.2020.100102 ↗
88. Effect of immobilization methods and the pore structure on CO2 separation performance in silica-supported ionic liquids10.1016/j.micromeso.2017.10.035 ↗