journal article·2007-06

Recovery of anthocyanins from red cabbage using sandy porous medium enriched with clay

Toni J. Lopes, Mara G.N. Quadri, Marintho B. Quadri

Applied Clay Science· Volume 37· Issue 1-2
Publisher page

Abstract

The present work studied the viability of the smectitic clay Tonsil Terrana 580 FF, used in the partial purification of anthocyanin from red cabbage, and the possible mechanisms involved in the column adsorption process. The performed essays studied the influence of the initial concentration and interstitial velocity on the adsorbed and desorbed mass of anthocyanins. Experimental design showed that adsorption is an instantaneous process, while dye fixation on clay depends on the contact time. Recovery of anthocyanins was compared to the results obtained when resin was used in chromatography and was used to partially purify dyes (Amberlite XAD-7). A model taking into account the dye transport processes, adsorption and fixation of the dye was developed. Recovery of anthocyanins adsorbed on clay was 21% higher than with Amberlite. Tonsil Terrana clay showed to be a good adsorbent for the proposed application.
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Research context

OpenAlex topics: Fermentation and Sensory Analysis · Phytochemicals and Antioxidant Activities · Biochemical Analysis and Sensing Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. Chromatographic separation of anthocyanins in Cowberry (Lingonberry) Vaccinium vites-idaea L10.1111/j.1365-2621.1985.tb10449.x ↗
2. Anvisa – Agência Nacional de Vigilância Sanitária · 2006
3. Anthocyanin pigments: comparison of extract stability10.1111/j.1365-2621.1994.tb14681.x ↗
4. Dead-end pore volume and dispersion in porous media10.2118/647-PA ↗
5. Partial purification of anthocyanins from Brassica oleracea (red cabbage)10.1081/SS-200036539 ↗
6. A mathematical model for dispersion in the direction flow in porous media10.2118/493-PA ↗
7. Food dyes: anthocyanins10.1080/10408398909527503 ↗
8. Adsorption of methylene blue on kaolinite10.1016/S0169-1317(01)00081-3 ↗
9. Determination of adsorptive properties of clay/water system: methylene blue sorption10.1016/j.jcis.2003.09.004 ↗
10. The natural distribution in angiosperms of anthocyanins acylated with aliphatic dicarboxilic acids10.1016/S0031-9422(00)81168-1 ↗
11. Anthocyanins and betalains
12. To reduce color losses in strawberry preserve
13. Solid-phase extraction (SPE) – a comparison of 16 materials for the purification of anthocyanins from Aronia melanocarpa var Nero10.1002/(SICI)1097-0010(199811)78:3<435::AID-JSFA139>3.0.CO;2-Q ↗
14. Influence of pigment composition on skin color in a wide range of fruit and vegetables10.21273/JASHS.122.4.594 ↗
15. Purification of commercial grape pigment10.1111/j.1365-2621.1980.tb02600.x ↗
16. Adsorption of acid dye from water onto pristine and acid-activated clays in fixed beds10.1016/j.jhazmat.2004.06.028 ↗
17. Lopes, T.J. Adsorção de Antocianinas do repolho roxo em argilas. Universidade Federal de Santa Catarina, Florianópolis, Brazil; 2002, Masters Thesis.
18. Lopes, T.J. Desenvolvimento de estratégias pra aperfeiçoar a utilização de argilas adsorventes em processos industriais. Universidade Federal de Santa Catarina, Florianópolis, Brazil; 2006, Doctor Thesis.
19. Mazza · 1993
20. MERCOSUL/GMC/RES. N° 51/00. Regulamento Técnico Mercosul Atribuição de Aditivos e seus Limites Máximos para a Categoria de Alimentos 21 – Preparações Culinárias Industriais. Available at: http://www.mercosul.org.uy– Accessed in: August, 2001.
21. Antioxidant effect of anthocyanin on enzymatic and non-enzymatic lipid peroxidation10.1054/plef.1998.0001 ↗
22. Comparative cost of colour removal from textile effluents using natural adsorbents10.1002/jctb.280500210 ↗
23. Antioxidant activity of nasunin, an anthocyanin in eggplant peels10.1016/S0300-483X(00)00202-X ↗
24. Novy Quadri, M.G. Transferts de solutés dans lês sols satures et non satures: application au pentachorophénol, Universite Joseph Fourier–Grenoble I, Grenoble–France 1993. Doctor Thesis.
25. Patankar · 1980
26. A kinetic and equilibrium study of competitive adsorption between atrazine and Congo red dye on activated carbon: the importance of pore size distribution10.1016/S0008-6223(00)00078-6 ↗
27. Contribution à l'étude des désplacements des fluides miscibles dans un milieu poreux
28. Anthocyanin pigments of royal okanogan huckleberry juice10.1111/j.1365-2621.1995.tb05675.x ↗
29. Quadri, M.B. Contribution of irreversible fixation to the stagnant volumes model. Non published, 2001. E-mail: m-quadri@enq.ufsc.br.
30. Wine, alcohol, platelets, and the French paradox for coronary heart disease10.1016/0140-6736(92)91277-F ↗
31. Rohm and Haas Company. Technical Bulletin. Information captured at Internet on May, 12, 2004. www.rohmhaas.com.
32. Correlations between anthocyanins type, pollinator and flower color in the Labiatae10.1016/0031-9422(92)83437-4 ↗
33. Transient mass-transport in the presence of non-linear physicochemical interaction laws: progressive modeling and appropriate experimental procedures10.1016/0016-7061(86)90010-8 ↗
34. Modeling the nonlinear transport of linearly interacting solutes in porous media: a review10.1029/91WR01034 ↗
35. Experimental study and modeling of basic dye sorption by diatomaceous clay10.1016/S0169-1317(03)00154-6 ↗
36. SÜD CHEMIE DO BRASIL · 2004
37. Militated anthocyanins in Malacca Malonylmalvin from Malva sylvestris10.1016/0031-9422(89)80040-8 ↗
38. Acylated cyanidin glycosides in the orange-red flowers of Sophoronitis coccinea10.1016/S0031-9422(98)00182-4 ↗
39. Anthocyanins—occurrence, extraction and chemistry10.1016/0308-8146(80)90065-5 ↗
40. Anthocyanins pigments of tulips10.1016/S0031-9422(99)00328-3 ↗
41. Adsorption of basic dyes in aqueous solution by clay adsorbent from regenerated bleaching earth10.1016/j.clay.2004.10.004 ↗
42. Mass transfer studies in sorbing porous media. Analytical solutions10.2136/sssaj1976.03615995004000040011x ↗