Synthesis and characterization of clay composites with Zeolitic imidazolate framework for application as an herbicide adsorbent
Source abstract
Abstract
Glyphosate is one of the most widely used herbicides globally; however, its extensive application is linked to environmental contamination and the onset of various human diseases. Therefore, developing effective strategies to remove glyphosate (GLY) from aqueous effluents in crucial. Zeolitic imidazole frameworks (ZIFs), a subclass of metal-organic framework (MOF) formed with imidazole ligands, closely resemble natural zeolites in structure. Their unique textural properties make them suitable candidates as adsorbents. In this study, a Cu (II)-based ZIF was synthesized in the presence of clay minerals, specifically palygorskite (PAL) and Na + montmorillonite (CloNa), and its adsorption efficiency for GLY was evaluated. The CloNa/Cu-MOF hybrid demonstrated the highest GLY adsorption efficiency among the materials tested, reaching a value of 63 mg g −1 at pH 4, 25 °C, and an initial GLY concentration of 500 mg L −1. This high efficiency was attributed to the improved textural properties, thermal stability, and stability in aqueous media of CloNa/Cu-MOF hybrid. GLY adsorption followed the pseudo-second-order kinetic model, and the isotherm study revealed a favorable adsorption profile, with the best fit to the Langmuir model. Q max values ranged from 20.04 to 277.77 mg g −1 for the different studied temperatures. The thermodynamic analysis confirmed that the adsorption process is endothermic and occurs spontaneously.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Analytical chemistry methods development · Adsorption and biosorption for pollutant removal · Pesticide and Herbicide Environmental Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (77)
Show source-provided references
1. Lead in drinking water: Adsorption method and role of zeolitic imidazole frameworks for its remediation: a review10.1016/j.jclepro.2022.133010 ↗
2. Phosphate adsorption by metal organic framework: Insights from a systematic review, meta-analysis, and predictive modelling with artificial neural networks10.1016/j.chemosphere.2023.139674 ↗
3. Adsorption of commercial glyphosate by MOF-808: a new ZrMOF for water purification10.1007/s10450-024-00451-0 ↗
4. Glyphosate: environmental contamination, toxicity and potential risks to human health via food contamination10.1007/s11356-016-7425-3 ↗
5. Recent progress in adsorptive removal of water pollutants by metal-organic frameworks
6. Impact of the glyphosate-based commercial herbicide, its components, and its metabolite AMPA on non-target aquatic organisms10.1016/j.mrgentox.2019.05.002 ↗
7. A Fourier transform infrared spectroscopic study of Mg-rich, Mg-poor and acid leached palygorskites. Spectrochem10.1016/j.saa.2006.02.053 ↗
8. Recent advancement of surface modification techniques of 2-D nanomaterials10.1016/j.mseb.2023.116817 ↗
9. Recent advances on ZIF-8 composites for adsorption and photocatalytic wastewater pollutant removal: fabrication, applications and perspective10.1016/j.ccr.2021.213985 ↗
10. Towards the use of metal-organic frameworks for water reuse: a review of the recent advances in the field of organic pollutants removal and degradation and next steps in the field10.1039/C5TA05440K ↗
11. Two-dimensional copper-based metal-organic frameworks nano-sheets composites: One-step synthesis and highly efficient U(VI) immobilization10.1016/j.jhazmat.2019.03.119 ↗
12. Glyphosate on plant mineral nutrition crop rhizosphere microbiota, and plant disease in glyphosate-resistant crops10.1021/jf302436u ↗
13. Sepiolite-metal organic framework-Iron oxide catalyst for degradation of Rhodamine B using Fenton-like process10.1016/j.jtice.2023.105181 ↗
14. Technologies employed in the treatment of water contaminated with glyphosate: a review10.3390/molecules25235550 ↗
15. Hybridization of nanoclay with a chromium-based metal-organic framework for boosting adsorption of organic dyes from wastewater
16. Comparisons of glyphosate adsorption properties of different functional Cr-based metal-organic frameworks10.1002/jssc.201700886 ↗
17. A new photoactive crystalline highly porous titanium (IV) dicarboxylate10.1021/ja903726m ↗
18. Health effects of herbicides and its current removal strategies
19. A determination of thermodynamics parameters from Langmuir isotherm constant revisited10.1016/j.molliq.2016.11.058 ↗
20. Studies in adsorption. Part XI* a system of classification of solution adsorption isotherms, and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids
21. High-temperature water adsorption isotherms and ambient temperature water diffusion rates on water harvesting metal–organic frameworks
22. Influence of metal ions on glyphosate detection by FMOC-Cl10.1007/s10661-019-7387-2 ↗
23. Adsorption kinetic model: Physical meanings, applications and solving methods
24. Efficient removal of glyphosate from aqueous solution by adsorption on Mg-Al-Layered oxides: thermodynamic kinetic and mechanistic investigation10.1007/s11356-022-21703-y ↗
25. Insights into mathematical characteristics of adsorption models and physical meaning of corresponding parameter10.1016/j.molliq.2018.01.073 ↗
26. Simultaneous adsorption of aniline and Cr(VI) ion by activated carbon/chitosan composite
27. Ecotoxicology of glyphosate and recent advances in its mitigation by adsorption10.1007/s11356-020-11521-5 ↗
28. Low-cost magnetic clay derivants from Palygorskite/MIL101(Fe) for high-performance adsorption-photocatalysis10.1016/j.clay.2022.106427 ↗
29. Pesticides Curbing Soil Fertility effect of complexation of free metal ions10.3389/fchem.2017.00043 ↗
30. Glyphosate adsorption on montmorillonite: an experimental and theoretical study of surface complexes10.1016/j.clay.2010.07.018 ↗
31. Crystallographic and compositional dependence of thermodynamic stability of [Co(II), Cu(II), and Zn(II)] in 2-methylimidazole-containing zeolitic imidazolate frameworks10.1021/acs.chemmater.3c01464 ↗
32. Metal centers and organic ligands determine electrochemistry of metal-organic frameworks
33. A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability10.1021/ja8057953 ↗
34. Adsorption behavior and adsorption mechanism of glyphosate in water by amino-MIL-101(Fe)
35. Nanoclays and mineral derivates applied to pesticides water remediation10.1016/j.jconhyd.2023.104264 ↗
36. Investigation of synthesized planar Cu-MOF and spherical Ni-MOF nanofillers for improving the anti-corrosion performance of epoxy coatings
37. Water-stable nanoscale zirconium-based metal–organic frameworks for the effective removal of glyphosate from aqueous media
38. Grafting of organophilic silane in the interlayer space of acid-treated smectite: application to the direct electrochemical detection of glyphosate10.1016/j.clay.2020.105513 ↗
39. A comprehensive review on the adsorption of heavy metals by zeolite imidazole framework (ZIF-8) based nanocomposite in water10.1016/j.cej.2022.136320 ↗
40. Glyphosate adsorption from water using hierarchically porous metal-organic frameworks10.1002/adfm.202213862 ↗
41. Recent advances in application of metal-organic frameworks (MOFs) as absorbent and catalyst in removal of persistent organic pollutants (POPs)10.1016/j.jhazmat.2022.130127 ↗
42. Highly efficient and low-cost clay-based adsorbent for glyphosate removal from contaminated water10.1002/ceat.202100437 ↗
43. On the adsorption of neodymium species from aqueous solution by beneficiated palygorskite10.1016/j.mineng.2023.108029 ↗
44. Effect of mechanical activation of montmorillonite on the intercalation efficiency of polyhydroxyaluminum cations in the formation of pillar structure
45. Water-stable nanoscale zirconium-based metal-organic frameworks for the effective removal of glyphosate from aqueous media10.1021/acsomega.8b00921 ↗
46. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks10.1073/pnas.0602439103 ↗
47. Facile modification of montmorillonite by intercalation and grafting: the study of the binding mechanisms of a quaternary alkylammonium surfactant10.1016/j.clay.2020.105738 ↗
48. Adsorbents for glyphosate removal in contaminated waters: a review10.1007/s10311-020-01108-4 ↗
49. CuNCs modified with dual-ligand to achieve fluorescence visualization detection of tin (IV)10.1016/j.microc.2022.108086 ↗
50. Temperature-dependent adsorption behavior of organic pollutants on metal–organic frameworks: Shift from heterogeneous to homogeneous binding sites
51. Utilization of multi-metal laden spent biosorvent for removal of glyphosate herbicide from aqueous solution and its mechanism elucidation10.1016/j.cej.2018.12.163 ↗
52. Enhanced glyphosate removal by montmorillonite in the presence of Fe(III)10.1021/ie502773j ↗
53. Adsorption of glyphosate by palygorskite10.1590/1980-5373-mr-2022-0335 ↗
54. Glyphosate, pathways to modern diseases III: manganese, neurological diseases, and associated pathologies10.4103/2152-7806.153876 ↗
55. Multifunctional 2D hemin-bridged MOF for the efficient removal and dual-mode detection of organophosphorus pesticides10.1007/s00604-024-06398-x ↗
56. Uranium (VI) adsorption from carbonate solutions using cetyltrimethylammonium bromide modified purified-bentonite-MOF composite10.1016/j.clay.2023.106986 ↗
57. Reporting physisorption data for gas/solid systems. With special reference to the determination of surface area and porosity10.1351/pac198254112201 ↗
58. Copper-based metal-organic frameworks (MOFs) as an emerging catalytic framework for click chemistry10.3390/catal13010130 ↗
59. Highly efficient removal of glyphosate from water by hierarchical-pore UiO-66: selectivity and effects of natural water particles
60. Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: a critical review10.1016/j.watres.2017.04.014 ↗
61. FTIR study of glyphosate- copper complex10.1021/jf010988w ↗
62. Environmental and health effects of the herbicide glyphosate10.1016/j.scitotenv.2017.10.309 ↗
63. Synthesis of ZIF-8/Fly Ash Composite for Adsorption of Cu2+, Zn2+ and Ni2+ from Aqueous Solutions10.3390/ma13010214 ↗
64. Interface engineering of metal organic framework on graphene oxide with enhanced adsorption capacity for organophosphorus pesticides10.1016/j.cej.2016.12.041 ↗
65. Wang · 2009
66. Adsorption and detoxification of glyphosate and aminomethylphosphonic acid by montimorillonite clays10.1007/s11356-022-22927-8 ↗
67. Modified attapulgite for phosphorus removal from glyphosate by-product salt solution10.5004/dwt.2022.28258 ↗
68. Experimentally validated ab initio crystal structure prediction of novel metal-organic framework materials10.1021/jacs.2c12095 ↗
69. Magnetic MnFe2O4-graphene hybrid composite for efficient removal of glyphosate water10.1016/j.cej.2016.03.051 ↗
70. FTIR spectroscopy study of the structure changes of palygorskite under heating. Spectrochem10.1016/j.saa.2012.07.085 ↗
71. Interface engineering of metal organic framework on graphene oxide with enhanced adsorption capacity for organophosphorus pesticide10.1016/j.cej.2016.12.041 ↗
72. The simultaneous detection and removal of organophosphorus pesticides by a novel Zr-MOF based smart adsorbent10.1039/C7TA08399H ↗
73. One-pot facile synthesis of CuNCs/RGO nanocomposite for the sensitive detection of heparin in human serum samples10.1016/j.talanta.2020.120838 ↗
74. Insights into to glyphosate removal efficiency by using magnetic powder activated carbon composite10.1016/j.seppur.2020.117662 ↗
75. Application of a novel hybrid MIL-53(Al)@rice husk for the adsorption of glyphosate in water: characteristics and mechanism of the process10.1016/j.chemosphere.2023.138457 ↗
76. In situ synthesis of core–shell ZIF-8@modified sepiolite hybrids for multi-scale construction of epoxy composites with improved low-dielectric properties and thermal stability10.1007/s10854-020-03248-3 ↗
77. Influence of the interaction between surfactants and sepiolite on the rheological properties and thermal stability of organo-sepiolite in oil-based drilling fluids10.1016/j.micromeso.2018.06.017 ↗