Harnessing organoclays: Advancements and perspectives in cosmetics and personal care products
Source abstract
Abstract
The use of clay minerals for curative, decorative or protective purposes is old as mankind. Advancements in the design and production of modified clays have enhanced their applications. “Organoclays” are nanocomposite materials formed by the association of clays with cationic surfactants through an intercalation process. Consequently, organoclays are dispersible in non-aqueous environments, therefore expanding their versatility. This review focuses on the cosmetic and personal care field, where organoclays can act as functional ingredients on formulations and packaging. Organoclays can be found in make-up and skincare products, with a particular presence in sunscreens. Although the current scientific literature on cosmetic packaging and organoclays is scarce, their usefulness in food packaging could be extended to cosmetics and personal care products. This extension may bring innovative properties such as tailored polymer degradation rates and improved color pay-off. The chemical association of different clay minerals allows the creation of cutting-edge ingredients with synergistic properties. Their usefulness as polymer functional ingredients is already being exploited to produce sustainable, ecofriendly packaging. Along the same line, future research efforts could also revolve around eco-friendly, non-contaminant biosurfactants for new organoclays' synthesis.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Therapeutic Uses of Natural Elements
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Styrene monomer migration from polystyrene based food packaging nanocomposite: effect of clay and ZnO nanoparticles10.1016/j.fct.2019.04.019 ↗
2. Aspectos farmacéuticos de peloides de empleo cosmético y dermatológico
3. Nail cosmetics: Handle of Skin Care
4. On the impact of intermolecular interactions between the quaternary ammonium ions on interlayer spacing of quat-intercalated montmorillonite: a molecular mechanics and ab-initio study10.1016/j.clay.2014.04.035 ↗
5. Barel · 2009
6. Antiperspirant composition
7. Investigation of the effect of titanium dioxide and clay grafted with glycidyl methacrylate by gamma radiation on the properties of EVA flexible films10.1016/j.radphyschem.2018.08.022 ↗
8. Self-assembly of organic molecules on montmorillonite10.1016/j.clay.2004.06.006 ↗
9. Safety Assessment of ammonium Hectorites as used in cosmetics10.1177/1091581813507722 ↗
10. Surface modification of clay minerals
11. Cation and Anion Exchange
12. Biodegradable PLA based nanocomposites for packaging applications: the effects of organo-modified bentonite concentration10.1002/app.50907 ↗
13. Montmorillonite protection of an UV-irradiated hairpin ribozyme: Evolution of the RNA world in a mineral environment10.1186/1471-2148-7-S2-S2 ↗
14. Studies of organophilic clays: the distribution of quaternary ammonium compounds on clay surfaces and the role of impurities10.1016/0277-5387(95)00053-U ↗
15. Enhancing sun care using bentone® hectorite clay technology
16. Clay minerals and their beneficial effects upon human health: A review10.1016/S0169-1317(01)00085-0 ↗
17. Clay and non-clay minerals in the pharmaceutical and cosmetic industries Part II. Active ingredients10.1016/j.clay.2009.10.016 ↗
18. Desarrollo galénico de peloides terapéuticos
19. Boosting the effectiveness of UV filters and sunscreen formulations using photostable, non-toxic inorganic platelets10.1039/D3CC05279F ↗
20. Rheology of complex topical formulations: an analytical quality by design approach to method optimization and validation10.3390/pharmaceutics15071810 ↗
21. Clay minerals and layered double hydroxides for novel biological applications
22. Cosmetic packaging to save the environment: Future perspectives10.3390/cosmetics6020026 ↗
23. Towards sustainable color cosmetics packaging10.3390/cosmetics10050139 ↗
24. Novel polylactic acid (PLA)-organoclay nanocomposite bio-packaging for the cosmetic industry; migration studies and in vitro assessment of the dermal toxicity of migration extracts10.1016/j.polymdegradstab.2019.108938 ↗
25. The influence of organic modification on the cytotoxicity of clay particles to keratinocytes, hepatocytes and macrophages; an investigation towards the safe use of polymer-clay nanocomposite packaging10.1016/j.fct.2019.02.015 ↗
26. Palygorskite organophilic for dermopharmaceutical application10.1007/s10973-012-2891-4 ↗
27. The influence of different concentrations of a natural clay material as active principle in cosmetic formulations10.1590/1980-5373-mr-2019-0572 ↗
28. Characterization of intercalation compounds of sunscreens in a bentonite organoclay
29. Spectral Homeostasis - the fundamental requirement for an ideal sunscreen10.1159/000517593 ↗
30. Melanoma risk factors and prevention10.1016/j.cps.2021.05.001 ↗
31. Nanostructured Zn-Ti layered double hydroxides with reduced photocatalytic activity for sunscreen application10.1007/s11051-019-4488-3 ↗
32. EU · 2009
33. A skin moisturizing cream containing Quaternium-18-Bentonite effectively improves chronic hand dermatitis10.1177/120347540100500302 ↗
34. Sustainable materials with enhanced mechanical properties based on industrial polyhydroxyalkanoates reinforced with organomodified sepiolite and montmorillonite10.3390/polym11040696 ↗
35. Wound healing activity of nanoclay/spring water hydrogels10.3390/pharmaceutics12050467 ↗
36. Assessment of hectorite/spring water hydrogels as wound healing products
37. Natural inorganic ingredients in wound healing10.2174/1381612826666200113162114 ↗
38. Clay minerals as bioink ingredients for 3D printing and 3D bioprinting: application in tissue engineering and regenerative medicine10.3390/pharmaceutics13111806 ↗
39. Solid-state synthesis of organoclays: physicochemical properties and application for bisphenol a removal from aqueous solutions10.5772/intechopen.107503 ↗
40. Biomedical applications of cationic clay minerals10.1039/C4RA16945J ↗
41. Decorative cosmetics
42. Peloids and pelotherapy: Historical evolution, classification and glossary10.1016/j.clay.2013.02.008 ↗
43. Benefits and risks of clays and clay minerals to human health from ancestral to curent times: a synoptic overview10.1007/s42860-021-00160-7 ↗
44. Biocosmetics: technological advances and future outlook10.1007/s11356-021-17567-3 ↗
45. Hectorite and bentonite effect on water-based polymer coating rheology10.1016/j.crci.2018.11.011 ↗
46. Influence of monomer on structure, processing and application characteristics of UV curable urethane acrylate composite coatings10.1088/1757-899X/111/1/012008 ↗
47. High oxygen barrier cosmetic packaging material comprises perchloroethylene resin, epoxy resin, amino silicone oil, dibutyl benzoate, acrylonitrile, paraffin wax, nano clay, quartz, bismaleimide, antioxidant, plasticizer and stabilizer
48. Sunscreens and photoaging: a review of current literature10.1007/s40257-021-00632-5 ↗
49. Gubitosa · 2020 · 349
50. Organoclay applications and limits in the environment10.1016/j.crci.2018.09.004 ↗
51. Organoclay applications and limits in the environment10.1016/j.crci.2018.09.004 ↗
52. Organo-modification of montmorillonite10.1007/s42860-020-00098-2 ↗
53. GVR · 2022 · 2023
54. Magnesium and calcium organophyllosilicates: Synthesis and in vitro cytotoxicity study10.1021/am200406k ↗
55. Rheology of organoclay suspension10.1007/s00396-011-2438-4 ↗
56. A novel organoclay with antibacterial activity prepared from montmorillonite and Chlorhexidini Acetas10.1016/j.jcis.2005.10.031 ↗
57. Synthesis of organoclays: a critical review and some unresolved issues10.1016/j.clay.2014.02.008 ↗
58. Analysis of organoclays and organic adsorption by clay minerals10.1016/B978-0-08-100355-8.00010-2 ↗
59. Antibacterial activity of organomontmorillonites and organovermiculites prepared using chlorhexidine diacetate10.1016/j.clay.2013.07.013 ↗
60. Antimicrobial activity of organically modified nano-clays10.1166/jnn.2008.248 ↗
61. Rheological characterization of pharmaceutical and cosmetic formulations for cutaneous applications10.2174/1381612825666190716110919 ↗
62. Characterization of natural clays from Italian deposits with focus on elemental composition and exchange estimated by EDX analysis: potential pharmaceutical and cosmetic uses10.1346/CCMN.2016.064038 ↗
63. Overview of bioplastic introduction and its applications in product packaging10.3390/coatings11111423 ↗
64. Copolymer having carbosiloxane dendrimer structure, and composition and cosmetic containing the same
65. Mechanochemical methods for the preparation of intercalation compounds, from intercalation to the formation of layered double hydroxides10.1039/C7DT03736H ↗
66. Preparation of a microporous biphenyl-pillared layered hybrid material using organic-bridged alkoxysilane and layered silicic acid10.1039/b415504a ↗
67. Powder design for UV-attenuating agent with high transparency for visible light10.1023/A:1004826002503 ↗
68. In vitro toxicity of functionalised nanoclays is mainly driven by the presence of organic modifiers10.3109/17435390.2013.776123 ↗
69. Surface grafting of sepiolite with a phosphaphenanthrene derivative and its flame-retardant mechanism on PLA nanocomposites10.1016/j.polymdegradstab.2019.04.012 ↗
70. The rheologically-complex fluid beauty of nail lacquer formulations10.1039/D0SM02248A ↗
71. Jones, S., Coughlin, G., 2008. Iridescent film for gas-containing articles such as balloon, and container including cosmetics and personal care products such as perfume, shampoo, baby oil, mascara, eye shadow, conditioner, and deodorant, has silicate coating layer. US2008014380-A1.
72. Use of nanoclay platelets in food packaging materials: technical and cytotoxicity approach10.1080/19440049.2013.874045 ↗
73. Powdered solid cosmetic and manufacturing method therefor
74. Adsorption of quaternary amine surfactants and their penetration into the intracrystalline cavities of sepiolite10.1039/c3nj00752a ↗
75. Intercalation of 8-hydroxyquinoline into Al-smectites by solid-solid reactions10.1346/000986002320514154 ↗
76. Korichi · 2009
77. Adsorption of the quaternary ammonium salts on montmorillonite10.1016/j.jpcs.2003.09.015 ↗
78. Laba · 1993
79. Layer charge determination by alkylammonium ions
80. Determination of the layer charge in mica-type layer silicates
81. Magadiite and H-magadiite: I. Sodium magadiite and some of its derivatives
82. Clay mineral–organic interactions10.1016/B978-0-08-098258-8.00015-8 ↗
83. Efficacy of a novel SPF booster based on research aboard the international space station10.3390/cosmetics10050138 ↗
84. Rheological properties of organoclay suspensions in epoxy network precursors10.1016/j.clay.2003.11.004 ↗
85. Compositional, technical and safety specifications of clays to be used as pharmaceutical and cosmetic products10.1016/j.clay.2006.06.016 ↗
86. Pharmaceutical and cosmetic uses of fibrous clays
87. Lignosulfonate is an efficient SPF booster: Application to eco-friendly sunscreen formulations
88. Antimicrobial agent as disinfectant for plants, obtained by introducing tertiary and/or quaternary ammonium ion to magadiite and/or kenyaite, and carrying out scale like crystallization to obtain spherical shape particles
89. Cytotoxicity and mutagenicity assessment of organomodified clays potentially used in food packaging10.1016/j.tiv.2015.03.010 ↗
90. In vitro toxicity evaluation of new silane-modified clays and the migration extract from a derived polymer-clay nanocomposite intended to food packaging applications10.1016/j.jhazmat.2017.08.003 ↗
91. The antimicrobial properties of modified pharmaceutical bentonite with zinc and copper10.3390/pharmaceutics13081190 ↗
92. Synthesis and characterization of nanomaterial based on halloysite and hectorite clay minerals covalently bridged10.3390/nano11020506 ↗
93. Thixotropic hydrogels based on laponite® and cucurbituril for delivery of lipophilic drug molecules10.1002/cplu.202300370 ↗
94. Preparation and performance of superhydrophobic surfaces with low surface energy modified attapulgite10.1016/j.molstruc.2023.136586 ↗
95. Controlled release and antibacterial activity chlorhexidine acetate (CA) intercalated in montmorillonite10.1016/j.ijpharm.2009.08.004 ↗
96. Effect of organically modified layered double hydroxides on the properties of poly(lactic acid)/poly[(butylene succinate)-co-adipate] immiscible blends
97. Synthesis of nano pigments using clay minerals and organic dyes and their application as colorants in polymer matrix
98. Yield stress and thixotropy: on the difficulty of measuring yield stresses in practice10.1039/b517840a ↗
99. Nanomaterials for lip and nail cares applications10.1016/B978-0-12-822286-7.00029-2 ↗
100. Clay minerals: Properties and applications to dermocosmetic products and perspectives of natural raw materials for therapeutic purposes—a review10.1016/j.ijpharm.2017.10.031 ↗