Influence of coal-measure kaolinite with different types on the preparation of kaolinite nanotube

Coal-measure kaolinite with different types were selected to explore the influence of raw mineral on the preparation of intercalation compounds and kaolinite nanotubes. Types of coal-measure kaolinite were feldspar-pseudomorph kaolinite (HSS), worm-like kaolinite (XY), brain striatum kaolinite (CBM), mica-pseudomorph kaolinite (CBM) and crypto crystalline kaolinite (HW and HY), respectively. And the average crystal size of coal-measure kaolinite after grinding of HSS, XY, CBM, HW and HY were 2.60 μm, 6.81 μm, 3.28 μm, 0.52 μm and 0.32 μm, respectively. Characterization methods of XRD, FTIR and SEM were utilized to reveal the change in the crystal structure of kaolinite before and after intercalation reactions, the vibrational pattern of the chemical bond and the surface morphology characteristics of raw minerals and kaolinite nanotubes. Results showed that intercalation effects were significantly different among the selected coal-measure kaolinite, and the intercalation rates of intercalation compound of HSS-KD, XY-KD, CBM-KD, HW-KD and HY-KD were 80.71%, 83.33%, 82.99%, 55.13% and 65.23%, respectively. That is to say, Intercalation rates of feldspar-pseudomorph kaolinite, worm-like kaolinite, brain striatum kaolinite and mica-pseudomorph kaolinite were significantly higher than those of crypto crystalline coal-measure kaolinite which were reflected from intercalation compound of coal-measure kaolinite/dimethyl sulfoxide. Furthermore, the intercalation rates of the precursor intercalation compounds affect the intercalation effect of macromolecular intercalation agents and the yield of kaolinite nanotubes. According to the SEM patterns of kaolinite nanotubes, yield of kaolinite nanotube of HSS, XY, CBM, HW and HY were 80%, 88%, 72%, 28% and 35%, respectively. It could be concluded that yield of kaolinite nanotube of coarse crystalline coal-measure kaolinite was higher than that of crypto crystalline coal-measure kaolinite.