journal article·2022-10

CO2 fixation mechanism of kaolin treated with organic amines at varied temperatures and pressure

Qinghe Liu, Jinlong Jiang, Fan Zhang, Xiaohui Jia, Hongfei Cheng, Andrei Krasilin, Jing Ouyang

Publisher page

Abstract

CO 2 capture and storage is an effective way to control CO 2 levels in the atmosphere. However, the adsorption technology is determined by many factors, such as temperature, pressure, and material cost. In this study, a clay-based CO 2 adsorbent was designed to monitor the possible factors that affect the geological condensation of CO 2 under varied conditions. The effect of molecular chain length on the CO 2 adsorption performance of intercalated kaolinite was discussed in detail. The prepared kaolinite/n-hexylamine complex achieved a 17.0 (±0.4) mL/g CO 2 adsorption capacity when 6.35% (±0.05) n-hexylamine was loaded, which has significantly improved the utilization rate of organic amines. A higher relative CO 2 adsorption capacity (in proportion to the amount of amine) was obtained at lower temperatures and higher pressures. The mechanism of CO 2 adsorption of organic amine-intercalated kaolinite was discussed based on Fourier transform infrared spectroscopy and specific surface area measurements. The enhanced relative CO 2 adsorption capacity at low-temperature and high-pressure conditions may provide a hint to the geological condensation of CO 2 at high latitude positions.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Dioxide Capture Technologies · Membrane Separation and Gas Transport · Phase Equilibria and Thermodynamics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Evaluation of kaolinite and quartz differential thermal curves with a new high temperature cell
2. Methanol synthesis through CO2 capture and hydrogenation: thermal integration, energy performance and techno-economic assessment10.1016/j.jcou.2020.101407 ↗
3. High-efficiency photo-Fenton Fe/g-C3N4/kaolinite catalyst for tetracycline hydrochloride degradation10.1016/j.clay.2021.106213 ↗
4. Amine modification on kaolinites to enhance CO2 adsorption10.1016/j.jcis.2014.08.050 ↗
5. A comparative study on energy efficient CO2 capture using amine grafted solid sorbent: Materials characterization, isotherms, kinetics and thermodynamics10.1016/j.energy.2021.122348 ↗
6. Electrokinetic energy conversion in self-assembled 2D nanofluidic channels with Janus nanobuilding blocks10.1002/adma.201700177 ↗
7. Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation10.1016/j.progpolymsci.2007.01.008 ↗
8. Enhancement of CO2 adsorption on phenolic resin-based mesoporous carbons by KOH activation10.1016/j.carbon.2013.08.034 ↗
9. Monodispersed CuFe2O4 nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation10.1016/j.apcatb.2019.04.052 ↗
10. Grafted organic derivatives of kaolinite: II. Intercalation of primary n-alkylamines and delamination10.1180/0009855054040191 ↗
11. Zeolite imidazolate framework (ZIF)-based mixed matrix membranes for CO2 separation: a review10.1002/app.48968 ↗
12. Amine-impregnated millimeter-sized spherical silica foams with hierarchical mesoporous–macroporous structure for CO2 capture10.1016/j.cej.2014.08.043 ↗
13. Y2O3 functionalized natural palygorskite as an adsorbent for methyl blue removal10.1039/C6RA04350J ↗
14. Study on the efficiency of multiple amino groups in ionic liquids on their sorbents performance for low-temperature CO2 capture10.1016/j.cherd.2021.01.016 ↗
15. Time-efficient preparation and mechanism of methoxy-grafted kaolinite via acid treatment and heating10.1016/j.clay.2019.04.001 ↗
16. Energy modeling of competition between tubular and platy morphologies of chrysotile and halloysite layers10.1007/s42860-020-00086-6 ↗
17. An overview of current status of carbon dioxide capture and storage technologies10.1016/j.rser.2014.07.093 ↗
18. CO2 capture in amine-based aqueous solution: role of the gas–solution interface10.1002/anie.201101250 ↗
19. Mechanism of kaolinite sheets curling via the intercalation and delamination process10.1016/j.jcis.2014.12.039 ↗
20. Methoxy-grafted kaolinite preparation by intercalation of methanol: Mechanism of its structural variability10.1016/j.clay.2016.12.031 ↗
21. A comparative study of synthetic tubular kaolinite nanoscrolls and natural halloysite nanotubes10.1016/j.clay.2018.12.014 ↗
22. CO2 adsorption properties and thermal stability of different amine-impregnated MCM-41 materials10.1016/S1872-5813(13)60025-0 ↗
23. Simulation assisted characterization of kaolinite–methanol intercalation complexes synthesized using cost-efficient homogenization method10.1016/j.apsusc.2015.09.081 ↗
24. Influencing parameters of direct homogenization intercalation of kaolinite with urea, dimethyl sulfoxide, formamide, and N-methylformamide10.1016/j.clay.2019.105287 ↗
25. The effect of structural order on nanotubes derived from kaolin-group minerals10.1346/CCMN.2009.0570406 ↗
26. Review of the fabrication and application of porous materials from silicon-rich industrial solid waste10.1007/s12613-021-2360-9 ↗
27. Amine-impregnated mesoporous silica nanotube as an emerging nanocomposite for CO2 Capture10.1021/acsami.6b05044 ↗
28. Infrared spectra of kaolin mineral-dimethyl sulfoxide complexes10.1021/j100847a045 ↗
29. Radical guided selective loading of silver nanoparticles at interior lumen and out surface of halloysite nanotubes10.1016/j.matdes.2016.07.127 ↗
30. CO2 capturing performances of millimeter scale beads made by tetraethylenepentamine loaded ultra-fine palygorskite powders from jet pulverization10.1016/j.cej.2018.02.040 ↗
31. Polyethyleneimine (PEI) loaded MgO-SiO2 nanofibers from sepiolite minerals for reusable CO2 capture/release applications10.1016/j.clay.2017.11.023 ↗
32. Textural properties determined CO2 capture of tetraethylenepentamine loaded SiO2 nanowires from α-sepiolite10.1016/j.cej.2017.12.109 ↗
33. Degradation of Congo red dye by a Fe2O3@CeO2-ZrO2/palygorskite composite catalyst: synergetic effects of Fe2O310.1016/j.jcis.2018.12.052 ↗
34. Porous inorganic membranes for CO2 capture: present and prospects10.1021/cr400237k ↗
35. Efficient CO2 sorbents based on silica foam with ultra-large mesopores10.1039/c2ee21394j ↗
36. Process and engineering trends in membrane based carbon capture10.1016/j.rser.2016.10.025 ↗
37. Poly(glycidyl amine)-loaded SBA-15 sorbents for CO2 capture from dilute and ultradilute gas mixtures10.1021/acsapm.9b00788 ↗
38. A strategy for introducing modern bioenergy into developing Asia to avoid dangerous climate change10.1016/j.apenergy.2009.04.023 ↗
39. High-capacity loading of 5-fluorouracil on the methoxy-modified kaolinite10.1016/j.clay.2014.02.022 ↗
40. CO2 capture in ionic liquids: a review of solubilities and experimental methods10.1155/2013/473584 ↗
41. Chemically modified kaolinite. Grafting of methoxy groups on the interlamellar aluminol surface of kaolinite10.1039/jm9960601679 ↗
42. Single-route delaminated clay composites for efficient visible-light photo-mineralization of antibiotic-resistant bacteria and associated genes in water10.1016/j.apcatb.2021.120143 ↗
43. Infrared study of CO2 sorption over “molecular basket” sorbent consisting of polyethylenimine-modified mesoporous molecular sieve10.1021/jp809946y ↗
44. Amine-modified ordered mesoporous silica: the effect of pore size on CO2 capture performance10.1016/j.apsusc.2014.10.135 ↗
45. Functionalized 2D clay derivative: hybrid nanosheets with unique lead sorption behaviors and interface structure10.1002/admi.201700934 ↗
46. Enhancing the CO2 capture efficiency of amines by microgel particles10.1016/j.ijggc.2020.103172 ↗
47. A review of CO2 capture by absorption and adsorption10.4209/aaqr.2012.05.0132 ↗
48. From platy kaolinite to aluminosilicate nanoroll via one-step delamination of kaolinite: effect of the temperature of intercalation10.1016/j.clay.2013.08.027 ↗
49. Intercalation of acrylic acid and sodium acrylate into kaolinite and their in situ polymerization10.1016/j.jpcs.2006.09.020 ↗
50. Strategic design of clay-based multifunctional materials: from natural minerals to nanostructured membranes