journal article·2011-01

Adsorption of berberine on commercial minerals

Giora Rytwo, Hilla Varman, Nir Bluvshtein, Tom N. König, Asaf Mendelovits, Amir Sandler

Applied Clay Science· Volume 51· Issue 1-2
Publisher page

Abstract

Abstract There is interest in studying interactions between organic modifiers and raw commercial clays aiming the production of low-cost “organoclays”. In this study we report the interaction between berberine — a monovalent organic cation — and three commercial bentonites and a Turkish zeolite. The Turkish zeolite exhibited adsorption at values of 5–10% of the cation exchange capacity (CEC) with no neutralization of the particles. Adsorption of the organo-cation on Egyptian bentonite, Volclay KWK and Pure-Flo B80, was above the CEC of the bentonites, yielding neutral and even slightly positively charged particles. Electron microscopy and X-ray diffraction results showed expansion of the basal spacing of the smectite. Such low-cost organo-bentonites might be suitable for environmental applications as removal of pollutants, drug and pesticides delivery, or water treatment. Application in turbidity reduction of industrial effluents is demonstrated.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Clay minerals and soil interactions · Soil and Unsaturated Flow · Grouting, Rheology, and Soil Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Pretreatment of corn oil for physical refining10.1007/s11746-998-0191-8 ↗
2. American Colloid Company · 2001
3. The use of organo-clays in water treatment10.1016/j.clay.2003.07.006 ↗
4. Suitability of dye–clay complexes for removal of non-ionic organic compounds from aqueous solutions10.1016/S0045-6535(00)00337-4 ↗
5. Clays and pollution control
6. Photostabilization of biocontrol agents by berberine10.1080/09670870150215612 ↗
7. Temperature effects on iodine adsorption on organo-clay minerals II10.1016/j.clay.2004.01.005 ↗
8. Conventional applications
9. Beneficiation and applications of an Egyptian bentonite10.1016/S0169-1317(98)00021-0 ↗
10. Production of conjugated linoleic acid-rich potato chips10.1111/j.1750-3841.2006.00201.x ↗
11. Expandable palygorskite from the Cretaceous-Tertiary boundary, Mangyshlak Peninsula, U.S.S.R10.1346/CCMN.1987.0350609 ↗
12. Removal of ammonium ion from aqueous solution using natural Turkish clinoptilolite10.1016/j.jhazmat.2005.12.042 ↗
13. Preparation and application of organo-minerals as sorbents of phenol, benzene and toluene10.1016/S0169-1317(00)00040-5 ↗
14. Colloid Clay Science
15. Clay mineral organic interactions
16. Identification of berberine in ancient and historical textiles by surface-enhanced Raman scattering10.1002/jrs.1726 ↗
17. Mineralogical and geochemical characterization of palygorskite from Gabasa (NE Spain)10.1180/claymin.1996.031.1.03 ↗
18. Moore · 1989
19. Clay-organic complexes as adsorbents for phenol and chlorophenols10.1346/CCMN.1986.0340512 ↗
20. Rheological and electrical properties of Egyptian bentonite as a drilling mud10.1002/app.25277 ↗
21. Use of modified bentonite for phenolic adsorption in treatment of olive oil mill wastewater
22. Clays and pesticides
23. Oil-Dri Corp. 2005. Pure-Flo Natural B80 CG technical data sheet. Available at www.oildri.com.
24. Protein haze in bottled white wines: how well do stability tests and bentonite fining trials predict haze formation during storage and transport?10.1111/j.1755-0238.2006.tb00061.x ↗
25. Use of CV- and TPP-montmorillonite for the removal of priority pollutants from water10.1016/j.clay.2006.04.016 ↗
26. Preparation of berberine–montmorillonite–metolachlor formulation from hydrophobic/hydrophilic mixtures10.1016/j.clay.2007.09.006 ↗
27. Rytwo, G., Mendelovits, A., Eliyahu, D., Pitcovski J., Aizenshtein, E., 2010. Adsorption of two vaccination related proteins to montmorillonite and organo-montmorillonite. Submitted to Applied Clay Sciences, May 2010.10.1016/j.clay.2010.10.015 ↗
28. Rytwo, G.; A. Rettig and Y. Gonen, 2011. Organoclay nanoparticles for efficient removal of suspended solids: application to winery effluents. Submitted to Applied Clay Sciences., September 2010.
29. Removal of ammonium ion from aqueous solution by natural Turkish (Yıldızeli) zeolite for environmental quality10.1016/j.jhazmat.2006.06.124 ↗
30. Phenol adsorption by organoclays having different charge characteristics10.1016/j.colsurfa.2003.10.014 ↗
31. Potential contribution of smectite clays and organic matter to pesticide retention in soils10.1021/jf001485d ↗
32. Hepatobiliary excretion of berberine10.1124/dmd.32.4.405 ↗
33. USACE, 2001. Adsorption design guide, U.S. Army Corps of Engineers. Available at: http://www.usace.army.mil/inet/usace-docs/design-guides/dg1110–1–2/contents.htm.
34. Adsorption properties of tetradecyl- and hexadecyl trimethylammonium bentonites10.1016/j.clay.2004.08.001 ↗
35. Kinetics of phenol and aniline adsorption and desorption on an organo-clay10.2136/sssaj1993.03615995005700020009x ↗
36. Sorption of trichloroethylene by organoclays in the presence of humic substances10.1016/S0043-1354(98)00172-9 ↗
37. Sorption of phenol, p-nitrophenol and aniline to dual-cation organobentonites from water10.1021/es990177x ↗
38. Zoecklein · 1990 · 355