journal article·2014-11

Composite pigments based on surface coated kaolin and metakaolin

Václav Štengl, Daniela Popelková, Tomáš Matys Grygar

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Abstract

Abstract Synthesis The method of homogeneous hydrolysis of Fe, Co, Cr, Ni, Mn, Ti, Al, and Zn salts with urea in aqueous solutions in the presence of substrates (kaolin, metakaolin and mullite) was used for the preparation of composite pigments. In these composites individual kaolinite platelets were covered by a thin layer of hydroxide or oxy-hydroxides of selected metals, which were transformed into a metal oxide layer strongly bond to the aluminosilicate surface by heat treatment. An analogous method, homogeneous hydrolysis of thioacetamide in the presence of Cd and Zn salts was used for pigments based on sulphides. Characterization The mineralogical composition of the pigments was identified by X-ray powder diffraction (XRD), the particle morphology was studied by transmission electron microscopy (TEM) and the color was characterized in CIEL*a*b colours coordinates. Results The kaolin and metakaolin coated with layer of metal oxides are interesting new composite materials, obtained by a very simple preparation process at a low cost.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Pigment Synthesis and Properties · TiO2 Photocatalysis and Solar Cells · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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