journal article·2011-10

Effects of adding organo-clays for acrylic-based intumescent coating on fire-retardancy of painted thin plywood

Chih-Shen Chuang, Kuang-Chung Tsai, Te-Hsin Yang, Chun-Han Ko, Ming-Kuang Wang

Applied Clay Science· Volume 53· Issue 4
Publisher page

Abstract

Abstract Intumescent material with commercial resin, such as acrylic copolymer resin, has been demonstrated to be extremely effective in improving the fire performance of wooden materials used for indoor furnishing. This study investigates the enhancement of painted thin red lauan (Parashorea spp.) plywood by using intumescent coating with organo-clays added with different types of Cloisite 30B, Cloisite 10A and Cloisite 15A and different amounts of organo-clays (1, 3, 5 and 10%). These intumescent formulations significantly enhanced the fire retardancy of painted plywood, exhibiting lower peak heat release rates (PHRR) and extending the time to reach PHRR, as compared with plywood panels coated with intumescent coating with absence of organo-clay. Therefore, the amount of organo-clays added in intumescent is important. In additional, 3% of Cloisite 30B and 5% of Cloisite 10A further enhanced fire retardancy. The FT-IR, 27Al and 31P NMR analyses demonstrated that adding organo-clay extended the survival duration of the phosphor-carbonaceous chars structure.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Flame retardant materials and properties · Fire dynamics and safety research · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

Show source-provided references
1. A.S.T.M. Standard · 1999
2. Synergistic effect of zeolite in an intumescence process: study of the carbonaceous structures using solid-state NMR10.1039/ft9969200149 ↗
3. PA-6 clay nanocomposite hybrid as char forming agent in intumescent formulations10.1002/1099-1018(200007/08)24:4<201::AID-FAM739>3.0.CO;2-D ↗
4. Recent advances for intumescent polymers10.1002/mame.200400007 ↗
5. Nanomorphology and reaction to fire of polyurethane and polyamide nanocomposites containing flame retardants10.1016/j.polymdegradstab.2009.11.011 ↗
6. Study of the mechanism of intumescence in fire retardant polymers: Part VI — mechanism of ester formation in ammonium polyphosphate–pentaerythritol mixtures10.1016/0141-3910(85)90090-4 ↗
7. Chinese National Standard · 1993
8. Chinese National Standard · 2010
9. Effects of intumescent formulation for acrylic-based coating on flame-retardancy of painted red lauan (Parashorea spp.) thin plywood10.1007/s00226-008-0197-2 ↗
10. Influence of ammonium polyphosphate on the mechanism of thermal degradation of an acrylic binder resin10.1002/app.20868 ↗
11. On the 31P chemical shift anisotropy in condensed phosphates10.1016/0301-0104(84)85115-0 ↗
12. Flammability and thermal stability studies of polymer layered-silicate (clay) nanocomposites10.1016/S0169-1317(99)00019-8 ↗
13. The effect of new flame retardant systems containing montmorillonite-butyl acrylate nanoclay on the flammability properties of polyurethane polymer10.1080/03602550701298598 ↗
14. Complex char formation in flame-retarded fire-intumescent combinations-II. Thermal analytical studies10.1016/S0141-3910(96)00054-7 ↗
15. p-Nitrophenol, phenol and aniline sorption by organo-clays10.1016/j.jhazmat.2007.03.075 ↗
16. Effects of some impregnation chemicals on combustion characteristics of laminated veneer lumber (LVL) produced with oak and poplar veneers10.15376/biores.5.1.70-80 ↗
17. Combustion properties of Oak (Quercus robur L.) laminated veneer lumbers bonded with PVAc, PF adhesive and impregnated with some fire-retardants10.1163/156855408X402939 ↗
18. Comprehensive study of the degradation of an intumescent EVA-based material during combustion10.1023/A:1004758218104 ↗
19. Mechanisms of action of phosphorus based flame retardants in acrylic polymers10.1002/1097-0126(200010)49:10<1183::AID-PI584>3.0.CO;2-7 ↗
20. Phosphate sorption by synthetic amorphous aluminum hydroxides: a 27Al and 31P solid-state MASS NMR-spectroscopy study10.1111/j.1365-2389.1994.tb00484.x ↗
21. Solid-state high-resolution 27Al nuclear magnetic resonance studies of the structure of CaO–Al2O3–P2O5 glasses
22. Data Handbook for Clay Minerals and other Non-Metallic Minerals
23. Effect of clay on the fire-retardant properties of a polyethylenic copolymer containing intumescent formulation10.1088/1468-6996/9/2/024408 ↗