journal article·2010-02

Mechanical and textural properties of extruded materials manufactured with AlFe and AlCeFe pillared bentonites

N.R. Sanabria, P. Ávila, M. Yates, S.B. Rasmussen, R. Molina, S. Moreno

Applied Clay Science· Volume 47· Issue 3-4
Publisher page

Abstract

Abstract Extrudates were developed on AlFe and AlCeFe pillared bentonites shaped as pellets, Raschig rings and monoliths were prepared with Na- or Ca-bentonite as binder. The AlFe and AlCeFe poly(hydroxo metal) bentonites were tested as catalyst in the oxidation of phenol. The mechanical stability of the extrudates, measured as breaking force was evaluated as a function of thermal treatment (105, 400 and 500 °C) together with the stability to water immersion. Calcination at 500 °C was needed to obtain water stable materials. Specific surface area, micro- and mesopore volume of the extrudates depended on the calcination temperature. The conversion rate for phenol oxidation with extrudates was generally lower than for powders, due to an increased induction period and diffusion limitations.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Polymer Nanocomposites and Properties · Clay minerals and soil interactions · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. The catalytic acylation of alcohols with acetic acid by using Lewis acid character pillared clays10.1016/j.apcata.2004.04.010 ↗
2. A novel method of Al-pillared montmorillonite preparation for potential industrial up-scaling10.1016/j.clay.2004.02.003 ↗
3. Monolithic reactors for environmental applications: a review on preparation technologies10.1016/j.cej.2005.02.025 ↗
4. Catalytic wet peroxide oxidation (CWPO) of phenol over mixed (Al–Cu)-pillared clays10.1016/S0926-3373(97)00054-4 ↗
5. Catalytic wet peroxide oxidation over mixed (Al–Fe) pillared clays10.1016/S0926-3373(00)00170-3 ↗
6. Metal-ion pillared clays as hydrocracking catalysts (I): catalyst preparation and assessment of performance at short contact times10.1016/S0016-2361(01)00193-4 ↗
7. Metal-ion pillared clays as hydrocracking catalysts (II): effect of contact time on products from coal extracts and petroleum distillation residues10.1016/S0016-2361(03)00126-1 ↗
8. Catalytic wet peroxide oxidation of phenol over Al–Cu or Al–Fe modified clays10.1016/S0169-1317(03)00124-8 ↗
9. Catalytic wet peroxide oxidation of phenol by pillared clays containing Al–Ce–Fe10.1016/j.watres.2005.06.034 ↗
10. Synthesis of pillared clays containing Al, Al–Fe or Al–Ce–Fe from a bentonite: characterization and catalytic activity10.1016/j.cattod.2005.07.157 ↗
11. Effect of Fe and Ce on Al-pillared bentonite and their performance in catalytic oxidation reactions10.1016/j.apcata.2006.10.009 ↗
12. Structural and textural characterization of a Colombian bentonite
13. A study on Al and Al–Ce–Fe pillaring species and their catalytic potential as they are supported on a bentonite10.1016/j.apcata.2007.09.047 ↗
14. Selective reduction of NO with NH3 over pillared clays modified with transition metals10.1016/j.cattod.2004.04.007 ↗
15. Pillar effects in MoS2 catalysts supported on Al and Zr pillared clays in a hydrotreatment reaction: A preliminary study
16. Preparation and characterization of extruded monolithic ceramic catalysts10.1016/S0920-5861(98)00040-6 ↗
17. The dehydrogenation of ethylbenzene to styrene catalyzed by a natural and an Al-pillared clays impregnated with cobalt compounds: a comparative study10.1016/j.apcata.2003.08.004 ↗
18. Pillared clays: catalytic evaluation in heavy oil cracking using a microactivity test10.1016/S0926-860X(98)00391-3 ↗
19. Active iron species in the catalytic wet peroxide oxidation of phenol over pillared clays containing iron10.1016/S0926-3373(03)00003-1 ↗
20. Pillared clays as catalysts for hydrocracking of heavy liquid fuels10.1016/j.apcata.2004.12.012 ↗
21. Fe-containing pillared clays as catalysts for phenol hydroxylation10.1016/S0169-1317(03)00079-6 ↗
22. High surface area monoliths based on pillared clay materials as carriers for catalytic processes10.1016/j.clay.2004.12.003 ↗
23. Catalytic reduction of nitric oxide with hydrogen and carbon monoxide in the presence of excess oxygen by Pd supported on pillared clays10.1016/j.apcata.2003.09.040 ↗
24. Surface area and microporosity of 1.8nm pillared clays from the nitrogen adsorption isotherm10.1016/S0927-6513(96)00021-1 ↗
25. Synthesis of pillared bentonite starting from the Al–Fe polymeric precursor in solid state, and its catalytic evaluation in the phenol oxidation reaction10.1016/j.cattod.2007.12.082 ↗
26. Pillared clays with Al–Fe and Al–Ce–Fe in concentrated medium: synthesis and catalytic activity10.1016/j.apcata.2009.01.013 ↗
27. Catalytic activity of pillared clays in methanol conversion10.1016/S0926-860X(02)00466-0 ↗
28. Cation exchanged and impregnated Ti-pillared clays for selective catalytic reduction of NOx by propylene10.1016/S0926-3373(02)00274-6 ↗
29. Pillared clays — a historical perspective10.1016/0920-5861(88)85002-8 ↗
30. Catalytic cracking properties of Al–Zr–B composite pillared clays10.1016/S0166-9834(00)83120-6 ↗