journal article·2015-12

Ultrasound-assisted reconstruction and delamination studies on CaAl layered double hydroxides

Elena Pérez-Barrado, Pilar Salagre, Lluís F. Marsal, Magdalena Aguiló, Yolanda Cesteros, Francesc Díaz, Josep Pallarès, Fabio Cucinotta, Leonardo Marchese, Maria Cinta Pujol

Publisher page

Abstract

Abstract Two kinds of CaAl layered double hydroxides (CaAl-LDHs) were synthesized with chloride and nitrate anions by co-precipitation method. The samples were calcined and finally reconstructed by rehydration using ultrasounds, in the presence of NaCl or NaNO 3 . Reconstructed samples presented smaller lamella size than the parent ones. All samples were characterized by X-ray powder diffraction, FT-IR spectroscopy, thermogravimetric analysis and TEM microscopy. Delamination was not achieved by mechanical stirring for 2 days, whereas most samples underwent delamination by the use of ultrasounds. Additionally, a hybrid CaAl-LDHs with CdTe quantum dots was synthesized by reconstruction of a calcined CaAl-LDHs in the presence of the quantum dots.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Layered Double Hydroxides Synthesis and Applications · Magnesium Oxide Properties and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Nanoplatelet-based reconstructed hydrotalcites: towards more efficient solid base catalysts in aldol condensations
2. Delamination of layered double hydroxides by use of surfactants10.1039/a908251d ↗
3. Preparation and study of Cu–Al mixed oxides via hydrotalcite-like precursors10.1021/cm980500f ↗
4. Structure evolution of layered double hydroxide activated by ultrasound induced reconstruction10.1016/j.clay.2013.08.006 ↗
5. Hydrotalcite-type anionic clays: Preparation, properties and applications10.1016/0920-5861(91)80068-K ↗
6. Quantum dot-layered double hydroxide composites for near-infrared emitting codes10.1039/C3TC31699H ↗
7. New synthetic routes to hydrotalcite-like compounds — characterisation and properties of the obtained materials
8. Multiwavelength luminescence in lanthanide-doped hydrocalumite and mayenite10.1021/cm200408x ↗
9. Quantum dots in organo-modified layered double hydroxide framework-improved peroxynitrous acid chemiluminescence for nitrite sensing10.1016/j.snb.2013.07.060 ↗
10. Structural aspects of layered double hydroxides
11. Evidences for decarbonation and exfoliation of layered double hydroxide in N,N-dimethylformamide-ethanol solvent mixture10.1016/j.jssc.2007.05.003 ↗
12. Synthetic hydrotalcite-type and hydrocalumite-type layered double hydroxides for arsenate uptake10.1016/j.clay.2010.03.017 ↗
13. Mesoporous layer-by-layer ordered nanohybrids of layered double hydroxide and layered metal oxide: highly active visible light photocatalysts with improved chemical stability10.1021/ja203388r ↗
14. He · 2006 · vol. 119 · 89
15. New approach to the delamination of layered double hydroxides10.1039/b101135i ↗
16. Delamination of layered double hydroxides containing amino acids10.1021/cm048842a ↗
17. Delamination and restacking of hybrid layered double hydroxides assessed by in situ XRD10.1016/j.jcis.2004.01.082 ↗
18. Sonication assisted rehydration of hydrotalcite catalyst for isomerization of glucose to fructose10.1016/j.molcata.2014.06.019 ↗
19. Positively charged nanosheets derived via total delamination of layered double hydroxides10.1021/cm0510460 ↗
20. Study of as-synthesized and calcined hydrocalumites as possible antacid agents10.1007/s12034-014-0029-y ↗
21. Synthesis, anion exchange, and delamination of Co–Al layered double hydroxide: assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies10.1021/ja0584471 ↗
22. Exfoliating layered double hydroxides in formamide: a method to obtain positively charged nanosheets10.1039/b605422f ↗
23. Crystal structure of Kuzel's salt 3CaO·Al2O3·1/2CaSO4·1/2CaCl2·11H2O determined by synchrotron powder diffraction10.1016/j.cemconres.2011.01.015 ↗
24. Neutral nanosheets that gel: exfoliated layered double hydroxides in toluene10.1021/jz2004655 ↗
25. Synthetic hydrotalcites from different routes and their application as catalysts and gas adsorbents: a review10.1002/aoc.1517 ↗
26. Impact of the memory effect on the catalytic activity of Li–Al hydrotalcite-like compounds for the cyanoethylation reaction10.1016/j.materresbull.2010.06.003 ↗
27. The effect of ageing step elimination on the memory effect presented by Mg0.75Al0.25 hydrotalcites (HT) and their catalytic activity for cyanoethylation reaction10.1016/j.catcom.2011.02.005 ↗
28. Fast aging treatment for the synthesis of hydrocalumites using microwaves10.1016/j.clay.2013.05.006 ↗
29. Layered double hydroxide-like materials: nanocomposites for use in concrete10.1016/j.cemconres.2004.05.012 ↗
30. Structural phase transition and high temperature phase structure of Friedels salt, 3CaO · Al2O3 · CaCl2 · 10H2O10.1016/S0008-8846(99)00199-4 ↗
31. Thermal behavior of the nitrated AFm phase Ca4Al2(OH)12(NO3)2 · 4H2O and structure determination of the intermediate hydrate Ca4Al2(OH)12(NO3)2 · 2H2O10.1016/S0008-8846(99)00251-3 ↗
32. Intercalation of drugs in layered double hydroxides and their controlled release: a review10.1016/j.clay.2013.12.002 ↗
33. Layered double hydroxides applications as sorbents for environmental remediation
34. Revised effective radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
35. Reconstructed Mg/Al hydrotalcite as a solid base catalyst for synthesis of jasminaldehyde10.1016/j.apcata.2010.07.021 ↗
36. Layered double hydroxides as carriers for quantum dots@silica nanospheres10.1039/c2nr31550e ↗
37. Layered double hydroxide platelets exfoliation into a water-based polyester10.1002/app.38483 ↗
38. Carbon quantum dot/NiFe layered double-hydroxide composite as a highly efficient electrocatalyst for water oxidation10.1021/am501256x ↗
39. Silylation of layered double hydroxides via a calcination–rehydration route10.1021/la902812g ↗
40. Comprehending the thermal decomposition and reconstruction process of sol–gel MgAl layered double hydroxides10.1021/jp910538r ↗
41. Hydrocalumite and its polymer derivatives. 1. Reversible Thermal behavior of Friedel's salt: a direct observation by means of high-temperature in situ powder X-ray diffraction10.1021/cm031069j ↗
42. Recent advances in the synthesis and application of Layered Double Hydroxide (LDHs) nanosheets10.1021/cr200434v ↗
43. Characterization of exfoliated layered double hydroxide (LDHs, Mg/Al=3) nanosheets at high concentrations in formamide10.1039/B612389A ↗
44. Hydrotalite reconstructed by in situ rehydration as a highly active solid base catalyst and its application in aldol condensations10.1039/C2RA21762G ↗
45. Organo-LDH synthesized via tricalcium aluminate hydration in the present of Na-dodecylbenzenesulfate aqueous solution and subsequent investigated by near-infrared and mid-infrared10.1016/j.saa.2014.01.062 ↗
46. Structure and luminescence behaviour of as-synthesized, calcined, and restored MgAlEu-LDH with high crystallinity10.1039/c2dt31249b ↗
47. The 2-phenylbenzimidazole-5-sulfonate/layered double hydroxide co-intercalation composite and its luminescence response to nucleotides10.1039/c4tc00755g ↗
48. Intercalation of sulfanilic acid–phenol–formaldehyde polycondensate into hydrocalumite type layered double hydroxide10.1002/zaac.201200196 ↗